• 제목/요약/키워드: reverse phase

검색결과 793건 처리시간 0.032초

PMMA Coated BaF2:Er3+ Nanoparticles via a Novel One-Step Reverse-Emulsion Polymerization Process

  • Lian, Hongzhou;Fu, Lianshe;Andre, Paulo S.;Lin, Jun
    • Bulletin of the Korean Chemical Society
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    • 제34권8호
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    • pp.2451-2454
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    • 2013
  • Poly(methyl methacrylate) coated $BaF_2:Er^{3+}$ nanoparticles were prepared via a novel reverse-emulsion polymerization process using methyl methacrylate as continuous phase and water as dispersed phase. Preparation and coating of $BaF_2:Er^{3+}$ particles were processed in a single step. The resulting polymeric composites show the characteristic $Er^{3+}$ luminescence at excitation of 980 nm and may have potential applications in amplified optical networks.

Extraction behavior of $\alpha$-lactalbumin using reverse micellar system

  • Noda, Kazuki;Konishi, Taiji;Naoe, Kazumitsu;Kawagoe, Mikio;Imai, Masanao
    • 한국막학회:학술대회논문집
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    • 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
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    • pp.179-182
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    • 2004
  • This study reports the extraction behavior of $\alpha$-lactalbumin using bis(2-ethylhexyl) sulfosuccinate sodium (AOT) reverse micelles. Forward extraction of $\alpha$-lactalbumin in the reverse micellar organic phase from aqueous feed solutions was strongly dependent on the AOT concentration and the complete forward extraction of 0.03 mM $\alpha$-lactalbumin was successfully achieved at an AOT concentration of ca. 100 mM. A similar dependency of the forward extraction on the AOT concentration was obtained in isooctane, n-hexane, and n-octane systems. In the backward extraction from the micellar organic phase, the recovery of the protein as high as ca. 90% was obtained with pH control and/or salt addition.

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Dansyl 유도체화와 역상 고성능액체크로마토그래피에 의한 아미노산의 정량 (Reverse-Phase High Performance Liquid Chromatographic Determination of Amino Acids after Precolumn Derivatization with 1-Dimethyl-aminonaphthalene-5-sulfonyl chloride)

  • 나혜경;전덕영;홍윤호
    • 한국식품영양과학회지
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    • 제22권6호
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    • pp.815-822
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    • 1993
  • This experiment was carried out to determine the separation condition of 1-dimethylaminonaphthalene-5-sulfony(Dansyl) derivatives of amino acids by reverse-phase high performance liquid chromatography with Nova-Pak C18 column. Determined solvent system was solvent A(200mA phosphate buffer pH 6.8 15%, acetonitrile 11%, water 74%) and solvent B(acetonitrile 65%, methanol 28%, water 7%). Linear gradient of solvent B was applied from 12% to 80% for 50min. Complete separation of 20 amino acids including asparagine and glutamine which constitute protein was achieved within 50min. As the detection limit was the range of picomole, the resolution power was excellent. Reproducibility of the retention time was less than mean $\pm$0.05min. According to the above optimum chromatographic conditions, the amino acid composition of some food and human blood was examined. The most affluent amino acid was alanine in human blood, aspartic acid and glutamic acid in soy sauce, alanine and threonine in soy milk and proline in milk and yoghurt.

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결합 인덕터를 이용한 효율적인 단상 듀얼-벅 인버터 (High-Efficiency Dual-Buck Inverter Using Coupled Inductor)

  • 양민권;김유진;최우영
    • 전력전자학회논문지
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    • 제24권6호
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    • pp.396-405
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    • 2019
  • Single-phase full-bridge inverters have shoot-through problems. Dead time is an essential way of solving these issues, but it distorts the output voltage and current. Dual-buck inverters are designed to eliminate the abovementioned problems. However, these inverters result in switching power loss and electromagnetic interference due to the diode reverse-recovery problem. Previous studies have suggested reducing the switching power loss from diode reverse-recovery, but their proposed methods have complex circuit configurations and high system costs. To alleviate the switching power loss from diode reverse-recovery, the current work proposes a dual-buck inverter with a coupled inductor. In the structure of the proposed inverter, the current flowing into the original diode is divided into a new diode. Therefore, the switching power loss is reduced, and the efficiency of the proposed inverter is improved. Simulation waveforms and experimental results for a 1.0 kW prototype inverter are discussed to verify the performance of the proposed inverter.

오스테나이트계 스테인리스강의 감쇠능에 미치는 역변태 오스테나이트의 영향 (Effect of Reversed Austenite on the Damping Capacity of Austenitic Stainless Steel)

  • 김영화;성지현;강창룡
    • 동력기계공학회지
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    • 제19권1호
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    • pp.70-75
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    • 2015
  • The influence of reversed austenite on the damping capacity in austenitic stainless steel with two phase of martensite and reversed austenite was investigated. The two phases of deformation induced martensite and reversed austenite was obtained by an reverse annealing treatment at $500^{\circ}C{\sim}700^{\circ}C$ for various time after 70% cold rolling. With an increase of the reverse annealing treatment temperature and time, volume fraction of reversed austenite was rapidly increased. With an increase of volume fraction of reveresd austenite, damping capacity was rapidly increased. At same volume of reveresd austenite, damping capacity of reversed austenite obtained by reverse annealing treatment at $700^{\circ}C$ for various time was higher then reveresd austenite obtained by reverse annealing treatment at $500^{\circ}C{\sim}700^{\circ}C$ for 10min. Thus, the damping capacity was affected greatly by reversed austenite obtained by annealing treatment at $700^{\circ}C$ for various time.

Effects of reverse waves on the hydrodynamic pressure acting on a dual porous horizontal plate

  • Kweon, Hyuck-Min;Choi, Young-Hwan
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제6권1호
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    • pp.60-73
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    • 2014
  • The seaward reverse wave, occurring on the submerged dual porous horizontal plate, can contribute to the reduction of the transmitted wave as it reflects the propagating wave. However, the collision between the propagating and seaward reverse waves increases the water level and acts as a weight on the horizontal plate. This study investigated the characteristics of the wave pressure created by the seaward reverse wave through the analysis of experimental data. The analysis confirmed the following results: 1) the time series of the wave pressure showed reverse phase phenomena due to the collision, and the wave pressures acted simultaneously on both upper and lower surfaces of the horizontal plate; 2) the horizontal plate became repeatedly compressed and tensile before and after the occurrence of the seaward reverse wave; and 3) the seaward reverse wave created the total wave pressure to the maximum towards the direction of gravity, primarily on the upper plate. It was also confirmed that the wave distributions showed a similar trend to the wave steepness. Such outcome of the analysis will provide basic information to the structural analysis of the horizontal plate as a wave dissipater of the steel-type breakwater (STB).

Performance Evaluation of Access Channel Slot Acquisition in Cellular DS/CDMA Reverse Link

  • Kang, Bub-Joo;Han, Young-Nam
    • ETRI Journal
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    • 제20권1호
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    • pp.16-27
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    • 1998
  • In this paper, we consider the acquisition performance of an IS-95 reverse link access channel slot as a function of system design parameters such as postdetection integration length and the number of access channel message block repetitons. The uncertainty region of the reverse link spreading codes compared to that of forward link is very small, since the uncertainty region of the reverse link is determined by a cell radius. Thus, the parallel acquisiton technique in the reverse link is more efficient than a serial acquisition technique in terms of implementation and of acquisition time. The parallel acquisition is achieved by a bank of N parallel I/Q noncoherent correlator are analyzed for band-limited noise and the Rayleigh fast fading channel. The detection probability is derived for multiple correct code-phase offsets and multipath fading. The probability of no message error is derived when rake combining, access channel message block combining, and Viterbi decoding are applied. Numerical results provide the acquisition performance for system design parameters such as postdetection integration length and number of access channel message block repetitions in case of a random access on a mobile station.

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Back-Extraction Processes of C.C.Lipase with Mediated AOT Reverse Micellar System

  • Lee, Sung-Sik;Kim, Bong-Gyu;Sung, Nak-Chang;Lee, Jong-Pal
    • Bulletin of the Korean Chemical Society
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    • 제25권6호
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    • pp.873-877
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    • 2004
  • The relationship between the behaviors of c.c.lipase back-extraction and their percolation phenomena by using AOT reverse micellar systems (RVMS) has been studied by the addition of a small amount of additives to organic phase such as thiols and nonionic-surfactants focusing on micelle-micelle interactions. The values of ${\beta}_t$ defined by the variation of percolation processes and back-extraction behaviors of c.c.lipase have a good linear correlation. The hydrophobicity of additive molecules suppressing the cluster formation of reverse micelles (high values of ${\beta}_t$) improved the back-extraction behavior of c.c.lipase. The back-extraction fraction and its rate of c.c.clipase are increased with decreasing of the value of hydrophilic lipophilic balance (HLB) and increasing of the hydrophobicity per additive molecules added to reverse micellar systems (RVSM) in the same additives concentration.

기준전류추정형 인버어터에 의한 2 권선전동기의 2 상운전특성 (Characteristics of Two Phase Operation of Two Winding Motor Driven by Reference Current Adaptive Inverter)

  • 원종수;정의상
    • 대한전기학회논문지
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    • 제33권8호
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    • pp.289-298
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    • 1984
  • The single phase induction motor is recently requested to meet a broad speed control and smooth forward and reverse operation due to the multifarious usages. This paper deals with two phase operation of a two winding motor by reference current adaptive inverter which can supply the currents to satisfy the balanced oeration into the main and auxiliary winding through the entire operational region. According to the roposed system, the starting, forward and reverse and variable speed control of a two winding motor eliminated the capacitor from the capacitor-run motor is also possible. The formation and its principle of the reference current adaptive inverter and characteristic analysis of the motor fed by this apparatus are described in this paper. Excellent agreement with the measured results and calculated values by computer simulation is obtained.

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Determination of Mono- and Oligosaccharides Derivatized with p-Aminobenzoic Ethyl Ester by Reverse Phase HPLC

  • Kwon, Hyokjoon;Kim, Joon
    • 분석과학
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    • 제8권4호
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    • pp.859-864
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    • 1995
  • Mono- and oligosaccharides are derivatized with p-aminobenzoic ethyl ester (ABEE), strongly absorbs UV light at 254 nm, in the presence of sodium cyanoborohydride. C18-bonded silica column is used for the separation of sugar-ABEE derivatives in an isocratic mode. RP-HPLC conditions are optimized by using ternary mixture as mobile phase and $45^{\circ}C$ as a column temperature. Sugar-ABEE derivatives are separated well within a short run time (ca. 25 min) by reverse-phase partition chromatographic mode. The ($1{\rightarrow}6$) linkage type of dihexose-ABEE derivatives has shorter retention time than ($1{\rightarrow}4$)-linkage type. After acid hydrolysis of glycoproteins with 2M trifluoroacetic acid, monosaccharide composition and contents are determined. This procedure is very useful for the simultaneous analysis of neutral and amino sugars in a single chromatographic step using RP-HPLC without reacetylation of deacetylated amino sugars, which are produced by acid hydrolysis.

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