• Applied Chemistry for Engineering
• /
• v.20 no.3
• /
• pp.279-284
• /
• 2009

The formation of mesoporous pores in the microporous mordenite crystals was performed by controlled silica extraction on alkaline treatment. Inner tunable mesopore size could be controlled by changing the concentration of alkaline solution. The pore structure of mordenite zeolite was studied by instrumental analysis after alkaline-treatment. To obtain the cage type mesopores, Ti-coating on the ourside mordenite crystals before alkaline treatment was investigated to be the most effective. Polymeric chiral salen Co (III) complexes were successfully encapsulated in mesoporous mordenite zeolite by "ship-in-a-bottle" method. The heterogeneous catalyst could be applied in asymmetric ring opening of epichlorohydrine by water. It showed very excellent enantioselectivity with a high yield in the catalysis.

• Polymer(Korea)
• /
• v.32 no.2
• /
• pp.143-149
• /
• 2008

We synthesized PEG-PLA (or PLGA) amphiphilic di-block copolymers, which consist of PEG as biocompatible and hydrophilic block and PLA (or PLGA) as biodegradable and hydrophobic block, by ring opening polymerization of LA in the presence of methoxy PEG as a macroinitiator. The compositions and the molecular weights of the copolymers were controlled by changing the feed ratio of LA (and GA) to PEG initiator. The di-block copolymers could self-assemble in aqueous media to form micellar structure. A hydrophobic model drug, pioglitazone, was loaded into the polymer micelle using solid dispersion and dialysis methods, and the drug-loaded micelles were characterized by AFM, DLS and HPLC measurements. The drug loading capacity and in vitro release studies were performed and evaluated under various conditions. These results indicated that the amphiphilic di-block copolymers of PEG-PLA (or PLGA) could solubilize pioglitazone by solid dispersion method and the drug release was modulated according to micellar chemical compositions.

• Journal of the Korean Chemical Society
• /
• v.39 no.7
• /
• pp.493-500
• /
• 1995

The geometry optimization of oxazole, relevant to the binding of lexitropsin that contains this ring to the base pair (G-C sequence) of minor groove of DNA, is performed with the aid of MM+ and ab initio (Hartree-Fock) calculations. The proton affinity and electronic structure are calculated at the 6-31G and $6-31G^{\ast}$ level for the optimized geometry. The proton affinities are also studied for various substituted oxazoles with the electron-donating and -withdrawing groups to estimate the substituent effect on the proton affinities of oxazoles. It is shown that the electron-donating substituents increase the proton affinity of oxazole, while the electron-withdrawing substituents decrease it. This result can be explained with atomic charge and electron density at oxygen of substituted oxazoles.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.15 no.1
• /
• pp.575-580
• /
• 2014

The liquid crystalline copolymers were synthesized through direct polycondensation using 4-[4-(4-hydroxyphenoxy)butoxy]benzoic acid (HBBA) and p-hydroxy benzoic acid (HBA) as monomers. The structure and properties for synthesized copolymers were investigated by $^1H$-NMR, FT-IR, differential scanning calorimetry (DSC), thermogravimetry analysis (TGA) and polarizing optical microscope (POM). As result of investigations, inherent viscosities (${\eta}_{inh}$) of polymers were measured as 0.77~1.60 dL/g in phenol/p-chlorophenol/1,1,2,2-tetrachloroethane (25/40/35=w/w/w). Except for P-80, the ranges of the transition and mesophase temperature of copolymers were increased with increasing the amount of HBA. These properties of polymers were presumably due to increasing of the irregularity and rigidity of polymer chains.

• Journal of the Korean Chemical Society
• /
• v.55 no.3
• /
• pp.354-363
• /
• 2011

Quantum-chemistry study was explored to investigate the electronic structures, absorption and phosphorescence mechanism, as well as electroluminescence (EL) properties of three red-emitting Ir(III) complexes, $(fpmqx)_2Ir$(L) {fpmqx=2-(4-fluorophenyl)-3-methyl-quinoxaline; L=triazolylpyridine (trz) (1); L=picolinate (pic) (2) and L=acetylacetonate (acac) (3)}. The calculated results show that the HOMO distribution for 1 is mainly localized on trz moiety due to its stronger ${\pi}$-electron acceptor ability, and HOMO for 2 and 3 is the combination of Ir d- and phenyl ring ${\pi}$-orbital. The higher phosphorescence yields and differences among 1-3 are investigated in this paper. In addition, the reasons of higher EL efficiency of 2 than 1 and 3 have been rationalized.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.6
• /
• pp.1141-1148
• /
• 2008

Geometry optimizations and electronic structure calculations are reported for meso-tetraphenyl porphyrin (TPP) and a series of meso-substituted catecholic porphyrins (KP99150, KP99151, KP99152, KP99153, and KP99090) using density functional theory (DFT). The calculated B3LYP//RHF bond lengths are slightly longer than those of LSDA//RHF. The calculated electronic structures clearly show that TPP and meso-catecholic group contribute to π-electron conjugation along porphyrin ring for HOMO and LUMO, significantly reduced the HOMO-LUMO gap. The wavelength due to B3LYP energy gaps is favored with experimental value in Soret (B), and LSDA energy gaps are favored with experimental value in visible bands (Q). The electronic effect of the catecholic groups is to reduced energies of both the HOMOs and LUMOs. However, the distortion of porphyrin predominantly raises the energies of the HOMOs, so the net result is a large drop in HOMO and smaller drop in LUMO energies upon meso-substituted catecholic group of the porphyrin macrocycle as shown in KP99151 and KP99152 of Figure 5(a). These results are in reasonable agreement with normal-coordinate structural decomposition (NSD) results. The HOMO-LUMO gap is an important factor to consider in the development of photodynamic therapy (PDT).

• Proceedings of the IEEK Conference
• /
• 2005.11a
• /
• pp.857-860
• /
• 2005

We reported 94 GHz, low conversion loss, and high isolation single balanced active-gate mixer based on 70 nm gate length InGaAs/InAlAs metamorphic high electron mobility transistors (MHEMTs). This mixer showed that the conversion loss and isolation characteristics were 2.5 ${\sim}$ 2.8 dB and under -30 dB, respectively, in the range of 93.65 ${\sim}$ 94.25 GHz. The low conversion loss of the mixer is mainly attributed to the high-performance of the MHEMTs exhibiting a maximum drain current density of 607 mA/mm, a extrinsic transconductance of 1015 mS/mm, a current gain cutoff frequency ($f_t$) of 330 GHz, and a maximum oscillation frequency ($f_{max}$) of 425 GHz. High isolation characteristics are due to hybrid ring coupler which adopted dielectric-supported air-gapped microstrip line (DAML) structure using surface micromachined technology. To our knowledge, these results are the best performance demonstrated from 94 GHz single balanced mixer utilizing GaAs-based HEMTs in terms of conversion loss as well as isolation characteristics.

• Journal of the Korea Furniture Society
• /
• v.29 no.1
• /
• pp.1-7
• /
• 2018

A study was carried out to observe the 1% aqueous safranine solution flow speed in longitudinal and radial directions of softwood Metasequoia glyptostroboides, diffuse-porous wood Anthocephalus cadamba and ring-porouswood Fraxinus rhynchophylla. In radial direction, ray cells and in longitudinal direction, tracheids, vessel and wood fiber were considered for the measurement of liquid penetration speed at less than 12% moisture contents (MC). The length, lumen diameter, pit diameter, end wall pit diameter and the numbers of end wall pits determined for the flow rate. The liquid flow in the those cells was captured via video and the capillary flow rate in the ones were measured. Vessel in hardwood species and tracheids in softwood was found to facilitate prime role in longitudinal penetration. Anatomical features like the length and diameter, end-wall pit numbers of ray parenchyma were found also responsible fluid flow differences. On the other hand, vessel and fiber structure affected the longitudinal flow of liquids. Therefore, the average liquid penetration depth in longitudinal tracheids of Metasequoia glyptostroboides was found the highest among all cells considered in Anthocephalus cadamba and Fraxinus rhynchophylla In radial direction, ray parenchyma of Metasequoia glyptostroboides was found the highest depth and the one of Fraxinus rhynchophylla was the lowest. The solution was penetrated lowest depth in the wood fiber of Fraxinus rhynchophylla. The large vessel of Fraxinus rhynchophylla was found the lowest depth among the vessels. The solutin was penetrated to the wood fiber of Anthocephalus cadamba higher than the one of Fraxinus rhynchophylla.

• The Proceeding of the Korean Institute of Electromagnetic Engineering and Science
• /
• v.2 no.2
• /
• pp.19-24
• /
• 1991

This paper propose a new taegeuk shaped directional couper and verify the possibility of high power division rate in those directional coupler through the experiments. We took the taegeuk shaped structure in those proposed directional coupler to utilize a $3\lambda/4$ section of hybrid ring directional coupler actively, and calculated the branch admittances, which satisfied the condition of perfect matching and isolation in the center frequency, by even odd mode analyzing methodes. On the result, we knew that it can be realized a much higher power division rate than reported result in same circuit area within the producible resistance limit in the microstrip line, made the taegeuk shaped directional couplers with 0, 8, 16 dB power split ratio in the 10 GHz frequency using CGP - 502 plate, and confirmed the validity of theory through the experiments.

• The Korean Journal of Quaternary Research
• /
• v.14 no.1
• /
• pp.57-63
• /
• 2000

A simulation model was used to examine the effects of climate variation on the tree-ring structure of Larix leptolepis trees growing at a plantation plot in Worak National Park in central Korea. The model uses mathematical equations to simulate processes affecting cell(tracheid) size variations for individual rings using daily precipitation and temperature measurements. Limiting conditions are estimated from temperature, day length and a calculated water balance. The results indicate that the seasonal growth is mostly limited by the soil moisture content and precipitation income during April and May. The April-May temperature also inversely influences the growth by increasing water losses from soil. The global climate-change scenario which includes regional warming(increasing temperature in spring-summer periods) appears to decrease the duration of optimal growths. Consequently, the model estimated that Larix leptolepis would lose the total production of xylem by 25%.