• Title/Summary/Keyword: rheology behavior

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Non-isothermal Effect on the Flow Behavior of Polymer Melts in a Coextrusion Die (고분자의 Coextrusion에서 유동에 대한 비등온 효과)

  • 정인재
    • The Korean Journal of Rheology
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    • v.6 no.2
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    • pp.129-138
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    • 1994
  • 공압출되는 sheet die에서 고분자 물질의 비등온 유동유동을 수치모사하였다. 유변학 적 식으로 power-law model을 사용하였고, 격자생성법을 이용한 유한차분법을 사용하였다. 수치계산을 통해 수축채널에서의 온도 분포를 구해보고 점도가 채널에서의 온도 분포를 구 해 보고 점도가 채널에서의 압력강하 및 신장속도에 미치는 영향을 알아보았다. 압력강하는 외부 유체의 점도 및 heat dissipation의 영향을 크게 받았다. 신장속도는 외부 유체의 점도 가 증가함에 따라 커진 반면 내부 유체의 점도가 증가함에 따라 커진반면, 내부 유체의 점 도증가에 따라 감소하였고, heat dissipation에 의해 증가하였다.

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Effects of dissolution temperature on the rheological properties of polyvinyl alchol solutions in dimethyl sulfoxide

  • Cho, Yong-Han;Dan, Kyung-Sik;Kim, Byoung-Chul
    • Korea-Australia Rheology Journal
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    • v.20 no.2
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    • pp.73-77
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    • 2008
  • The rheological properties of polar solutions are very sensitive to preparative methods as well as measuring conditions. The effects of dissolution temperature on the rheological properties of the solutions of polyvinyl alcohol (PVA) in dimethyl sulfoxide were investigated over the range of dissolution temperatures $70-130^{\circ}C$. Viscosity was increased as dissolution temperature was increased. PVA solutions prepared at 120 and $130^{\circ}C$ showed Bingham behavior, which became less noticeable with decreasing dissolution temperature. The modified Cole-Cole plot of the solutions gave slope less than 2, suggesting the solutions were a heterogeneous system irrespective of optical transparency. Further, the slope was decreased with increasing dissolution temperature, indicating that the solid character got more prominent as dissolution temperature was increased. However, the relaxation time of the solutions was little dependent on dissolution temperature.

Silicate dispersion and rheological properties of high impact polystyrene/organoclay nanocomposites via in situ polymerization

  • Kim, Byung-Chul;Lee, Seong-Jae
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.227-233
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    • 2008
  • High impact polystyrene (HIPS)/organoclay nanocomposites via in situ polymerization were synthesized and their rheological properties were investigated. For the study, two types of organoclays were used: a commercially available organoclay, Cloisite 10A (C10A), and a laboratory-prepared organoclay having a reactant group, vinylclay (ODVC). The X-ray diffraction and transmission electron microscopy experiments revealed that the HIPS/ODVC nanocomposite achieved an exfoliated structure, whereas the HIPS/C10A nanocomposite achieved an intercalated structure. In the small-amplitude oscillatory shear experiments, both storage modulus and complex viscosity increased with increasing organoclay. A pronounced effect of the organoclay content was observed, resulting in larger storage modulus and stronger yield behavior in the low frequency region when compared to neat HIPS. The crossover frequencies associated with the inverse of a longest relaxation time decreased as the organoclay content increased. Over a certain value of ODVC content, a change of pattern in rheological properties could be found, indicating a solid-like response with storage modulus greater than loss modulus at all frequencies.

Influence of temperature, time, and moisture content on rheology of tomatoes and pepper purees

  • Adeshina Fadeyibi;Zainab Ololamide Ayinla;Rasaq A. Ajiboye
    • Food Science and Preservation
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    • v.31 no.2
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    • pp.199-209
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    • 2024
  • This study explored how temperature, time, and moisture content affect the rheological properties (apparent viscosity, flow behavior index, and consistency coefficient) of stored tomato and pepper purees. These purees were prepared with moisture contents of 85%, 90%, and 95% (w/v) using the hot-break method and tested over 6 days at 2-day intervals and temperatures of 5℃, 10℃, and 15℃. Results displayed distinct ranges for apparent viscosity, consistency coefficient, and flow behavior indices: tomato puree (2,519.9-4,324.6 mPa·s, 258.0-550.6 mPa·Sn, 1.80-0.48) and pepper puree (2,105.6-4,562.0 mPa·s, 268.4-580.4 mPa·Sn, 0.22-0.48). The temperature and storage time had significant (p≤0.05) effects, but moisture content did not affect these properties. Flow behavior and consistency coefficients demonstrated relative variation with apparent viscosity, indicating pseudoplastic behavior. Optimal processing and storage conditions were identified within specific ranges: 13.21-14.42℃ for 2 days with 92.22-94.23% (w/v) moisture content for pepper, and 8.42-11.77℃ for 2-6 days with 85% (w/v) moisture for tomato.

Cast cake rheology of ash-clay

  • Lee, K.G.;Kim, Y.T.;Kim, J.H.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.41-44
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    • 1997
  • Dispersion and flocculation behaviors of clay-ash powders in a slurry state were examined, and we have systematically investigated the effects of colloid/interfaces variables on slip properties and the rheological behavior of ash-clay slurry. Ash-clay slurries have been characterized on the basis of the time dependent rheology which was done out by the gel-curve test. Gel-curve for the coagulated slip shows interesting rheological behavior which was caused by the formation of the new network structure and the readsoption of the polysilicon hydroxo species on the particle surfaces.

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