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Effect of Time-dependancy of Surface Chloride Content on the Time-to-corrosion Initiation in concrete (콘크리트 표면염화물량의 시간의존성이 철근부식 개시시기에 미치는 영향)

  • Moon, Han-Young;Kim, Hong-Sam;Kim, Seong-Soo;Choi, Doo-Sun;Lee, Jong-Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.201-204
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    • 2005
  • The initiation of steel corrosion due to chloride diffusion is predicted to consider time-dependancy of surface chloride content. the profile of chloride concentration is the following: constant condition > square root condition > linear condition From these results, the initiation of steel corrosion in concrete is reverse order of above results of chloride profile. the effect of prolongation to initiation of steel corrosion is decreased with increasing concrete cover

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The strongest control of thermophoresis coefficient on nanoparticle profile at intermediate gaps: A spinning sphere

  • Sharif, Humaira;Naeem, Muhammad Nawaz;Khadimallah, Mohamed A.;Ayed, Hamdi;Hussain, Muzamal;Alshoaibi, Adil
    • Computers and Concrete
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    • v.29 no.3
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    • pp.201-207
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    • 2022
  • The evaluation of velocity profile for large values of buoyancy parameter and Bioconvected Rayleigh number is examined. The non-linear problem has been tackled numerically by shooting technique. Nanofluid temperature and nanoparticle concentration slightly elevates for increasing values of thermophoresis coefficient. Thickness of thermal boundary layer is significantly increased with thermophoresis coefficient whereas thickness of concentration boundary layer is more slightly enhanced. The response of temperature and nanoparticles concentration is observed due to change in Brownian motion parameter. As Brownian motion parameter increased temperature distribution is slightly enhanced. The reverse behavior is observed in case of nanoparticles concentration. Comparison of numerical technique with the extant literature is made and an acceptable agreement is attained.

Kinetics and Thermodynamic Studies on the Reaction of Cysteine with Cinnamaldehyde

  • Kim, Tae-Rin;Yun, Se-Joon;Park, Byung-Bin
    • Bulletin of the Korean Chemical Society
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    • v.7 no.1
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    • pp.25-29
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    • 1986
  • The reaction of cysteine with cinnamaldehyde have been studied kinetically and thermodynamically. It was found that the reaction proceeds in two steps; formation of the monoadduct by a Michael type addition followed by the nucleophilic attack of the second cysteine to the carbonyl carbon of the monoadduct to afford the thiazolidine derivative. A reaction profile for the reaction of cysteine with cinnamaldehyde was constructed based on the thermodynamic parameters analyzed for the forward and the reverse reactions. It was assumed that the second step of this reaction accompanies an intermediate, a Schiff base.

Distinctive pH Dependence and Substrate Specificity of Peptide Hydrolysis by Human Stromelysin-1 (Stromelysin-1에 의한 펩타이드 가수분해에서 pH와 기질특이성 연구)

  • ;Marianne V. Sorensen
    • Journal of Life Science
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    • v.10 no.2
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    • pp.210-217
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    • 2000
  • A kinetic profile of the catalytic domain of stromelysin-1 (SCD) using the fluorescent peptide substrate has been determined by the stopped-flow technique. The pH profile has a pH optimum of about 5.5 with an extended shoulder above pH 7. Three pKa values, 5.0, 5.7, and 9.8 are found for the free enzyme state and two pH independent Kcat/Km values of 4.1$\times$104 M-1 s-1 and 1.4$\times$104 M-1 s-1 at low and high pH, respectively. The profile is quite different in shape with other MMP family which has been reported, having broad pH optimum with two pKa values. The substrate specificity of SCD towards fluorescent heptapeptide substrates has been also examined by thin layer chromatography. The cleavage sites of the substrates have been identified using reverse-phase HPLC method.SCD cleaves Dns-PLA↓L↓WAR and Dns-PLA↓L↓FAR at two positions. However, the Dns-PLA↓LRAR, Dns-PLE↓LFAR, adn Dns-PLSar↓LFAR are cleaved exclusively at one bond. The double cleavages of Dns-PLALWAR and Dns-PLALFAR by SCD are in marked contrast to the close structurally related matrilysin. A notable feature of SCD catalysis agrees with the structural data that the S1' pocket of SCD is deeper than that of matriysin. The differences observed between SCD and matrilysin may form the basis of understanding the structural relationships and substrate specificities of the MMP family in vivo.

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Automobile Collision Reconstruction Using Post-Impact Velocities and Crush Profile (충돌 후 속도와 충돌 변형으로부터 자동차 충돌 재구성)

  • 한인환
    • Journal of Korean Society of Transportation
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    • v.18 no.4
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    • pp.107-115
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    • 2000
  • We suggest a method which solves the planar, two vehicle collision reconstruction problem. The method based on the Principle of impulse and momentum determines the pre-impact velocity components from Post-impact velocity components, vehicle Physical data and collision geometry. A novel feature is that although the impact coefficients such as the restitution coefficient and the impulse ratio are unknown, the method can estimate automatically the coefficients and calculate the pre-impact velocity components. This reverse calculation is important for vehicle accident reconstruction, since the pre-impact velocities are unknown and Post-impact Phase is the starting Point in a usual collision analysis. However. an inverse solution is not always Possible with the analytical rigid-body impact model. Mathematically, one does not exist under the common velocity condition. On the other hand, our method has a capability of reverse calculation under the condition if the absorbed energy during the collision process can be estimated using the crush profile. To validate the developed collision reconstruction a1gorithm, we use car-to-car collision test results. The analysis and experimental results agree well in the impact coefficients and the Pre-impact velocity components.

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Purification and Characterization of Paclitaxel from Plant Cell Cultures of Taxus chinensis in Large-Scale Process (식물세포 Taxus chinensis 배양으로부터의 Paclitaxel 대량 정제 및 특성)

  • 김진현;기은숙;민범찬;최형균;홍승서;이현수
    • KSBB Journal
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    • v.15 no.5
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    • pp.537-540
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    • 2000
  • In developing a HPLC purification process, it was hoped that a single chromatographic system would be sufficient to abtain pure paclitaxel in high yield. However, no such system was found, due in part to the complex taxoid profile of crude paclitaxel and to the rigorous nature of the product specification. A two step HPLC purification was adopted using reverse-phase separation on C(sub)18 as a first step, and normal-phase separation on silica as the final polishing step. Impurity profiles were established and maintained for paclitaxel, which identified and quantified each impurity observed in purified paclitaxel from these two steps, all impurities at or above 0.1% were identified. Results provide information for improving the quality control of paclitaxel production.

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Lecithin : Cholesterol Acyltransferase Activities in Rats Fed Cow량s Milk with Different Levels of Cholesterol (식이 콜레스테롤의 섭취량에 따라 우유가 흰쥐의 Lecithin: Cholesterol Acyltransferase 활성에 미치는 영향)

  • 최명숙
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.3
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    • pp.371-379
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    • 1994
  • The effect of milk in low and high cholesterol diets were investigated on serum cholesterol esterification. Weanling male Sprague-Dawley rats were divided into low(0.01% w/w) and high (1.01% w/w) cholesterol-diets groups. Bothlow and high cholesterol groups were consisted of three groups : control , LM(low heat milk), and HM (high heat milk) groups. After feeding these experimental diets for six weeks, serum cholesterol (free cholesterol and cholestryl ester) concentration and activity of lecithin.: cholesterol acyltransferase (LCAT) were measured, and serum lipoprotein profile was examined using gel column chromatography. According to the result, activity of LCAT was elevated independently by intakes of high cholesterol and milk , which resulted in the increase of daily turnover of serum cholesteryl ester. However, the turnover of HDL-cholesteryl ester increased only by milk. LCAT activity was moderately correlated with levels of total-and HDL-free choelsterol. It is concluded from the present study that milk had the cholesterol-lowering effect which partly appears to be mediated through facilitated reverse cholesterol transport.

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Characteristics of Vortical Jet Structures of a Hydrofoil

  • Yang, Chang-Jo;Kim, You-Taek;Choi, Min-Seon
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.7
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    • pp.842-851
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    • 2007
  • Oscillating foil propulsion, the engineering application of fish-like movement of a hydrofoil, has received in recent decades as a possible competitor for propellers. The oscillating foil produces an effective angle of attack, resulting in a normal force vector with thrust and lift components, and it can be expected to be a new highly effective propulsion system. We have explored propulsion hydrodynamics as a concept in wake flow pattern. The present study has been examined various conditions such as oscillating frequencies and amplitudes in NACA0010 profile. Flow visualizations showed that high thrust was associated with the generation of moderately strong vortices, which subsequently combine with trailing-edge vorticity leading to the formation of a reverse $K\acute{a}rm\acute{a}n$ vortex street. Vortex generation was inherent to jet production and playeda fundamental role in the wake dynamics. And it was shown that the strong thrust coefficient obtained as the Strouhal number was larger.

Mathematical Analysis and Simulation Based Survey on Initial Pole Position Estimation of Surface Permanent Magnet Synchronous Motor

  • Kim, Tae-Woong;Wheeler, Patrick;Choi, Jae-Ho
    • Journal of Power Electronics
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    • v.9 no.3
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    • pp.499-506
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    • 2009
  • In this paper, the initial pole-position estimation of a surface (non-salient) permanent magnet synchronous motor is mathematically analyzed and surveyed on the basis of simulation analysis, and developed for accurate servo motor drive. This algorithm is well carried out under the full closed-loop position control without any pole sensors and is completely insensitive to any motor parameters. This estimation is based on the principle that the initial pole-position is simply calculated by the reverse trigonometric function using the two feedback currents in the full closed-loop position control. The proposed algorithm consists of the predefined reference position profile, the information of feedback currents, speed, and relative position, and the reverse trigonometric function for the initial-pole position estimation. Comparing with the existing researches, the mathematical analysis is introduced to get a more accurate initial pole-position of the surface permanent magnet motor under the closed-loop position control. It is found that the proposed algorithm can be easily applied in servo drive applications because it satisfies the following user's specifications; accuracy and moving distance.