• Textile Coloration and Finishing
• /
• v.4 no.3
• /
• pp.116-121
• /
• 1992

This paper is on for a material to replace the petroleum-based resins used as adhesives for the fiber in rubber composite materials. The study limited to the reaction properties of tannin with formaldehyde. Tannin-formaldehyde(TF) reactions were carried out in aqueous media. Rates of reaction were strongly dependent on concentration, temperature, pH, and the mole ratio of tannin to formaldehyde. Viscosities of reaction mixtures were followed up to gelation. The reactivity of tannin-formaldehyde resins was greater than that of resorcinol-formaldehyde resins. To formulate an adhesive, a styrene-butadiene-vinyl pyridine terpolymer latex(L) was added to the TF. This preliminary results suggest that the condensed tannins have considerable promise as substitutes for resorcinol used in resin formulation for bonding of fiber to rubber.

• Journal of the Korean Applied Science and Technology
• /
• v.24 no.3
• /
• pp.309-318
• /
• 2007

Novolac is widely used as the primary solid component of most photoresists in semiconductor and microelectronic devices. In this study, novolac resins were prepared by condensation of 35% formaldehyde with phenolic compounds such as m-/p-cresol, 2,5-dimethylphenol and bisphenol A in the presence of oxalic acid as catalyst. The average molecular weight $(M_w)$ of these novolac resins has been varied on the changing of mixing ratio of m-/p-cresol/2,5-dimethylphenol/bisphenol A or formaldehyde/phenolic compound. Also, thermal properties of novolac were observed by TGA.

• Journal of Adhesion and Interface
• /
• v.7 no.4
• /
• pp.45-52
• /
• 2006

Five low molar ratio urea-formaldehyde (LUF) resins were synthesized in this study. The effects of molar ratio, free formaldehyde content, and catalysts on the curing characteristics of LUF resins were studied by measuring its free formaldehyde content, pH value change after catalysts added, curing rate, and pot life, observing its cured appearance, and analyzing its thermal behavior. The results indicate that: 1) The LUF resin with lower molar ratio than 1.0 can still cure; 2) Free formaldehyde content is not the main factor in affecting curing rate of LUF resin; 3) Compared with ammonium chloride as a traditional catalyst, persulfate salts markedly accelerate the curing rate of LUF resin, and result in the different appearance; 4) the addition of sodium chloride to catalysts can accelerate the curing rate of LUF resin, but the effect is moderate.

• Elastomers and Composites
• /
• v.31 no.1
• /
• pp.13-22
• /
• 1996

In order to Improve the fracture toughness of epoxy resin system, liquid chloroprene rubber(LCR) and liquid butadiene rubber (LBR) which have hydroxy group were used in the brittle epoxy system. Mechanical and toughness characterization of the modified epoxy resins were investigated as a function of liquid rubbers content. Epoxy resins modified with both of the liquid rubbers showed complete phase-separation microstructure : In all of the LCR content, it was observed that the domain size of LCR dispersed in the epoxy matrix ranging from $2{\mu}m\;to\;5{\mu}m$. It was found that fracture toughness, $K_{ic}$, of the modified LCR system was enhanced continuously as increasing LCR content. However around 10phr of LBR system showed maximum fracture toughness. Specifically, when BPA add to the modified LCR system, thermal and mechanical properties increased than neat epoxy. At the same time, fracture toughness was enhanced.

• The Korean Journal of Ecology
• /
• v.24 no.2
• /
• pp.121-123
• /
• 2001

Gums, resins and gum-resins represent a variety of plant exudates that are highly prized and are extensively used in various industries. The usage of water soluble gums is growing at faster rate as they are excellent suspending agents, dispersants stabilizing agents, emulsifiers and gel forming agents. The gums are made up of carbohydrate polymers, composed of sugar units glycosidically condensed to form large molecules. Resins are non-volatile products, and oxidative products of terpenes or fatty acids, and are of greater commercial importance. They are soluble in water and contrasted with gums, soluble in organic solvents only.

• Journal of Korean Society of Industrial and Systems Engineering
• /
• v.25 no.4
• /
• pp.69-78
• /
• 2002

The basic purpose of the JIT(Just In Time) production system is to increase profits by reducing costs-that is, by completely eliminating waste such as excessive stocks or workforce. To achieve cost reduction, Production must promptly and flexibly adapt to changes in market demand without having wasteful slacks. :iuch an ideal is accomplished by the concept of JIT, producing the necessary items in the necessary quantities at the necessary time. The JIT production system is supported by the following: reduction of setup time, smoothing of production, standardization of jobs, improvement activities, design of machine layout, Kanban system, autonomation etc. This study examined the present state of the domestic JIT production system and introduced the empirical case of JIT application a small and medium manufacturing company. A synthetic resins manufacturing company applied JIT principles to its processes and achieved the great performance.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 1998.10a
• /
• pp.124-130
• /
• 1998

The wear characteristics and wear mechanisms of dental composite resins were investigated. Composite resins such as Metalii, Silux Plus, Heliomolar and Palfique Estelite were selected as specimens and contents of filler in specimens in order to analyze the effect of Prepolymerized Particle Fillers in friction and wear characteristics. Ball on flat wear tester was used for a wear test. Friction and wear tests are carried out at room temperature. The friction coefficient of Metafil was quite high relatively, and the wear resistance of Silux Plus and Palfique Estelite was better than that of Metafil and Hellomolar at the same experimental condition. The main wear mechanism is plastic flow and abrasive wear by crack propagation.

• Journal of environmental and Sanitary engineering
• /
• v.20 no.4 s.58
• /
• pp.38-44
• /
• 2005

Cryptand resins were synthesized with 1-aza-15-crown-5 macrocyclic ligand attached to styrene divinylbenzene (DVB) copolymer with crosslink of $1\%,\;2\%,\;5\%\;and\;10\%$ by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time, dielectric constant of solvent and crosslink on adsorption of uranium$(UO_2^{2+})$ ion were investigated. The uranium ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium$(UO_2^{2+})$ > zinc$(Zn^{2+})$ > samarium$(Sm^{3+})$ ion. The adsorption was in order of $1\%>2\%>5\%>10\%$ crosslink resin and adsorption of resin decreased in proportion to order of dielectric constant of solvents.

• Journal of environmental and Sanitary engineering
• /
• v.23 no.1
• /
• pp.57-65
• /
• 2008

Resins were synthesized with 1-aza-15-crown-5 macrocyclic ligand attached to styrene(dangerous matter) divinylbenzene(DVB) copolymer with crosslink of 1, 2, 6 and 15% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time and crosslink on adsorption of metal ion　from water fire extinguishing agent by the synthetic resin adsorbent were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in water was in increasing order of $Mg^{2+}>Al^{3+}>Pb^{2+}$. The adsorption was in the order of 1, 2, 6, and 15% crosslink resin.

• Tribology and Lubricants
• /
• v.15 no.2
• /
• pp.212-217
• /
• 1999

The wear characteristics and wear mechanisms of dental composite resins were investigated. Composite resins such as Metafil, Silux Plus, Heliomolar and Palfique Estelite were selected as specimens and contents of filler in specimens in order to evaluate the effect of Prepolymerized Particle Fillers in friction and wear characteristics. Ball on flat wear tester was used for the wear test at room temperature. The friction coefficient of Metafil was quite high relatively, and the wear resistances of Silux Plus and Palfique Estelite were better than that of Metafil and Heliomolar at the same experimental condition. It was found that The main wear mechanism is plastic flow and abrasive wear by failure of filler's bond to the matrix.