• Title/Summary/Keyword: resin composites

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The Biological Functionality of Electro-Galvanized Steels Coated with a Hybrid Composite Containing Pyrethroid

  • Jo, Du-Hwan;Kim, Myung-Soo;Kim, Jong-Sang;Oh, Hyun-Woo
    • Corrosion Science and Technology
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    • v.17 no.2
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    • pp.74-80
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    • 2018
  • The electronic industries require environmentally-friendly and highly functional materials to enhance the quality of human life. Home appliances require insect repellent steels that work to protect household microwave ovens from incurring damage by insects such as fire ants and cockroaches in tropical regions. Thus, POSCO has developed new types of functional steels, coated with an array of organic-inorganic hybrid composites on the steel surface, to cover panels in microwave ovens and refrigerators. The composite solution uses a fine dispersion of hybrid solution with polymeric resin, inorganic and a pyrethroid additive in aqueous media. The hybrid composite solution coats the steel surface, by using a roll coater and is cured using an induction curing furnace on both the continuous galvanizing line and the electro-galvanizing line. The new steels were evaluated for quality performances, salt spray test for corrosion resistance and biological performance for both insect repellent and antimicrobial activity. The new steels with organic-inorganic composite coating exhibit extraordinarily biological functionalities, for both insect repellent and antimicrobial activities for short and long term tests. The composite-coating solution and experimental results are discussed and suggest that the molecular level dispersion of insecticide on the coating layer is key to biological functional performances.

A Study on Fatigue Crack Propagation Behavior in Random Short-Fiber SMC Composites (비규칙 단섬유강화 SMC 복합재료의 피로균열 전파거동에 관한 연구)

  • Kim, Jae-Dong;Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.26 no.2
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    • pp.204-212
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    • 1990
  • The SMC composite, now being considered in certain structural applications, is anticipated to experience repeated loading during service. Thus, understanding of the fatigue behavior is essential in proper use of the composite material. In this paper, using the SMC composite composed of E-glass chopped strand and unsaturated polyester resin three point bending fatigue tests are carried out to investigate the fatigue crack propagating behavior under various cyclic stresses and fatigue damage of various microcrack forms. The following results are obtained from this study; 1) Most of the total fatigue life of the SMC composite is consumed at the initial extension or the growth of the macroscopic crack. 2) A Paris' type power-law relationship between the crack propagation rate and stress intensity factor range is obtained, and the value of material constant m is much higher (m=9~11)than that of other metals. 3) In case of high cyclic stress the fatigue damage show high microcrack density and short crack length, but in case of low cyclic stress does it vice versa. 4) Fatigue damage is characterized by microcrack density, crack length and distribution of crack orientation.

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Performance Evaluation on the Reinforcing Material of Plastic Composites for the Electromagnetic Shielding (전자차폐(電磁遮蔽)를 위한 플라스틱 복합재료용(複合材料用) 강화재(强化材)의 성능평가(性能評價))

  • Kim, Dong-Jin;Murakami, Ri-ichi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.23 no.6 s.165
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    • pp.1048-1054
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    • 1999
  • It is important to study the shielding effectiveness(SE) of reinforcing material of plastic composite materials against the electromagnetic(EM) waves. In this paper, SE of the shielding material of EM waves was investigated with actual experiments. The materials used in this study were made up of film, fiber and powder of conductive materials - Cu, Al, CF etc. Also, The resin film was used as matrix. The experiment was carried out by using a shielding evaluator(Shielding box) TR17302 with an ADVANTEST spectrum analyzer, model R3361C. It was found from the experimental results that copper, aluminum and carbon fiber were good candidates as a shielding material against the EM waves with increasing the SE as the composite was laminated. The characteristics of the SE against the EM waves depended on a mode of preparation of specimen. The effects of interval of wires on the SE were studied when the orientation and the space of Cu wires were changed. The SE strongly depended on the. orientation and the space of the Cu wire. SE decreased as the space of the Cu wires was increasing.

Comparison of fabrication cost of composite bipolar plates for PEM fuel cell: compression molding and machining (PEM 연료전지용 복합재 분리판의 제작비용 비교: 압축성형과 기계식 가공)

  • Lee, Hee-Sub;Chu, Won-Shik;Kang, Yun-Cheol;Kang, Hyuk-Jin;Ahn, Sung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.105-108
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    • 2006
  • The fuel cell is one of the promising environment-friendly energy sources for the next generation. The fuel cell provides good energy efficiency above 40% without pollution or noise. Different fuel cell types are usually distinguished by the kind of electrolyte. Among these, the proton exchange membrane fuel cell (PEMFC) has advantages of high power density. low operating temperature, relatively quick start-up, and rapid response to varying loads. The bipolar plate is a major component of the PEM fuel cell stack, and it takes a large portion of stack volume, weight and cost. In this study, as alternative materials for bipolar plate of PEM fuel cells, graphite composites were fabricated by compression molding and by machining. Graphite particles mixed with epoxy resin were used as the main substance to provide electric conductivity. Flow channels were fabricated by compression molding with design of experiments (DOE) to evaluate moldability. The cost for compression molding of graphite-composite bipolar plate was compared with machining cost to make the same bipolar plate.

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Development of Automotive Structural Part Considering the Formability of Sandwich Panel (샌드위치 판재의 성형성을 고려한 차체 부품의 개발)

  • Choi, Won-Ho;Choi, Bo-Sung;Lee, Dug-Young;Hwang, Woo-Seok
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.4
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    • pp.33-38
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    • 2012
  • Sandwich composite panel with high strength steel face can reduce the weight of the automotive structural parts. Unlike the parts in aerospace application, the automotive parts are made by the forming process for mass production. The CAE simulation can predict the failures caused by forces and deformation during the forming process. Since the material properties are very important factor for the simulation, we performed the tensile test to get the material properties. The inspections by the optical microscope at each strain level show the states of the polymer resin. The material properties measured by the tensile tests are used for the input data of simulation. The simulation predicts the forming process of the bumper back beam very exactly compared with the try out results.

Trends of Technologies for High Performance Polymer Barriers against Radiation (고성능 방사선 고분자 차단막 기술동향)

  • Lee, Gi-Bbeum;Park, Sung-Eun;Kim, In-Woo;Jeong, Kwang-Un;Lee, Hong-Ki;Nah, Chang-Woon
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.94-101
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    • 2011
  • The conventional radiation barriers may show some disadvantages such as heavy weight and possibility of poisoning human bodies because they are composed of lead plates or resin plates containing large amounts of lead powders. Another disadvantage may be direct penetration of radiation through small pin holes. In this article, technologies of multi-layered polymer barriers against radiation, which has been extensively focused recently, will be introduced. A new concept of radiation protection as well as improving endurance with employing nano-layered inorganic particles is introduced.

Characterization of Carbon Composite Bipolar Plates far Polymer Electrolyte Membrane Fuel Cells (고분자 전해질 연료전지용 탄소 복합체 Bipolar Plates의 기체 투과 특성 연구)

  • Hong Seong Uk;Kim Hyun Seon;Choi Won Seok;Kim Jeong Heon
    • Membrane Journal
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    • v.15 no.2
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    • pp.141-146
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    • 2005
  • In this study, carbon composites were prepared using carbon graphite, thermoset resin, and carbon black. Oxygen permeability was measured using the continuous flow gas permeation analyzer as a function of composition and processing conditions. The experimental results showed that the oxygen permeability increased as the carbon black content increased, whereas the oxygen permeability decreased as the pressing time increased. The oxygen permeability was not affected by the processing pressure.

X-ray Photoelectron Spectroscopic Analysis of Modified MWCNT and Dynamic Mechanical Properties of E-beam Cured Epoxy Resins with the MWCNT

  • Lee, Young-Seak;Im, Ji-Sun;Yun, Seok-Min;Nho, Young-Chang;Kang, Phil-Hyun;Jin, Hang-Kyo
    • Carbon letters
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    • v.10 no.4
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    • pp.314-319
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    • 2009
  • The surface treatment effects of reinforcement filler were investigated based on the dynamic mechanical properties of mutiwalled carbon nanotubes (MWCNTs)/epoxy composites. The as-received MWCNTs(R-MWCNTs) were chemically modified by direct oxyfluorination method to improve the dispersibility and adhesiveness with epoxy resins in composite system. In order to investigate the induced functional groups on MWCNTs during oxyfluorination, X-ray photoelectron spectroscopy was used. The thermo-mechanical property of MWCNTs/epoxy composite was also measured based on effects of oxyfluorination treatment of MWCNTs. The storage modulus of MWCNTs/epoxy composite was enhanced about 1.27 times through oxyfluorination of MWCNTs fillers at $25^{\circ}C$. The storage modulus of oxyfluorinated MWCNTs (OF73-MWCNTs) reinforced epoxy composite was much higher than that of R-MWCNTs/epoxy composite. It revealed that oxygen content led to the efficient carbon-fluorine covalent bonding during oxyfluorination. These functional groups on surface modified MWCNTs induced by oxyfluorination strikingly made an important role for the reinforced epoxy composite.

Dielectric Breakdown Characteristics Depending on The Nano Filler of Epoxy Nano-composites (나노 충진제에 따른 에폭시 나노 컴퍼지트의 절연파괴강도 특성)

  • Park, Tae-Hak;Back, Sung-Hak;Lee, Dong-Gun;Park, Hong-Kyu;Jeong, In-Bum;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.92-92
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    • 2010
  • In this paper, the test is performed on MgO, which is used as a filler in epoxy additives, respectively (0, 1.0, 3.0, 5.0, 7.0, 10 [wt%]) for HVDC(high voltage direct current) submarine cable insulating material to improve electrical properties of epoxy resin in high temperature. The breakdown strength due to increasing amount of filler increased to 5.0 [wt%] by the effects of the Coulomb blockade. However, it is confirmed that strength of dielectric breakdown decreased because the filler functioned as impurities and affected the breakdown when filler additive exceeded by 5.0 [wt%] or more. We have found that the highest dielectric breakdown strength of specimen added 5.0 wt% at $25^{\circ}C$, and is more increased approximately 13.7 [%] than virgin specimen.

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Temperature Dependence on dielectric breakdown strength of Epoxy Nano-Composites depending on MgO (MgO를 첨가한 에폭시 나노 컴퍼지트의 절연파괴강도 온도의존성)

  • Jeong, In-Bum;Han, Hyun-Seok;Lee, Young-Sang;Cho, Kyung-Soon;Shin, Jong-Yeol;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.48-48
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    • 2010
  • In this paper, we have investigated temperature dependence of dielectric breakdown voltage at epoxy with added nano-filler(MgO), which is used as a filler of epoxy additives for HVDC(high voltage direct current) submarine cable insulating material with high thermal conductivity and restraining tree to improve electrical properties of epoxy resin in high temperature region. In order to find dispersion of the specimen, the cross sectional area of nano-composite material is observed by using the SEM(Scanning Electron Microscope) and it is conformed that each specimen is evenly distributed without the cohesion. As a result, it is confirmed that the strength of breakdown of all specimen at 50 [$^{\circ}C$] decreased more than that of the dielectric breakdown strength at room temperature. When temperature increases from 50 [$^{\circ}C$] to 100 [$^{\circ}C$], we have confirmed that breakdown strength of virgin specimen decreases, but specimens with added MgO show constant dielectric breakdown strength.

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