• Food Science and Biotechnology
• /
• v.18 no.2
• /
• pp.379-383
• /
• 2009

For an accurate risk assessment of furan, a potential human carcinogen, levels must be determined in human blood plasma using a simple and robust assay. In this study, solid phase microextraction-gas chromatography/mass spectrometry (SPME-GC/MS) was used to analyze blood plasma levels of furan in 100 healthy individuals who consumed a normal diet. The subjects were 30 to 70 years of age and 51% were women. Ultimately, an analytical method was established for analyzing furan in human blood. The limit of quantification (LOQ) and furan recovery rate in blood were 1.0 ppb and 104%, respectively. Finally, furan was detected in 21 individuals (13 males, 8 females) with levels ranging up to 17.86 ppb (ng furan/g food).

• Analytical Science and Technology
• /
• v.10 no.3
• /
• pp.168-178
• /
• 1997

The optimum conditions for the residual analysis of the ethalfluralin herbicide on soils were investigated and the residues in soils were determined by gas chromatography with electron capture detector(GC-ECD). The soil samples extracted with methanol and dichloromethane and concentrated. The concentrated phase were redissolved with toluene and analyzed with GC-ECD after separated by cyanosilica gel Sep-Pak cartridge. From the standard addition experiments with 0.1 and 1.0ppm, the average recoveries were 92.8~101.2% and the detection limit was 0.004ppm. The half-life time of ethalfluralin in the soil(A) was 35 days in the laboratory and 7.2 days in the field test whereas it was 45 days and 9.7 days for each in case of soil(B).

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
• /
• v.2 no.1
• /
• pp.69-78
• /
• 1998

Contents of heavy metals (Cr, Cu, Zn, Cd, and Pb) in the sediments of Ulsan Bay were investigated by the sequential extraction methods that classifies heavy metals into five types of chemical forms: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter and residual. The analytes were determined by using an ICP-MS. Total Cr concentrations in the sediments were in the range of 41.6-96.4, Cu 60.7-680, Zn 189-1954, Cd 33.1-83.4, and Pb 138-567 mg/kg. Results of sequential fractionation indicates that relatively high proportion $(\~44\%)$ of Cu is associated with organic matter A large proportion of Pb is associated with three types of chemical forms: Fe-Mn oxides, organic matter, and residual. There were significant correlation in concentrations between the exchangeable components and total organic carbons. The heavy metals in the residual phase cannot be easily released to the environment since these are bound to the crystal lattice. But, reducible and organic Phases cfn a significant amount of most heavy metals. Therefore. there is potential danger of a substantial amount of metals becoming chemically mobile with environmental changes.

• Journal of Welding and Joining
• /
• v.33 no.6
• /
• pp.60-66
• /
• 2015

Molten zone shape of pulse laser welding is affected by welding conditions such as beam power, beam speed, irradiation time, pulse frequency, etc. and is divided into conduction type and keyhole type. It is necessary to design heat source model for irradiation of laser beam in the pulse laser welding. Shape variables and the maximum energy density value of the heat source model are different depending on the molten zone shape. In this paper, pulse laser welding simulation for joining of cylindrical part and circular cover was carried out. The heat source model for pulse laser beam with circular path was applied to the heat input boundary condition, radiative and conductive heat transfer were considered for the thermal boundary condition. For each phase, thermal and mechanical properties according to temperature were also applied to analysis. Analytical results were in good agreement with the molten zone size of specimen under the same welding conditions. So, the reliability of the welding simulation was verified. Finally, the improvements for reducing residual deformation after cover welding could be reviewed analytically.

• ETRI Journal
• /
• v.39 no.3
• /
• pp.398-405
• /
• 2017

In this paper, an artificial stereo extension method that creates stereophonic sound from a mono sound source is proposed. The proposed method first trains deep neural networks (DNNs) that model the nonlinear relationship between the dominant and residual signals of the stereo channel. In the training stage, the band-wise log spectral magnitude and unwrapped phase of both the dominant and residual signals are utilized to model the nonlinearities of each sub-band through deep architecture. From that point, stereo extension is conducted by estimating the residual signal that corresponds to the input mono channel signal with the trained DNN model in a sub-band domain. The performance of the proposed method was evaluated using a log spectral distortion (LSD) measure and multiple stimuli with a hidden reference and anchor (MUSHRA) test. The results showed that the proposed method provided a lower LSD and higher MUSHRA score than conventional methods that use hidden Markov models and DNN with full-band processing.

• Korean Journal of Pharmacognosy
• /
• v.32 no.3 s.126
• /
• pp.200-211
• /
• 2001

This study was carried out to determine the 11 organochlorine, 7 organophosphorus residual pesticides in 251 crude drugs. These residual pesticides in herbal drugs were extracted with acetonitrile and the extracts were cleaned up via LC-florisil solid phase extraction column. The prepared samples were assayed for pesticide residues using GC-ECD, NPD with capillary column and identified by GC-MSD. Recoveries were $63.9{\sim}111.5%$ in the organochlorine pesticides and $69.8{\sim}92.4%$ in the organophosphorus pesticides, and detection limits were $0.001{\sim}0.65\;ppm$ in the organochlorine pesticides and $0.0009{\sim}0.0074\;ppm$ in the organophosphorus pesticides. Pesticide residues were detected in 9 cases.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.13 no.1
• /
• pp.115-124
• /
• 1989

Near-threshold fatigue crack-growth behavior at room temperature for a duplex stainless steel weldments was investigated to evaluate the effect of load ratio, microstructural change, and residual stresses. Near-threshold fatigue crack propagation behavior is found to show a marked sensitivity to .alpha./.gamma. phase ratio, and little residual stress effects. Threshold values in the heat affected zones are higher than those of base metals and threshold values for crack growth decrease with increasing the load ratio in the base metals and weldments. The fractrographic features in base metals, weldments and heat affectred zones were discussed in terms mechanism of crack growth.

• Nuclear Engineering and Technology
• /
• v.52 no.11
• /
• pp.2552-2564
• /
• 2020

The crevice stress corrosion cracking (SCC) susceptibility of austenitic stainless steels was evaluated in simulated pressurized water reactor (PWR) environments. To simulate the abnormal condition in temporary clamping devices on leaking small bore pipes, crevice bent beam (CBB) tests were performed in the oxygenated as well as hydrogenated conditions. No SCC cracks were found for SS316 in both conditions. SS304 also showed good resistance in the hydrogenated condition. However, all SS304 specimens showed SCC cracks in the oxygenated condition, indicating poor crevice SCC resistance. It was found that residual ferrites were selectively dissolved because of the galvanic corrosion coupled with the neigh-bouring austenite phase, resulting in SCC initiation in SS304. Crack morphologies were mostly transgranular assisted by the damaged δ-ferrite and deformation-induced slip bands.

• Journal of Environmental Science International
• /
• v.2 no.1
• /
• pp.69-78
• /
• 1993

Contents of heavy metals (Cr, Cu, Zn, Cd, and Pb) in the sediments of Ulsan Bay were investigated by the sequential extraction methods that classifies heavy metals into five types of chemical forms: exchangeable, bound to carbonates, bound to Fe-Mn oxides, bound to organic matter and residual. The analyses were determined by using an ICP-MS. Total Cr concentrations in the sediments were in the range of 41.6-96.4, Cu 60.7-680, Zn 189-1954, Cd 33.1-83.4, and Pb 138-567 mg/kg. Results of sequential fractionation indicates that relatively high proportion ( ~44%) of Cu is associated with organic matter. A large proportion of Pb is associated with three types of chemical forms: Fe-Mn oxides, organic matter, and residual. There were significant correlation in concentrations between the exchangeable components and total organic carbons. The heavy metals In the residual phase cannot be easily released to the environment since these are bound to the crystal lattice. But, reducible and organic Phases con a significant amount of most heavy metals. Therefore, there is Potential dancer of a substantial amount of metals becoming chemically mobile with environmental changes.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.13 no.5
• /
• pp.901-910
• /
• 1989

Corrosion fatigue crack propagation behavior of duplex stainless steel weldments in substitute ocean water was investigated to evalulate effects of micro-structural change and residual stresses. Fatigue crack propagation rate was found influenced markedly .alpha./.gamma. phase ratio but little by residual stresses. Fatigue crack propagation rate is higher in the corrosive environment than in room atmosphere. The crack propagation rate estimated by the measurement of striation spacing was higher than that, obtained by crack length measurement in low .DELTK.K region. At hight .DELTK.K region, however, both crack propagation rates were found to be identical.