• Title/Summary/Keyword: ring structure

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Evaluating the performance of OBS-C-O in steel frames under monotonic load

  • Bazzaz, Mohammad;Andalib, Zahra;Kafi, Mohammad Ali;Kheyroddin, Ali
    • Earthquakes and Structures
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    • v.8 no.3
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    • pp.699-712
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    • 2015
  • Bracing structures with off-centre bracing system is one of the new resistant systems that frequently used in the frame with pin connections. High ductility, high-energy dissipation and decrease of base shear are advantages of this bracing system. However, beside these advantages, reconstruction and hard repair of off-centre bracing system cause inappropriate performance in the earthquake. Therefore, in this paper, the goal is investigating the behavior of this type of bracing system with ductile element (circular dissipater), in order to providing replacement of damaged member without needing repair or reconstruction of the general system. To achieve this purpose, some numerical studies have been performed using ANSYS software, a frame with off-centre bracing system and optimum eccentricity (OBS-C-O) and another frame with the same identifications without ductile element (OBS) has been created. In order to investigate precisely on the optimum placement of circular elements under monotonic load again three steal frames were modeled. Furthermore, the behavior of this general system investigated for the first time, linear and nonlinear behavior of these two steel frames compared to each other, to achieve the benefit of using the circular element in an off-centre bracing system. Eventually, the analytical results revealed that the performance of steel ring at the end of off-centre braces system illustrating as a first defensive line and buckling fuse in the off-centre bracing system.

Studies on the epoxy resins of stone cultural properties (석조문화재 에폭시수지 개발 시험 연구)

  • Kim, Sa-Dug;Kim, Soon-Kwan;Kim, Chang-Suk;Hong, Jung-Ki;Kang, Dai-Il;Lee, Myong-Hee
    • 보존과학연구
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    • s.20
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    • pp.139-154
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    • 1999
  • We tested to obtain the excellent Epoxy resins on the property of matter. Existing Epoxy resins is tested to regulate the viscosity, color and hardening time etc. Benzen-ring structure of Bisphenol A type (AY 103) is replaced by Hydrogenated B.P.A type. And hardener is replaced by Polyoxyalkylene Amine. So we are developed into the two resins(L-30, L-40).To know if this Epoxy resins was fitted to repairing and restoration of stone cultural properties. Three kinds of Epoxy resins (AY 103, L-30, L-40) are tested on the artificial weathering test, freezing-melting test, exposure test etc. As a result of test, L-30 is less the discoloration than that of other Epoxy resins and was superior to the excellent property of matter.

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NMR Studies of Zinc-binding Luteinizing Hormone Releasing Hormone

  • Kim, Dae-Sung;Lee, Mi-Sun;Lee, Chang-Jun;Won, Ho-Shik
    • Journal of the Korean Magnetic Resonance Society
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    • v.10 no.2
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    • pp.163-174
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    • 2006
  • Luteinizing Hormone Releasing Hormone(LHRH) is a decapeptide neurotransmitter known to be regulated by metal ions in the hyperthalamus. Zn-binding LHRH complex was systhesized, and zinc-LHRH complex was studied to understand what kinds of structural modifications would be critical in the LHRH releasing mechanism. Both nonexchangeable and exchangeable $^1H-NMR$ signal assignments were accomplished by pH-dependent and COSY NMR experiments. In addition, $^1H-NMR$ chemical shift changes of a-proton and peptide NH NMR signals at different pH condition, and $^1H-NMR$ signal differences between metal free and metallo-LHRH complex was monitored. NMR signals exhibit that primary metal-binding sites are nitrogens donor of imidazole ring and Arg, and peptide oxygen of Pro-His in the sequence. Structure obtained in this study has a cyclic conformation which is similar to that of energy minimized, and exhibits a specific a-helical turn with residue numbers $(2{\sim}7)$ out of 10 amino acids.

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Plasma-polymerized Styrene Prganic thin Film as Hybrid OLEDs Encapsulation (플라즈마 중합된 Styrene을 유기박막으로 사용한 하이브리드형 OLED 봉지기술)

  • Jung, Kun-Soo;Lee, Boong-Joo;Shin, Paik-Kyun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.63 no.10
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    • pp.1412-1416
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    • 2014
  • We report thin-film organic moisture barriers based on polystyrene(PS) laminates deposition by PECVD for an encapsulation of OLEDs. The organic polystyrene thin-film has the benzene ring structure and high hydrophobic characteristics and it was polymerized by PECVD in dry process. Life time properties of Ca test were obtained 32 minutes at the RF 100W process conditions. From the AFM test, the roughness of multi-layer thin-film was more excellent rather than that of a single-layer thin-film. In addition, 5 layers of the multi-layer film properties were obtained 45 minutes. So that the optical and electrical properties were not affected with these plasma polymerized organic thin-film encapsulation. For life time improvement, the inorganic $Al_2O_3$ thin-film were deposited 5nm using ALD atomic layer deposition. The WVTR(Water Vaper Transmission Rate) value of hybrid thin-film encapsulation in the optimum process conditions was resulted by less than $10-3g/m^2/day$. From the results of experiment, plasma polymerized hybrid encapsulation was suggested as the flexible display applications.

Synthesis and Thermal Property of Poly(styrene-g-caprolactone) with Well-defined Structure (분자구조가 제어된 Poly(styrene-g-caprolactone)의 합성 및 그라프트 공중합체의 열적 성질)

  • 오병석;안성국;조창기
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.306-313
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    • 2000
  • Polycaprolactone (PCL) macromer containing terminal methacrylate group was synthesized by ring-opening polymerization. The number average molecular weight of PCL macromer was 11600 g/mole and polydispersity index was 1.09. The synthesized PCL macromer was copolymerized with styrene by stable free radical polymerization using 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO), benzoyl peroxide, and well-defined poly(styrene-g-caprolactone)s were synthesized. The synthesized copolymers was characterized by $^1$H-NMR and gel permeation chromatography equipped with multiangle laser light scattering detector. Thermal properties of graft copolymers were investigated by DSC.

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Photosensitive Polyimides Having Aromatic Sulfonyloxyimide Groups in the Main Chain (주쇄에 광분해성 방향족 술포닐옥시이미드기를 함유한 감광성 폴리이미드)

  • 오세용;이지영;조성열;정찬문
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.407-417
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    • 2000
  • Photosensitive polyimides having cyclobutane or phenyl and aromatic sulfonyloxyimide units in the main chain have been synthesized and the photodegradation behavior was investigated in relation with the polymer structure. The polyimides were prepared by condensation polymerization of N-hydroxyl and sulfonyl chloride. The prepared polyimides were stable up to 25$0^{\circ}C$ without thermal degradation. It has been found that the photodegradation of polyimides upon irradiation of 254 nm UV light results from scission of N-O bonds or ring opening of imides moiety by spectroscopic measurements. The polyimides were useful as positive working photodegradable polymers. Especially, the positive tone image of polyimide containing a pyromellitic diimide moiety exhibited high sensitivity and resolution.

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The Dynamic Characteristics and Defect Analysis of Pressurized Water Reactor Internals (원자로 내부구조물의 동특성 및 결함해석)

  • Ahn, Chang-Gi;Park, Jin-Ho;Lee, Jeong-Han;Chae, Young-Chul;Song, Oh-Seop
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2005.11a
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    • pp.267-270
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    • 2005
  • Finite element model of pressurized water reactor internals were obtained using ANSYS software package to analyze dynamic characteristics. The pressure vessel, hold-down ring, alinement key, core support barrel(CSB), upper guide structure(UGS) and fluid gap were fully modeled using structural solid element(SOLID45) and fluid element(FLUID80) which is one of element types. Also modal analysis using the above finite element model has been performed. As a result, it was found that the fundamental beam mode natural frequency of the CSB were 8.2 Hz, the shell mode one 14.5 Hz. To verify the Finite Element Analysis(FEA), we compare the analysis result with experimental data that is obtained from the plant IVMS(internal Vibration Monitoring System). The experimental results are good agreement with the FEA model.

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Deposition of Amorphous Carbon Layer by PECVD (PECVD에 의한 비정질 탄소층 증착)

  • Jung, Ilhyun
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.322-325
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    • 2008
  • 3,3-Dimethyl-1-butene ($C_6H_{12}$) monomer was deposited using a plasma-enhanced chemical vapor deposition (PECVD) instrument. The more the R.F. power/pressure ratio in FT-IR spectrum, the less the hydrogen quantity and the dangling bond in amorphous carbon films observed so that the mechanical property of the films are improved related to the density. Also, with the increase D peak in Raman spectrum is increased and the ring structure's films are produced. According to these results, hardness and modulus are 12 GPa and 85 GPa, respectively. The refractive index (n) and extinction coefficients (k) of the deposited films are increased with the increase in a power/pressure ratio.

Effects of the gold nanoparticles including different thiol functional groups on the performances of glucose-oxidase-based glucose sensing devices

  • Christwardana, Marcelinus;Chung, Yongjin;Tannia, Daniel Chris;Kwon, Yongchai
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2421-2429
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    • 2018
  • Thiol-based self-assembled anchor linked to glucose oxidase (GOx) and gold nanoparticle (GNP) cluster is suggested to enhance the performance of glucose biosensor. By the adoption of thiol-based anchors, the activity of biocatalyst consisting of GOx, GNP, polyethyleneimine (PEI) and carbon nanotube (CNT) is improved because they play a crucial role in preventing the leaching out of GOx. They also promote electron collection and transfer, and this is due to a strong hydrophobic interaction between the active site of GOx and the aromatic ring of anchor, while the effect is optimized with the use of thiophenol anchor due to its simple configuration. Based on that, it is quantified that by the adoption of thiophenol as anchor, the current density of flavin adenine dinucleotide (FAD) redox reaction increases about 42%, electron transfer rate constant ($k_s$) is $9.1{\pm}0.1s^{-1}$ and the value is 26% higher than that of catalyst that does not use the anchor structure.

Characteristics of Typhoon Jelawat Observed by OSMI, TRMM/PR and QuikSCAT

  • Lim, Hyo-Suk;Choi, Gi-Hyuk;Kim, Han-Dol
    • Korean Journal of Remote Sensing
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    • v.16 no.4
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    • pp.293-303
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    • 2000
  • The typhoon Jelawat, which was formed over the tropical Pacific ocean on August 1, 2000 and made a landfall over China on August 10, 2000, was observed by Korea Multi-purpose Satellite (KOMPSAT-1) Ocean Scanning Multispectral Imager (OSMI), Tropical Rainfall Measuring Mission (TRMM)/Precipitation Radar(PR) and Quick Scatterometer (QuikSCAT). In spite of discontinuous observation, important mesoscale features of typhoon depending on life cycle were detected prominently. It is possible to distinguish on the OSMI photograph between the eye-wall convection and the stratiform and other convective clouds near the center of typhoon Jelawat. The TRMM/PR observations show quite clearly the eye-wall convection, stratiform regions, and convective bands. Vertical cross section of rainfall in the genesis stage of typhoon Jelawat exhibits circular ring of intense convection surrounding the eye. The mature stage of typhoon Jelawat consists of a strong rotational circulation with clouds which are well organized about a center of low pressure. The OSMI, TRMM/PR and QuikSCAT measurements presented here agree qualitatively with each other and provide a wealth of information on the structure of typhoon Jelawat.