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Adsorption Characteristic of Mg(II), Al(III), Pb(II) Metal Ions on Cryptand Ion Exchange Resin from Water Fire Extinguishing Agent  

Kim, Joon-Tae (Dept. of Chemistry, Chosun University)
Kim, Kwan-Chun (Dept. of Environmental Sanitation, Gwangju Health College)
Publication Information
Journal of environmental and Sanitary engineering / v.23, no.1, 2008 , pp. 57-65 More about this Journal
Abstract
Resins were synthesized with 1-aza-15-crown-5 macrocyclic ligand attached to styrene(dangerous matter) divinylbenzene(DVB) copolymer with crosslink of 1, 2, 6 and 15% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, and IR-spectrum. The effects of pH, time and crosslink on adsorption of metal ion　from water fire extinguishing agent by the synthetic resin adsorbent were investigated. The metal ion was showed fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in water was in increasing order of $Mg^{2+}>Al^{3+}>Pb^{2+}$. The adsorption was in the order of 1, 2, 6, and 15% crosslink resin.
Keywords
1-aza-15-crown-5; macrocyclic ligand; styrene; crosslink; divinylbenzene(DVB);
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
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1 M. A. Ahearn, J. Kim, A. J. Leong, L. F. Lindoy, G. V. Meehan, and O. A. Mattews : The interaction of copper(II), silver(I) and lead(II) with 22-membered macrocycles incorporating O4N2, O2S2N2 and S4N2-donor sets, Chem. Soc., Dalton Translation, 3591-3598, 1996
2 K. S. Huh and S. G. Sin : Preparation of glycidylmethacrylate-divinylbenzene copolymers containing phosphoric acid groups and adsorption characteristic of uranium(I), Kor. Ind. Eng. & Chem., 9, 680-688, 1998
3 G. Bombieri and G. Depaoli : Crown ether complexes of actinide elements, Inorg. Chem., 18, 123-130, 1976
4 E. Blasius and K. P. Janzen : Preparation and application of polymers with cyclic polyether anchor groups, Pure & Appl. Chem., 54, 2115-2122, 1982   DOI
5 Robert C. Weast : Handbook of chemistry and physics, 70th, .D52-D93, 1989
6 L. F. Lindoy, P. G. Grimslery, H. C. Lip, R. J. Smith and J. T. Baker :Synthesis of 14-, 15-, and 16-membered crown compounds containing oxygen and nitrogen heteroatoms, Aus. J. Chem.,30, 2095-2101, 1977   DOI
7 T. Hayashita, J. H. Lee, S. Chem, and R. A. Bartsch : Selective column concentration of alkali-metal cations with a crown ether carboxylic acid resin, Anal. Chem., 63, 1844-1852, 1991   DOI
8 L. F. Lindoy, K. R. Adam, D. S. Bladwine, A. Bashall, M. McPartlin, and H. R. Powell : Donor-set control of silver(I)/lead(II) discrimination using mixed-donor macrocyclic ligands, Chem. Soc., Dalton Translation, 237-243, 1994
9 H. K. Frensddorff : Salt complexes of cyclic polyethers. distribution equilibra, Am. Chem. Soc., 93, 4684-4689, 1971   DOI
10 K. W. Choi, Y. S. Ahn, K. T. Shim, H. Huh, and J. S. Ahn : Synthesis of diazacrown ethers containing phenolic side arms and their complex with divalent metal ions, Bull. Kor. Chem. Soc., 23, 688-693, 2002   DOI
11 M. Y. Suh, S. C. Sohn, C. H. Lee, K. S. Choi, D. Y. Kim, Y. J. Park, K. K. Park, K. Y. Jee, and W. H. Kim : Cation exchange separation and determation of ruthenium in a simulated spent nuclear fuel, Kor.Chem. Soc., 44, 526-532, 2000
12 Y. J. Park, K. K. Park, M. Y. Suh, S. K. Yoon, K. S. Choi, K. Y. Jee, and W. H. Kim : Surface complexation modeling of Ni(II), Co(II), and Sr(II) adsorption on amorphous alumina, Kor. Chem. Soc., 44, 305-311, 2000
13 C. J. Pederson : Crystalline salt complexes of macrocyclic polymers, Am. Chem. Soc., 92, 386-390, 1970   DOI
14 H. Egawa, T. Nonaka, and M. Ikari : Preparation of macroreticular chelating resins containing dihydroxyphosphino and/or phosphono groups and their adsorption ability for uranium, Appl. Poly. Sci., 29, 2045-2052, 1984   DOI   ScienceOn
15 S. K. Park, J. T. Kim, and G. H. Noh : Resin synthesis of 1-aza-15-crown- 5-styrene- divinylbenzene with crosslink, Kor. J. Sanitation., 17, 63-68, 2002