• Title/Summary/Keyword: rheological properties

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Effects of Irradiation of Electron Beam on the Rheological Properties of Poly(lactic acid) and Chemically Modified Poly(lactic acid) (전자선 조사가 Poly(lactic acid) 및 개질된 Poly(lactic acid)의 유변학적 특성에 미치는 영향)

  • Shin, Boo-Young;Kang, Kyoung-Su;Jo, Gyu-Soon;Han, Do-Hung;Song, Jeong-Sup;Lee, Sang-Il;Lee, Tae-Jin;Kim, Bong-Shik
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.269-272
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    • 2007
  • In this study, we investigated the effects of electron beam irradiation on the rheological properties of PLA for enhancing processability. The electron beam was irradiated onto the pure PLA, chemically modified PLA by reactive extrusion, and PLA containing functional monomer. The complex viscosity and log G'vs. log G" plot among dynamic rheological properties were chosen for comparison. The complex viscosity of irradiated pure and chemically modified PLA decreased significantly due to de-gradation of PLA molecules with increasing the E-beam dosages. Complex viscosity of irradiated PLA with functional monomer showed maximum value at moderate dosage, while at high dosage the complex viscosity was decreased by a prolonged irradiation.

Processing of Squeezed-Type Cockle Shell By-Product Paste (새조개 처리동결 가공부산물을 이용한 페이스트 젓갈 제조)

  • 배태진;강훈이
    • The Korean Journal of Food And Nutrition
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    • v.10 no.4
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    • pp.528-532
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    • 1997
  • A fermented squeezed-type paste was processed in order to highly effective utilization of cockle shell by-product, and improvement on rheological properties and texture of hydrolysate by used additives. The cockly shell by-products were homogenized with addition of water and enzymatically hydrolyzed at 5$0^{\circ}C$ for 8 hours added 4% Protease N.P.(Pacific Chemical Co.). And the hydrolysate was thermally treated for the purpose of flavor improvement, enzyme inactivation and pasteurization product at 10$0^{\circ}C$ for 1 hour, with 4% glucose. To make improvement of rheological properties, used complex additive with 0.5% alginic acid, 1% pectin and 0.2% agar were very effective. And stability of mixing was 98.1% after centrifuged at 10,000 rpm for 60 minutes. The chemical composition of moisture, total carbohydrate, total nitrogen and amino type nitrogen in the fermented squeeze-type cockle shell by-product paste were 57.7%, 20.6%, 1,458mg% and 1,187mg%, respectively. And the ratio of amino type nitrogen in total nitrogen was 81.4%.

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Rheological Properties of Dandelion Root Concentrates by Extraction Solvents

  • Lee, Ok-Hwan;Kang, Suk-Nam;Lee, Boo-Yong
    • Food Science and Biotechnology
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    • v.15 no.1
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    • pp.33-38
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    • 2006
  • This study was performed to provide basic rheological data of dandelion root concentrates in order to predict their processing aptitude and usefulness as functional foods material. The hot water and 70% ethanol extracts of dandelion root were concentrated at 5, 20, and 50 Brix, and their static viscosity, dynamic viscosity, and Arrhenius plots were investigated. Almost all hot water concentrates showed the typical flow properties of a pseudoplastic fluid, but evaluation using the power law model indicated that the 70% ethanol concentrates showed a flow behavior close to a Newtonian fluid. The apparent viscosity of hot water and 70% ethanol concentrates decreased with increasing temperature. Yield stresses of hot water and 70% ethanol concentrates by Herschel-Bulkley model application were in the range of 0.026 - 1.368 Pa and 0.022 - 0.238 Pa, respectively. The effect of temperature and concentration on the apparent viscosity was examined by Arrhenius equation. The activation energies of hot water and 70% ethanol concentrates were in the range of $8.762-23.778{\times}10^3\;J/mol{\cdot}kg$ and $3.217-20.384{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Storage (G') and loss (G") moduli were generally increased with increasing frequency. For the 70% ethanol concentrates, G" predominated over G' at all applied frequencies and so they showed the typical flow behavior of a low molecular solution. However, for the hot water concentrates, G' predominated over G" at more than 1.9 rad/sec (cross-over point) and so they showed the typical flow behavior of a macromolecular solution.

Rheological Properties of Fucoidans from Laminaria religiosa, Sporophylls of Undaria pinnatifida, Hizikia fusiforme and Sagassum fulvellum in Korea (국내산 다시마, 미역포자엽, 톳, 모자반 fucoidan의 리올리지 특성)

  • KOO Jae-Geun;JO Kil-Suk;PARK Jin-Hee
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.329-333
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    • 1997
  • Rheological properties of partially purified fucoidans of Laminaria religiosa, sporophylls of Undaria pinnatifida, Hizikia fusiforme, and Sargassum fulvellum in Korea were investigated, The fucoidans produced aqueous solutions of low apparent viscosity with pseudoplastic flow behavior. The viscosity of $5\%$ solution of the fucoidan from sporophylls of U. pinnatifida was 2.2 mPa.s. The activaton energies of L. religiosa, sporophylls of U. pinnatifida, H. fusiforme and S. fulvellum were $8.269\times10^6,\;7.498\times10^6,\;7.141\times10^6,\;and\;6.677\times10^6\;J/Kg.mol$ at 1,500 1/s of shear rate, respectively. The viscosity of the fucoidan solution was increased by the addition of sugar, but that was not changed by addition of NaCl.

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Rheological Properties of Gamma Irradiated Arrowroot (Pueraria thunbergina. B) Starch (감마선 조사 칡 전분 gel의 rheology 특성)

  • Kuhm, Herena;Lim, Jin-Hyuk;Lee, Eun-Ju;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
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    • v.36 no.5
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    • pp.740-743
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    • 2004
  • Rheological properties of gamma-irradiated arrowroot starch was examined to utilize as fundamental research data far processing. Irradiated arrowroot starch solutions (3, 4, 5, 6%) were gelatinized at $95^{\circ}C$ for 40 min, and its flow properties measured using rheometer at $30^{\circ}C$ and 10 to 200 rpm rotation rate. Rheological parameters of irradiated arrowroot starch gelatinized solution were calculated using Herschel-Bulkley equation. Gelatinized arrowroot starch solutions irradiated at $0^{\circ}C$ and 5kGy showed pseudoplastic fluid behavior, while those irradiated at 10, 20, and 30kGy were the dilatant with ${\tau}_y=0$ (yield stress).

Rheological Properties of Bread Dough Added with Flour Ferments by Seed Mash and Lactic Acid Bacteria (Seed Mash와 유산균 발효액을 첨가한 밀가루 반죽의 물성학적 특성)

  • Lee, Myung-Ku;Lee, Jeong-Hoon;Lee, Si-Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.3
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    • pp.346-351
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    • 2009
  • This study was carried out to determine the rheological properties of bread doughs containing flour-ferments prepared with seed mash obtained by Koji incubation, yeast, and lactic acid bacteria, using farinograph, extensograph, amylograph, and large scale-dough mixer. According to farinograph, the addition of the flour-ferments did not influence the water-absorption rate of doughs, regardless of the kinds of flour-ferments, however, it increased development time and decreased stability of doughs. According to extensograph, both dough resistance and resistance-to-extensibility ratio increased with the addition of flour-ferments. Especially the dough containing the flour-ferments prepared with seed mash, S. cerervisiae, and L. brevis showed the highest resistance-to-extensibility ratio. According to amylograph, although the doughs containing the flour-ferments did not show the differences in gelatinization temperature and temperature at maximum viscosity with the control which does not contain the flour-ferments, they showed lower maximum viscosity than the control. They also showed lower development value and faster development time.

Effect of Whey Brew Cultured by Lactobacillus helveticus ATCC 55163 and Propionibacterium acidipropionici 5020 on Rheological Properties of Flour Dough (Lactobacillus helveticus ATCC 55163과 Propionibacterium acidipropionici 5020로 배양한 유청발효물이 반죽의 레올로지에 미치는 영향)

  • Yun, Mi-Suk;Chae, Soo-Kyu;Lee, Jeong-Hoon
    • Culinary science and hospitality research
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    • v.15 no.1
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    • pp.149-156
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    • 2009
  • This study was carried out to evaluate the effect of whey brew cultured by the mixed Lactobacillus helveticus ATCC 55163 and Propionibacterium acidipropionici 5020 on the rheological properties of flour dough. 10 and 15% of whey brews were added to the dough based on flour. Farinograph, alveograph, Rapid Visco Analyzer, and fermenting power of dough were analyzed. In the farinograph analysis, as the amount of whey brews increased on dough samples, water absorption, dough development time, stability, and breakdown increased. In the alveograph analysis, as the amount of whey brews increased on dough samples, P and W value increased while L and G value decreased. In the Rapid Visco Analyzer analysis, as the amount of whey brews increased on dough samples, initial pasting temperature and peak viscosity increased while final viscosity and setback decreased. Decrease of setback showed the delay of starch retrogradation. As the amount of whey brews increased on dough samples, fermenting power of dough got reduced.

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Effect of Whey Ferment Cultured by L. acidophilus KCCM 32820 and P. freudenreichii KCCM 31227 on Rheological Properties of Bread Dough (L. acidophilus KCCM 32820과 P. freudenreichii KCCM 31227로 발효한 유청 발효물이 빵 반죽의 레올로지 특성에 미치는 영향)

  • Lee, Jeong-Hoon;Lee, Si-Kyung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.38 no.6
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    • pp.795-800
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    • 2009
  • This study was carried out to investigate the rheological properties of bread dough containing whey ferment cultured by L. acidophilus KCCM 32820 and P. freudenreichii KCCM 31227. Instrumental analysis such as farinograph, amylograph, extensograph, fermentation power, total titratable acidity (TTA) of dough and pH of dough were tested. On farinograph, difference of water absorption between doughs with and without whey ferment was 0.4% and dough containing whey ferment showed long development time of 3.2 min compared to dough without whey ferment, but showed shorter stability of 16.2 min. On amylograph, there was no significant difference on gelatinization and maximum viscosity temperature; however, maximum viscosity of flour with whey ferment revealed low amylograph unit. On extensograph, value of resistance and R/E ratio of dough containing whey ferment were higher than those of dough without whey ferment. On analysis of dough fermentation power by yeast, dough without whey ferment showed higher volume than dough with whey ferment during fermentation of 240 min. However, TTA of dough was higher in dough with whey ferment than that of the control without whey ferment, even though pH value was low.

Comparison of the rheological and diffusion properties of some gelling agents and blends and their effects on shoot multiplication

  • Dobranszki, Judit;Magyar-Tabori, Katalin;Tombacz, Etelka
    • Plant Biotechnology Reports
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    • v.5 no.4
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    • pp.345-352
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    • 2011
  • The rheological and diffusion properties of blends of agar/guar gum, agar/Phytagel and Phytagel/guar gum were analysed and compared to those properties of agar or Phytagel applied alone at two different gelling concentrations. Moreover, their effects on the shoot multiplication of the apple scion Galaxy and two black locust clones (SF63, SF82) were studied, and their cost benefits over agar were calculated. Elastic hydrogel formation was demonstrated for each blend by rheological measurements, but the gel strength depended on the types and concentrations of the applied gelling agents and blends. Guar gum was able to speed the diffusion in the different blends, and diffusion was independent of gel strength. The rate of shoot multiplication increased (to 8.9 shoots per explant) and the percent of hyperhydrated shoots decreased (to 12%) when the blend of agar/guar gum was used for the shoot multiplication of apple. Similarly, the highest multiplication rates of black locust clones (between 3.9 and 4.1) were obtained on media solidified by blends containing guar gum. The best shoot performance with the lowest percent of hyperhydrated shoots (11-12% in SF63 and 2-23% in SF82) was achieved using agar alone or the agar/guar gum blend. The shoot multiplication was improved of both species and the production cost was reduced by 42% by using the agar/guar gum blend.

Study on the talc dispersion and rheological properties of PP/talc compound (PP/talc 컴파운드의 talc 분산성 및 유변학적 특성 연구)

  • You, Young-Chul;Kim, Youn-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.9
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    • pp.4261-4266
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    • 2011
  • Polypropylene (PP)/talc compounds with talc content of 20wt% were fabricated by master-batch (MB) and direct compounding method using injection molding. The MB was prepared by mini compounder at $200^{\circ}C$ and the content of talc was 50wt%. The talc dispersion of the PP/talc compound was investigated by SEM-EDS. The talc was well dispersed within PP matrix in case of the MB-PP compound using MB. The rheological properties of the PP/talc compounds were measured by dynamic Rheometer. The MB-PP compound indicates higher shear thinning and elastic property than direct compound. The disperion of talc was certified by G'-G" plot, and Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.