• Title/Summary/Keyword: reverse phase

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Formation of Mesoporous Membrane by Reverse Thermally induced Phase Separation (RTIPS) Process Using Flash Freezing (Mesoporous 막 제조를 위한 급냉법에 의한 역 열유도상전이공정)

  • Yeom, Choongkyun;Kim, Jiwon;Park, Heeyoung;Park, Seong Eun;Lee, Kee Yoon;Lee, Kew-Ho
    • Membrane Journal
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    • v.31 no.1
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    • pp.67-79
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    • 2021
  • Mesoporous polystyrene (PS) and polyethersulfone (PES) membranes have been fabricated by reverse-thermally induced phase separation (RTIPS) process, using flash freezing. The mesoporous pores can be created by the nano-scaled phase separation induced by the formation and growth of solvent crystals in the dope solution in RTIPS process. RTIPS process has been characterized through analysis on the enthalpy change in the solvent of the dope solution, the morphology of the membrane fabricated with different polymer content, and the pore size distribution and its standard deviation of pore size of the membrane with polymer content via DSC, SEM, and BET, respectively. It is found that the kinetic aspect of the dope solution, i.e., the crystallization of solvent is a crucial factor to determine the structure of membrane fabricated in RTIPS rather than the thermodynamic aspect of the dope solution.

Effect of Joint Kinetics and Coordination on the Within-Individual Differences in Maximum Vertical Jump (관절 역학과 협응이 최대 수직 점프의 개인내 수행차에 미치는 영향)

  • Kim, Yong-Woon;Seo, Jung-Suk;Han, Dong-Wook
    • Korean Journal of Applied Biomechanics
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    • v.22 no.3
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    • pp.305-314
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    • 2012
  • The purpose of this study was to investigate the effects of joint kinetics and coordination on within-individual differences in maximum vertical jump. 10 male subjects aged 20 to 30 performed six trials in maximum vertical jump and with based on jump height the good(GP) and bad(BP) performances for each subject were compared on joint kinetics of lower extremity and coordination parameters such as joint reverse and relative phase. The results showed that maximum moment, power, and work done of hip joint and maximum moment of ankle joint in GP were significantly higher than that in the BP but no significant differences for the knee joint. We could observe a significant difference in joint reverse timing between both conditions. And also the relative phase on ankle-knee and ankle-hip in GP were significantly lower than that in the BP, which means that in GP joint movements were more in-phase synchronized mode. In conclusion, mechanical outputs of hip and ankle joints had an effect on within-individual differences in vertical jump and the inter-joint coordination and coordination including sequence and timing of joint motion also might be high influential factors on the performances within individual.

The Effect of Water in Four Adenine-Thymine and Three Guanine-Cytosine Pairs: Combining Quantum and Statistical Mechanics

  • Lee, Jinkeong;Ham, Sihyun
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.151-155
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    • 2015
  • The molecular interactions between the nucleic acid bases and water molecules are important in organism. Despite Adenine-Thymine Hoogsteen base pair and Guanine-Cytosine Watson-Crick base pair have been demonstrated to be most stable in a gas phase, the effect of water on the stability of these base pairs remains elusive. Here we report the structural and thermodynamic characteristics on possible Adenine-Thymine and Guanine-Cytosine base pairs in a gas phase as well as in an aqueous phase by using quantum mechanical method and statistical mechanical calculations. First, we optimized the direct base-pair interaction energies of four Adenine-Thymine base pairs (Hoogsteen base pair, reverse Hoogsteen base pair, Watson-Crick base pair, and reverse Watson-Crick base pair) and three Guanine-Cytosine base pairs (GC1 base pair, GC2 base pair, and Watson Crick base pair) in a gas phase at the $B3LYP/6-31+G^{**}$ level. Then, the effect of solvent was quantified by the electronic reorganization energy and the solvation free energy by statistical mechanical calculations. Thereby, we discuss the effect of water on the stability of Adenine-Thymine and Guanine-Cytosine base pairs, and argue why Adenine-Thymine Watson-Crick base pair and Guanine-Cytosine Watson-Crick base pair are most stable in an aqueous environment.

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Solubilization of BSA into AOT Reverse Micelles Using the Phase-Transfer Method: Effects of pH and Salts (상 접촉법을 이용한 BSA의 AOT 역미셀으로 가용화: pH와 염의 영향)

  • 노선균;강춘형
    • KSBB Journal
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    • v.16 no.1
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    • pp.48-53
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    • 2001
  • Bovine serum albumin(BSA) was solubilized into the reverse micellar phase consisting of sodium bis(2-ethylhexyl) sulfosuccinate(AOT) and isooctane using the phase transfer method. Of particular interest in this study were the effects of pH and the added salt type and concentration on the solubilization efficiency. When univalent or divalent salts such as KCl, NaCl, $MgCl_2$, or $CaCl_2$ were added to the aqueous phase at a concentration of 0.1 M, maximum solubilization efficiency was attained at a pH ranging from 5 to 7, depending on the added salt type. Increased salt concentration up to 1 M resulted in an increased solubilization efficiency for $CaCl_2$ and NaCl, while the addition of $MgCl_2$ beyond 0.1 M showed an anomalous trend. Further, it was noteworthy that too a large extent the protein precipitated in the interface between the organic and aqueous phases at lower pHs and lower salt concentrations. The size of the reverse micelle water pool was estimated by measuring the molar ratio of the surfactant to the water, $W_0$. Irrespective of pH in the aqueous phase, the resulting value of $W_0$ was almost constant, eg., 20 for $MgCl_2$ . However, the value of $W_0$ decreased with increased salt concentration in the cases of KCl and $CaCl_2$.

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The Study on Protective Coordination of Utility Interconnected Multiple Distributed Generations (다수 분산전원 연계시 계통측 보호협조에 관한 연구)

  • Jung, Seung-Bock;Kim, Jae-Chul;Lee, Bong-Yi
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.11a
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    • pp.233-235
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    • 2004
  • This paper studies protective coordination of utility interconnected multiple distirbuted generations(DG). The study of protective coordination interconnected DG has been conducted. A protective coordination of utility disturbed by reverse current of DG. Therefore, A protetive device is not operate when reverse current flows. In this paper, we use phase difference between V and I. Also, we studied protective coordination algorithm of utility interconnected multiple DG.

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Nonlinear State Feedback for Minimum Phase in Nuclear Steam Generator Level Dynamics

  • Jeong, Seong-Uk;Choi, Jung-In
    • Journal of Electrical Engineering and information Science
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    • v.2 no.3
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    • pp.66-70
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    • 1997
  • The steam generator level is susceptible to the nonminimum phase in dynamics due to the thermal reverse effects known as "shrink and swell" in a pressurized water reactor. A state feedback assisted control concept is presented for the change of dynamic performance to the minimum phase the concept incorporates a nonlinear digital observer as a part of the control system. The observer is deviced to estimate the state variables that provide the true indication of water inventory by compensating for shrink and swell effects. The concept is validated with implementation into the steam generator simulation model.

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Determination of DL-Carnitine Hydrochloride in Pharmaceutical Preparation by HPLC using UV Absorption Derivatives (자외부 흡광 유도체를 이용한 염산 DL-카르니틴의 분석)

  • Park, Jun-Kyu;Shin, Hee-Jong;Kim, Jung-Woo
    • Journal of Pharmaceutical Investigation
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    • v.26 no.2
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    • pp.83-89
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    • 1996
  • A reverse-phase HPLC method to determine DL-Carnitine Hydrochloride in pharmaceutical preparation is described. UV absorption derivatives of DL-Carnitine Hydrochloride were formed with p-Bromophenacyl Bromide in an essentially quantitative manner using crown ether as catalyst. The DL-Carnitine-bromophenacyl ester absorbed UV radiation strongly at 254nm, allowing the detection of as small a quantity as 12.5ng of DL-Carnitine Hydrochloride. A linear defection range was $5\;{\times}\;10-8 \;{\sim}\;5\;{\times}\;10-7M$ of DL-Carnitine Hydrochloride. And the linear regression at various drug concentration was =0.999 (n=10). The DL-Carnitine Hydrochloride in pharmaceutical preparation was successfully derivatized and separated from other constituents by reverse phase HPLC with detection at 254 nm.

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Two p-Terphenyls from Mushroom Paxillus panuoides with Free Radical Scavenging Activity

  • Yun, Bong-Sik;Lee, In-Kyoung;Kim, Jong-Pyung;Yoo, Ick-Dong
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.233-237
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    • 2000
  • As part of a continuing investigation to identify free radical scavengers from the fruit bodies of basidiomycetes, we isolated two p-terphenyl compounds, designated as PAl and PA2l, from cethanolic extract of the fruit body of Pasillus panuoides. The methanolic extract was processed by ethyl acetate extraction and silica gel column chromatography to yield two active fraction. PAl was obtained from one of the fractions through Sephadex LH-20 and silica gel column chromatographies and reverse-phase HPLC. The other fraction was purified by Sephadex LH-20 and reverse-phase column chromatographies to produce PA2. The compounds PA1 and PA2 were identified as leucomentin-4 and leucomentin-2, respectively, on the basis of various spectroscopic analyses. These compounds exhibited strong inhibitory activities against lipid peroxidation in rat liver microsomes with IC_{50}$ values of 0.10 and $0.06{\;}\mu\textrm{g}ml$, respectively.

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Peak-to-Average Ratio Reduction for DS/CDMA Reverse Link (DS/CDMA 역방향 링크 Peak-to-Average Ratio 개선 방법)

  • 우정효;이채관;안재민;윤순영;김제우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.24 no.6A
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    • pp.845-854
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    • 1999
  • In the reverse link of DS/CDMA systems, the Peak-to-Average Ratio(PAR) performance can be analyzed by phase variations of spread signals. In the paper, we propose s PAR analysis method using phase variations of signals. Using this method, we analyze the PAR performances of existing spreading methods and suggest several methods improving the PAR performances. Also we show the proposed methods have negligible BER degradation compared to the existing ones.

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High Purity Extraction and Simultaneous High-performance Liquid Chromatography Analysis of Curcuminoids in Turmeric (강황에서 curcuminoids의 고순도 추출 및 고성능 액체 크로마토그래피 동시분석)

  • Lee, Kwang-Jin;Ma, Jin-Yeul;Kim, Young-Sik;Kim, Dong-Seon;Jin, Yinzhe
    • Journal of Applied Biological Chemistry
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    • v.55 no.1
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    • pp.61-65
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    • 2012
  • Three major curcuminoids in turmeric (Curcuma longa), curcumin, demethoxycurcumin, and bisdemethoxycurcumin, were efficiently extracted by optimizing extraction condition and simultaneously analyzed and identified using reverse phase high-performance liquid chromatography, thin-layer chromatography, and liquid chromatography-mass spectrometry method. The highest yield of extraction amount 0.279 g, 9.30% was obtained by dipping method with extraction time of 7 h.