• 제목/요약/키워드: resin ratio

검색결과 731건 처리시간 0.028초

침엽수단판의 수지함침처리에 의한 압밀화 특성 (Densification Characteristics of Softwood Veneers Treated by Resin Impregnation)

  • 서진석
    • 한국가구학회지
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    • 제14권2호
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    • pp.21-29
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    • 2003
  • This study was carried out to investigate characteristics of plywood overlaid with softwood veneers densified by resin impregnation and compression. The resin impregnability of Korean pine veneer under atmospheric pressure soaking was greater than that of larch, and impregnability of melamine resin was slightly greater than phenolic resin. It was suggested that resin impregnation ratio was affected by density and thickness of veneer. The largest melamine resin impregnation ratio of 50.7% was obtained with 1.26mm thick Korean pine veneer, and the lowest phenolic resin impregnation ratio of 11.7% with 3.41mm thick larch veneer. Therefore, it was suggested that the vacuum-pres sure-soak treatment is required at thick larch veneer. In densifying resin-impregnated veneers, densification ratio from 13.4 to 31.2% was obtained by high pressure from 15.6 to $20.8kgf/cm^2$. Impregnation of melamine resin also showed relatively greater at densification than that of phenolic resin. So it showed the degree of densification of about 20% or greater. It was seemed that adhesive bonding strength of plywood(base panel) which was directly pressed and overlaid with resin-impregnated veneer was affected by resin tackiness after resin impregnation followed by semi-drying. In laboratory scale, melamine resin impregnation was more favorable for the development of adhesive bonding strength owing to moisture control.

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Effects of Formaldehyde to Urea Mole Ratio on Thermomechanical Curing of Urea-Formaldehyde Resin Adhesives

  • Park, Byung-Dae;Kim, Jae-Woo
    • Journal of the Korean Wood Science and Technology
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    • 제35권5호
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    • pp.76-86
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    • 2007
  • This study was conducted to investigate the effects of formaldehyde to urea (F/U) mole ratio on thermomechanical curing of UF resin adhesives with different F/U mole ratios. Thermomechanical curing of these UF resin adhesives was characterized using parameters of dynamic mechanical analysis (DMA) such as the gel temperature, maximum storage modulus, and peak temperatures of storage and loss modulus. As the F/U mole ratio decreased, the gel temperature of UF resin adhesives increased. The maximum storage modulus as an indicator of the rigidity of UF resin adhesives decreased with decreasing F/U mole ratio. The peak temperature of tan $\delta$ increased with decreasing F/U mole ratio, indicating that the vitrification occurred faster for high F/U mole ratio of UF resin adhesives than for the one of lower F/U mole ratio. These results partially explained the reason why UF resin adhesives with lower F/U mole ratio resulted in relatively poor adhesion performance when they were applied.

The Effects of Resin Ratio and Bed Depth on the Performance of Mixed-bed Ion Exchange at Ultralow Solution

  • Yoon, Tae-Kyung;Lee, Gang-Choon;Noh, Byeong-Il
    • 한국환경과학회지
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    • 제18권6호
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    • pp.595-601
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    • 2009
  • The effects of the cation-to-anion resin ratio and bed depth on ion exchange performance of mixed-bed were studied at ultralow solution concentration. Breakthrough curves were experimentally obtained for NaCI solution as functions of resin ratio and bed depth. The bed depth affects the pattern of the sodium breakthrough curve but not the chloride breakthrough curve in beds because of the selectivity difference. Resin selectivity determines the shape of breakthrough curves, Some sodium and chloride breakthrough curves crossed at a point as a function of resin ratio. The lower cation-to-anion resin ratio showed the higher effluent concentration or treated volume of the crossover point regardless of the total resin weight.

Properties of Urea-Formaldehyde Resin Adhesives with Different Formaldehyde to Urea Mole Ratios

  • Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제35권5호
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    • pp.67-75
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    • 2007
  • As a part of abating the formaldehyde emission of urea-formaldehyde (UF) resin adhesive by lowering formaldehyde to urea (F/U) mole ratio, this study was conducted to investigate properties of UF resin adhesive with different F/U mole ratios. UF resin adhesives were synthesized at different F/U mole ratios of 1.6, 1.4, 1.2, and 1.0. Properties of UF resin adhesives measured were non-volatile solids content, pH level, viscosity, water tolerance, specific gravity, gel time and free formaldehyde content. In addition, a linear relationship between non-volatile solids content and sucrose concentration measured by a refractometer was established for a faster determination of the non-volatile solids content of UF resin. As F/U mole ratio was lowered, non-volatile solids content, pH, specific gravity, water tolerance, and gel time increased while free formaldehyde content and viscosity were decreased. These results suggested that the amount of free formaldehyde strongly affected the reactivity of UF resin. Lowering F/U mole ratio of UF resin as a way of abating formaldehyde emission consequently requires improving its reactivity.

에폭시 수지 모르터의 특성에 관한 실험적 연구 (Experimental Studies on the Properties of Epoxy Resin Mortars)

  • 연규석;강신업
    • 한국농공학회지
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    • 제26권1호
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    • pp.52-72
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    • 1984
  • This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

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문화재 보존처리에 사용되는 에폭시수지의 사용현황과 배합비율에 따른 물성 변화 연구 (Evaluation of Physical Properties according to Mixing Ratio and the Survey of the Current Situation for Epoxy Resin used in Conservation)

  • 이은지;장성윤
    • 보존과학회지
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    • 제32권2호
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    • pp.223-234
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    • 2016
  • 2액형 에폭시 수지는 문화재 보존처리에 매우 광범위하게 사용되고 있으나 사용 시 주제와 경화제의 배합비율에 따라 경화특성, 기계적 강도, 화학 구조 등이 달라질 수 있고 대상 문화재의 안정성에 영향을 미칠 수 있다. 설문조사 결과, 보존처리 실무자들은 소량의 에폭시수지를 눈대중으로 혼합하거나 가사시간을 줄이기 위해 인위적으로 경화제를 과량 첨가하는 경우가 있는 것으로 조사되었다. 이 연구에서는 속경화형 2종과 일반경화형 2종의 에폭시수지를 대상으로 주제에 대한 경화제의 비율을 0.25~4배로 설정하여 각 경우의 경화특성, 기계적 강도, 화학 작용기를 분석하였다. 그 결과 속경화형 에폭시수지는 경화제가 0.5~2배일 때 높은 반응열과 함께 경화반응이 빠르게 나타났으며, 경화제 비율이 제조사에서 공시된 정비율보다 적을 때 더 높은 기계적 강도가 나타났고 에폭시의 가교결합도 활발히 일어난 것으로 관찰되었다. 일반경화형 에폭시수지는 대부분 경화반응열이 낮고 느린 반응속도로 경화가 진행되며, 경화제가 정비율 이하에서 가장 높은 기계적 강도를 나타냈다. 그러나 경화제 비율이 2배 이상 일 때는 경화속도가 매우 느려지고 접착강도도 낮아지는 것으로 나타났다. 따라서 배합비가 정비율 이하에서는 비교적 빠른 반응속도와 유사한 기계적 강도를 나타내는 반면 정비율 이상에서는 물성이 급격하게 저하되므로 구현하고자 하는 성능에 영향을 미칠 수 있을 것으로 판단된다.

요소·멜라민 수지 접착제의 겔화성 및 접착특성에 미치는 수지조성과 첨가물의 영향 (Effects of Resin Compositions and Additives on Gelation Properties and Bonding Characteristics of Urea-Melamine-Formaldehyde resin adhesives)

  • 노정관
    • Journal of the Korean Wood Science and Technology
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    • 제27권1호
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    • pp.72-78
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    • 1999
  • 요소 멜라민수지의 조성에 의한 속경화의 가능성, 경화촉진제의 첨가에 의한 경화촉진 효과 및 접착성능에 대하여 검토하였다. 수지조성과 동시반응에 의해 제조한 UMF 수지의 겔화성과의 관계는 요소(멜라민/요소 몰비=0.2)에 대한 포롬알데히드의 몰비가 증가할수록 겔화시간이 빨라졌다. 그러나, 요소에 대한 포름알데히드의 몰비가 2.5이상에서는 수지중의 유리포름알데히드량이 KS기준에 합격하지 못하므로 속경화를 위해 수지 합성시 포름알데히드의 첨가량을 높이는 것은 어려울 것으로 생각된다. 또한, 요소에 대한 포름알데히드의 몰비를 3.4로 고정한 UMF수지에 있어서 요소에 대한 멜라민의 몰비가 0.3에서 0.6으로 증가할 수록 수지의 겔화시간은 다소 단축되었으나, 0.6이상에서는 다시 증가하였다. UMF수지의 겔화성과 접착강도는 경화제로서 염화암모늄과 p-툴루맨설폰산, 증량제로서 소액분과 콘글루텐의 병용에 의해 크게 향상되었다.

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온도 및 경화제 비율에 따른 수중경화형 에폭시수지의 레올로지 특성 (The Properties of Rheology of Underwater-Hardening Epoxy Resin According to the Temperature and Hardener Ratio)

  • 정은혜;곽은구;이대경;조성현;배기선;김진만
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.761-764
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    • 2005
  • Epoxy resin, as no-hardening, applied for repair and finish materials is used to mix together with hardener. It is advantages that epoxy resin has reaction shrinkage less than other materials and has excellent in water proofing, thermal resistance. The other hands, because ratio of combination of epoxy resin and hardener is fixed, it is not possible to change according to field condition. This investigated suspended time by temperature and hardener ratio. As a results of study, it can select economical ratio of the epoxy resin and hardener according to site situation.

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프리프레그 제작용 에폭시 수지.경화제.경화촉진제 혼합비 변화에 따른 FRMLs의 피로거동 특성 (The Mixture Ratio Effect of Epoxy Resin, Curing Agent and Accelerator on the Fatigue Behavior of FRMLs)

  • 송삼홍;김철웅
    • 대한기계학회논문집A
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    • 제25권4호
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    • pp.592-601
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    • 2001
  • Fiber reinforced metal laminates(FRMLs) are new types of hybrid materials. FRMLs consists of high strength metal(Al 5052-H34) and laminated fiber with structural adhesive bond. The mixture ratio effect of epoxy resin$.$curing agent$.$accelerator on the fatigue behavior of FRMLs was investigated in this study. The epoxy, diglycidylether of bisphenol A(DGEBA), was cured by methylene dianiline(MDA) with or without an accelerator(K-54). Eight different kinds of resin mixture ratios were selected for the test ; five kinds of FRMLs(1) and three others of FRMLs(2). The relationship between da/dN and ΔK with variation of resin mixture ratio was studied. FRMLs(1) and FRMLs(2) indicated approximately 2 times and 2.2 times more improved maximum bending strengths in comparison with those of Al 5052-H34. The resin mixture ratio <1:1> in case of FRMLs(1) indicated the maximum fatigue life, while the resin mixture ratio <1:1:0.2> in case of FRMLs(2) indicated the maximum fatigue life. As results, FRMLs(2) turned out to have more effective characteristics on the fatigue properties and the bending strength than those of FRMLs(1).

경량골재를 사용한 콘크리트 복합체의 단열성능에 관한 연구 (A Study on the Thermal Insulation Property of Concrete Composites using Light-weight Aggregate)

  • 소승영
    • 한국건축시공학회지
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    • 제4권3호
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    • pp.93-100
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    • 2004
  • In recent years, it has widely been studied on the light-weight composites for the purpose of the large space and thermal insulation of building structures. The purpose of this study is to evaluate the properties of light-weight composites made by binders as cement, resin and polymer cement slurry. The concrete composites are prepared with various conditions such as polymer-cement ratio, void-filling ratio, type of resin, filler content and light-weight aggregate content, tested for thermal conductivity. From the test results, the thermal conductivity of concrete composites with the binder of cement tends to decrease with increasing polymer-cement ratio, and to increase with increasing void-filling ratio. The thermal conductivity of concrete composites with the binder of resin are markedly affected by the light-weight aggregate content, type of resin and filler content. The composites made by polymer-modified concrete and polymer cement slurry have a good thermal insulation property. From the this study, we can recommend the proper mix proportions for thermal insulation Panel or concrete. Expecially. the thermal conductivity of concrete composites made by polyurethane resin is almost the same as that of the conventional expanded polystyrene resin.