• Title/Summary/Keyword: rheological properties

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Rheological Properties of Cement Paste Containing Ultrafine Blastfurnace Slag (초미분말 고로슬래그를 혼합한 시멘트 페이스트의 유동특성)

  • You, Chang-Dal;Byun, Seung-Ho;Song, Jong-Taek
    • Journal of the Korean Ceramic Society
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    • v.44 no.8
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    • pp.430-436
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    • 2007
  • Rheological properties of cement paste containing ultrafine blastfurnace slag (UBS, $9600cm^2/g$) were investigated by mini-slump test, pH meter, conduction calorimeter and coaxial cylinder viscometer. In order to improve rheological properties of the cement paste, granulated blastfurnace slag (GBS, $3500cm^2/g$) and polycarboxylate type superplasticizer (PC) were also used in this experiment. The fluidity of cement paste containing UBS was decreased. The yield stress and plastic viscosity of cement paste was increased with increasing UBS. But the rheological properties were improved when GBS and PC were added to UBS blended cement paste. In the relationship between the yield stress and the plastic viscosity or the mini-slump value, the yield stress of the cement paste was proportional to the plastic viscosity of it. However the cement paste mini-slump value was in inverse proportional to the yield stress.

A new method to estimate rheological properties of lubricating layer for prediction of concrete pumping

  • Jang, Kyong Pil;Kim, Woo Jae;Choi, Myoung Sung;Kwon, Seung Hee
    • Advances in concrete construction
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    • v.6 no.5
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    • pp.465-483
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    • 2018
  • The most crucial factor determining the pumping performance of concrete is the characteristics of the lubricating layer formed between the pipe wall and the inner concrete. Thus, it is important to accurately identify the rheological properties of the lubricating layer to predict the pumping of concrete. In this study, a new method is proposed for measuring the rheological properties of the lubricating layer with improved convenience. To verify the new method, a pumping test was conducted with 337 m-long horizontal piping. The rheological properties of the lubricating layer were assessed by a previously verified method and the new method proposed in this study for a total of four concrete mixtures with design strength ranging from 27 MPa to 60 MPa. The correlation between the existing method and the new method in relation to the viscosity of the lubricating layer was determined, and it was possible to predict the pumping performance with an accuracy of about 88.5% using the viscosity of the lubricating layer obtained from this correlation.

Effect of Gum Addition on the Rheological Properties of Rice Flour Dispersions

  • Chun, So-Young;Kim, Hyung-Il;Yoo, Byoung-Seung
    • Food Science and Biotechnology
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    • v.15 no.4
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    • pp.589-594
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    • 2006
  • The effect of five commercial gums (carboxylmethylcellulose, CMC; guar gum, GG; hydroxypropylmethyl-cellulose, HPMC; locust bean gum, LBG; and xanthan gum) at a concentration of 0.25% on the rheological properties of rice flour (RF) dispersions was investigated in steady and dynamic shear. The steady shear rheological properties showed that RF gum mixture dispersions (5%, w/w) at $25^{\circ}C$ had high shear-thinning flow behavior (n=0.20-0.31) exhibiting a yield stress. Magnitudes of consistency index (K), apparent viscosity (${\eta}_{a,100}$), and Casson yield stress (${\sigma}_{oc}$) of RF-gum mixtures were much higher than those of RF dispersion with no added gum (control). Activation energy values (6.67-10.8 kJ/mole) of RF-gum mixtures within the temperature range of $25-70^{\circ}C$ were lower than that (11.9 kJ/mole) of the control. Dynamic rheological data of log (G', G") versus log frequency (${\omega}$) of RF-gum mixtures had positive slopes (0.15-0.37) with G' greater than G" over most of the frequency range (0.63-63 rad/sec), demonstrating a frequency dependency. Tan ${\delta}$ (G"/G') values of RF-gum mixtures, except for xanthan gum, were much higher than that of the control.

Rheological Properties of Binder Pastes for Self-Compacting Concrete

  • Park, Yon-Dong
    • KCI Concrete Journal
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    • v.13 no.1
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    • pp.35-41
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    • 2001
  • This paper investigated rheological properties of binder pastes for self-compacting high performance concrete. Six mixtures of self-compacting concrete were initially prepared and tested to estimate self-compacting property. Then, the binder pastes used in self-compacting concrete were tested for rheological properties using a rotary type rheometer. Binder pastes with different water-binder ratios arid flow values were also examined to evaluate their rheological characteristics. The binders were composed of ordinary Portland cement, fly ash, two types of pulverized blast-furnace slag, and limestone powder. The flow curves of binder pastes were obtained by a rotary type rheometer with shear rate control. Slump flow, O-funnel time, box, and L-flow teats were carried out to estimate self-compacting property of concrete. The flow curves of binder pastes for self-compacting concrete had negligible yield stresses and showed an approximately linear behavior at higher shear rates beyond a certain limit. Test results also indicated that the binders incorporating fly ash are more appropriate than the other types of binders in quality control of self-compacting concrete.

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Effect of Precured EPDM on the Property of Magneto-rheological Elastomer Based on NR/EPDM Blend

  • Na, Bokgyun;Chung, Kyungho
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.67-74
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    • 2018
  • Magneto-rheological elastomers (MREs) are smart materials in which the inherent stiffness and damping properties can be changed by the influence of an external magnetic field. The magneto-rheological (MR) effect depends on the orientation characteristics of the dispersed magneto-responsible particles (MRPs) in the matrix. In this study, natural rubber (NR) and ethylene propylene diene rubber (EPDM) were blended and used as a matrix of an MRE. EPDM was pre-cured before blending with NR. The Mooney viscosity, curing characteristics, and mechanical properties were analyzed with various pre-curing conditions of EPDM and the NR/EPDM blend. The results show that excellent mechanical properties of the NR/EPDM blend-based MRE were obtained when the pre-curing time of EPDM was 60 min. The aging property of the NR-based MRE was improved by the introduction of pre-cured EPDM. Also, the anisotropic MRE showed a higher MR effect than that of the isotropic MRE.

RHEOLOGICAL PROPERTIES OF OIL/WATER EMULSION AND OIL/LIQUID CRYSTAL/WATER SYSTEMS AND THEIR CONSUMER PERCEPTION IN HAIR CARE PRODUCTS

  • Kim, Chong-Youp;Hong, Jong-Eoun;Kim, Su-Hyun;Kang, Hak-Hee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.25 no.4 s.34
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    • pp.123-131
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    • 1999
  • Liquid crystal known as a rheological barrier to coalescence of oil droplets, increases emulsion stability, water-holding capacity and promotes active material penetration to skin. Some investigation for its rheological characteristics have been reported but its relations to consumer perception have been rarely published. In this study, oil/water emulsion and oil/liquid crystal/water systems were manufactured using the same composition or Behenyltrimethylammonium chloride/Cetostearyl alcohol/Lanolin oil. and rheological properties or each system were investigated with Cone and Plate rheometer. The formation of liquid crystalline phase was observed with polarized microscope and Differential Scanning Calorimeter. Continuous shear experiment, creep, yield and water holding capacity were measured for oil/water and oil/liquid crystal/water systems. The results were compared with sensory evaluations. Oil/liquid crystal/water system showed higher,viscosity at the same shear rate. higher viscoelasticity and higher yield stress than oil/water system. These properties were expected to show good spreadability and excellent richness without waxiness in hair can: products of creme type. This expectation was consistent with the results of sensory experiments. Water-holding capacity was evaluated by measuring residual water of specimens at specific temperature and relative humidity. Oil/liquid crystal/water system was proved to have higher ability to hold water in comparison with oil/water system. The results indicated that oil/liquid crystal/water system was of benefit to rheological properties creme type hair care products.

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Processibility of High Ductile Fiber-Reinforced ECCs (Engineered Cementitious Composites) (고인성 섬유복합재료 ECC (Engineered Cementitious Composite)의 시공성)

  • Kim Yun Yong;Kim Jeong-Su;Kim Jin-Keun;Ha Gee-Joo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.313-316
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    • 2005
  • In the recent design of high ductile fiber-reinforced cementitious composite ECC, which exhibits tensile strain-hardening behavior in the hardened state, optimizing both processing mechanical properties for specific applications is critical. This study introduced a method to develop useful ECCs in field, which possess the different fluid properties to facilitate diverse types of processing (i.e., self-consolidating or spray processing). Control of rheological modulation was regarded as a key factor to allow the performance of the desired processing, while retaining the ductile material properties. To control the rheological properties of the composite, we first determined basic ECC compositon, which is based on micromechanics and steady-state cracking theory. The stability and consequent viscosity of suspensions were, then, mediated by optimizing dosages of chemical and mineral admixtures. The rheological properties altered by this approach were revealed to be effective in obtaining ECC hardened properties, allowing us to readily achieve the desired function of the fresh ECC.

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Effect of PCE superplasticizers on rheological and strength properties of high strength self-consolidating concrete

  • Bauchkar, S.D.;Chore, H.S.
    • Advances in concrete construction
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    • v.6 no.6
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    • pp.561-583
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    • 2018
  • A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.

Influence of Ice Recrystallization on Rheological Characteristics of Ice Slurries and Physicochemical Properties of Concentrated Milk

  • Park, Sung-Hee;Kim, Jee-Yeon;Hong, Geun-Pyo;Kwak, Hae-Soo;Min, Sang-Gi
    • Food Science and Biotechnology
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    • v.15 no.5
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    • pp.756-762
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    • 2006
  • Freeze concentration of milk was carried out through the controlled recrystallization of ice in a multi-stage freeze concentrator. Rheological characteristics of ice slurries were analyzed to determine efficient concentration levels for the freeze concentration process. It was determined that efficient concentration level was 17% of total solids in the first and 27% in the second stage. Physicochemical properties were compared between freeze concentrated and evaporated milk. Freeze concentrated milk was more similar in color appearance to control milk than was evaporated milk. pH significantly decreased in evaporated milk than in freeze concentrated milk. pH of freeze concentrated milk resulted in similar value to control. These results indicated the advantages of freeze concentration as a non-thermal milk processing technology in terms of physicochemical properties. Consequently, we investigated the influence of ice recrystallization on the rheological characteristics of ice slurries and physicochemical properties of freeze concentrated milk.

Improvement of Rheological Properties of Silica Composites Employing Response Surface Methodology (반응표면분석법을 이용한 실리카복합재료의 레올로지 속성 개선)

  • Yim, Gie-Hong;Yang, Seung-Nam;Kim, Nam-Ki
    • Polymer(Korea)
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    • v.32 no.1
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    • pp.19-25
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    • 2008
  • The purpose of this study was improving the rheology properties of dentifrice by finding optimum binders polymer system which consists of carboxymethylcellulose (CMC), carbomer, and Mg/Al silicate. Response surface methodology (RSM) was employed to investigate the correlation between polymers and rheological properties of dentifrice and to optimize responses. Rheological properties were measured with oscillatory rheometer. As a result, it was identified that gel strength and yield stress were dependent on contents of CMC and carbomer and CMC caused long stringiness of dentifrice. And springness of dentifrice was dependent on contents of CMC and Mg/Al silicate. Optimum components proportion of polymers and silicate were obtained by responses optimization process. According to determined optimum components proportion, it was possible to observe a dentifrice with improved rheological properties.