• 한국음향학회지
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• 제36권3호
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• pp.186-193
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• 2017

신라대종은 성덕대왕신종을 계승하여 새 천년을 울리기 위해 제작되었다. 본 연구에서는 신라대종이 구조와 음향 측면에서 성덕대왕신종과 어떻게 유사한지를 조사하였다. 먼저 설계 및 제작 과정을 소개하고 두 종의 크기를 비교하여 유사성을 평가하였다. 한국 종소리의 세 가지 주요 특성은 웅장하고 조화로운 타격음, 역동적인 맥놀이와 길게 지속되는 여음이다. 이 세 가지 특성을 물리적 인자를 사용하여 객관적으로 평가한다. 이를 통하여 수려한 외관과 웅장하고 아름다운 소리를 내는 대형 한국 범종의 제작에 유용한 자료를 제공하는 것이 본 연구의 목적이다.

• Bulletin of the Korean Chemical Society
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• 제24권7호
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• pp.901-905
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• 2003

The lower critical solution temperature (LCST) of thermosensitive poly(organophosphazenes) with methoxypoly(ethylene glycol) (MPEG) and amino acid esters as side groups was studied as a function of saccharide concentration in aqueous solutions of mono-, di-, and polysaccharides. Most of the saccharides decreased the LCST of the polymers, and the LCST decrease was more prominently observed by saccharides containing a galactose ring, such as D-galactose, D-galactosamine and D-lactose, and also the polysacccharide, 1-6-linked D-dextran effectively decreased the LCST of the polymers. Such an effect was discussed in terms of intramolecular hydrogen bonding of saccharides in polymer aqueous solution. The saccharide effect was found to be almost independent on the kinds of the amino acid esters and MPEG length of the polymers. Such a result implies that the polymer-saccharide interaction in aqueous solution is clearly influenced by the structure of sacchardes rather than by that of the polymers. The acid saccharides such as D-glucuronic and D-lactobionic acid increased the LCST, which seems to be due to their pH effect.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1559-1563
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• 2004

The topoisomerase II poisoning effect of certain protoberberine alkaloids is associated with anti-cancer activity. Structure-activity relationships of protoberberine analogues substituted on the ring protons reveal that substitution at the C19 position is an important determinant of biological activity. In this study, the effects of substituent modification at the C19 position on the interaction of protoberberines with DNA are determined using UV and NMR spectroscopy. The line broadening effect on aliphatic resonances, chemical shift changes of the imino protons of HP14 upon berberine and berberrubine binding to HP14, and the rate of the exchange process between protoberberine analogs bound indicate that berberrubine binds HP14 more specifically than berberine. In addition, the free HP14 is altered by the substituent at the 19-position. UV spectra of berberrubine have shown a hypochromic effect together with a slight red shift, which are usually regarded as characteristics of DNA intercalation. These results are consistent with our previous report that the berberrubine is partially intercalated with HP14 with molar ratio 1 : 1, whereas a non-specific interaction is predominant between the berberine and HP14.

• 대한토목학회논문집
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• 제7권4호
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• pp.21-29
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• 1987

직립원통형 액체저장탱크가 지진하중을 받을 때, 벽면 유연성이 벽면에 작용하는 유동압력에 미치는 영향에 대해 연구하였다. 탱크 구조물은 환(ring)형 유한요소를 사용하여 이상화하였으며, 유동에 대한 해는 Laplace 방정식을 이용하여 구하였다. 쉘-유체계의 운동방정식은 자유표면거동과 벽면유연성의 상관효과까지 포함하여 구성하였으며, 이에 따른 쉘 거동과 자유표면거동에 대한 자유진동모우드를 해석하는 방법이 개발되었다. 예제해석으로는, 구조적 특성이 다른 몇개의 저장탱크에 대해, 응답스펙트럼 해석법과 시간영역 해석법을 사용하여 동적응답을 구하였고, 그 결과들을 비교 분석하였다.

• 대한화장품학회:학술대회논문집
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• 대한화장품학회 2003년도 IFSCC Conference Proceeding Book II
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• pp.184-191
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• 2003

New pyranone derivative, 2-((3E)-4(2H, 3H, -benzo[3, 4-d] 1, 3-dioxolan-5-yl)-2-oxo-but-3-enyloxy)-5-hydroxy-4H-pyran-4-one (Seletinoid $G^{TM}$), was designed as a novel retinoid on the assumption that the pyranone ring may mimic the carboxylic acid moiety in retinoid structure. The enolic hydroxy of pyranone at five position was easily deprotonated to form an enolate. The role of enolate was similar to that of carboxylic acid. To evaluate the value of Seletinoid G as an anti-aging ingredient, various tests were performed for example inhibitory effect for MMP-l expression, anti-oxidative activity, procollagen synthesis in hairless mouse and primary skin irritation. The result of this study suggested that our new synthetic retinoid could be used as a safe material for anti-aging cosmetics.

• 전자공학회논문지S
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• 제35S권5호
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• pp.42-47
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• 1998

Bridcage RF coil is one of the most widely used RF coils in MRI. In order to use birdcage RF coils in open MRI systems, an open tructured birdcage RF coil has been investigated. By opening the ring structure of an original birdcage RF coil and driving the coil at two opening ends, the original birdcage RF coil can be modified to an open structured coil. In order to improve magnetic field uniformity of the open birdcage RF coil, driving voltage phases at the two opening ends can be controlled to be in-phase or out-of-phase each other. Operating frequency of the open birdcage RF coil has been theoretically derived, and the theoretical derivation has been verified by experiments.

• 대한화학회지
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• 제24권2호
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• pp.121-128
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• 1980

Ambidentate 리간드인 isonitrosobenzoylacetone을 리간드로 하는 금속착물, tris(isonitrosobenzoylacetonato)cobalt(III) 및 bis(isonitrosobenzoylacetonato)palladium(II)을 합성한 후 분광학적 방법에 의하여 이들의 결합구조를 조사하였다. 즉 착물에서 리간드는 아세틸기의 산소 및 이소니트로소의 질소원자를 통하여 금속에 배위되어 5원의 킬레이트고리를 이루고 있음을 알 수 있었다. 이 결합구조는 Patel과 Haldar등이 얻었던 isonitrosoacetylacetone착물의 그 것들과 유사하다.

• 대한화학회지
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• 제42권4호
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• pp.391-397
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• 1998

퓨란 고리를 포함하는 bis-furan lexitropsin에서, DNA minor groove의 염기쌍과 결합하는 중요 부분인 퓨란의 기하학적 구조를 반경험적 방법(MNDO)과 ab initio(Hartree-Fock) 방법으로 최적화 시켰다. 최적화된 구조에 대해 6-31G와 $6-31G^{\ast}$ basis set을 사용하여 전자적 구조와 양성자 친화도를 구하였다. 아울러 퓨란의 양성자 친화도에 미치는 치환기 효과를 알아보기 위해 전자를 주는 기와 전자를 끄는 기를 갖는 여러 치환 퓨란에 대해 양성자 친화도를 조사하였다. 그 결과 전자를 주는 기는 퓨란의 양성자 친화도를 증가시키는 반면 전자를 끄는 기는 양성자 친화도를 감소시켰으며, 이 결과 치환 퓨란의 산소 원자의 atomic charge와 전자밀도로 설명할 수 있었다

• Earthquakes and Structures
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• 제8권3호
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• pp.699-712
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• 2015

Bracing structures with off-centre bracing system is one of the new resistant systems that frequently used in the frame with pin connections. High ductility, high-energy dissipation and decrease of base shear are advantages of this bracing system. However, beside these advantages, reconstruction and hard repair of off-centre bracing system cause inappropriate performance in the earthquake. Therefore, in this paper, the goal is investigating the behavior of this type of bracing system with ductile element (circular dissipater), in order to providing replacement of damaged member without needing repair or reconstruction of the general system. To achieve this purpose, some numerical studies have been performed using ANSYS software, a frame with off-centre bracing system and optimum eccentricity (OBS-C-O) and another frame with the same identifications without ductile element (OBS) has been created. In order to investigate precisely on the optimum placement of circular elements under monotonic load again three steal frames were modeled. Furthermore, the behavior of this general system investigated for the first time, linear and nonlinear behavior of these two steel frames compared to each other, to achieve the benefit of using the circular element in an off-centre bracing system. Eventually, the analytical results revealed that the performance of steel ring at the end of off-centre braces system illustrating as a first defensive line and buckling fuse in the off-centre bracing system.

• 보존과학연구
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• 통권20호
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• pp.139-154
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• 1999

We tested to obtain the excellent Epoxy resins on the property of matter. Existing Epoxy resins is tested to regulate the viscosity, color and hardening time etc. Benzen-ring structure of Bisphenol A type (AY 103) is replaced by Hydrogenated B.P.A type. And hardener is replaced by Polyoxyalkylene Amine. So we are developed into the two resins(L-30, L-40).To know if this Epoxy resins was fitted to repairing and restoration of stone cultural properties. Three kinds of Epoxy resins (AY 103, L-30, L-40) are tested on the artificial weathering test, freezing-melting test, exposure test etc. As a result of test, L-30 is less the discoloration than that of other Epoxy resins and was superior to the excellent property of matter.