• Title/Summary/Keyword: repulsive

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Post Ru CMP Cleaning for Alumina Particle Removal

  • Prasad, Y. Nagendra;Kwon, Tae-Young;Kim, In-Kwon;Park, Jin-Goo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.34.2-34.2
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    • 2011
  • The demand for Ru has been increasing in the electronic, chemical and semiconductor industry. Chemical mechanical planarization (CMP) is one of the fabrication processes for electrode formation and barrier layer removal. The abrasive particles can be easily contaminated on the top surface during the CMP process. This can induce adverse effects on subsequent patterning and film deposition processes. In this study, a post Ru CMP cleaning solution was formulated by using sodium periodate as an etchant and citric acid to modify the zeta potential of alumina particles and Ru surfaces. Ru film (150 nm thickness) was deposited on tetraethylorthosilicate (TEOS) films by the atomic layer deposition method. Ru wafers were cut into $2.0{\times}2.0$ cm pieces for the surface analysis and used for estimating PRE. A laser zeta potential analyzer (LEZA-600, Otsuka Electronics Co., Japan) was used to obtain the zeta potentials of alumina particles and the Ru surface. A contact angle analyzer (Phoenix 300, SEO, Korea) was used to measure the contact angle of the Ru surface. The adhesion force between an alumina particle and Ru wafer surface was measured by an atomic force microscope (AFM, XE-100, Park Systems, Korea). In a solution with citric acid, the zeta potential of the alumina surface was changed to a negative value due to the adsorption of negative citrate ions. However, the hydrous Ru oxide, which has positive surface charge, could be formed on Ru surface in citric acid solution at pH 6 and 8. At pH 6 and 8, relatively low particle removal efficiency was observed in citric acid solution due to the attractive force between the Ru surface and particles. At pH 10, the lowest adhesion force and highest cleaning efficiency were measured due to the repulsive force between the contaminated alumina particle and the Ru surface. The highest PRE was achieved in citric acid solution with NaIO4 below 0.01 M at pH 10.

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A Study on Heaping of Granules (알갱이 군의 무더기 현상에 관한 연구)

  • Han, Ji Heum;Han, Won Heum;Lee, Kwang-Hee
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.183-191
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    • 2013
  • In order to elucidate the granular heaping phenomenon, the movement behaviors of 3 different types of granule (millet, sand and thin foil disc) have been investigated by applying the vertical or the rotational vibration to each of the 3 vessels, respectively containing one of the 3 types of granule. In case of vertical vibrations, all of them showed the heaping phenomenon like Gerner's simulation, and that in the order of the millet, sand and thin foil disc, regardlessly of weight. Especially, a heaping of disc granules was proven to be relatively delayed, and that with several small complex clutters. For rotational vibration, the central area of vessel turned out to rise up due to the repulsive force by vessel wall as well as the collision between elastic granules, right after the turning point of vibration. Even spiral pattern was made when the rotational vibration amplitude got higher. From these facts, one can see that the heaping be characterized by the inclusion of attractive granules as well as the vibrational type applied to granule vessel.

Detection of SNPs using electrical biased method on diamond FETs (다이아몬드 FETs에서 전기적 바이어스 방법을 이용한 단일염기 다형성(SNPs) 검출)

  • Song, Kwang Soup
    • Journal of the Institute of Electronics and Information Engineers
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    • v.52 no.3
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    • pp.190-195
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    • 2015
  • The detection of single nucleotide polymorphisms (SNPs) caused of mutant or genetic diseases is important to diagnosis and medicine. There are many methods have been proposed to detect SNPs. However the detection of SNPs is difficulty, because the difference of energy between complementary DNA (cDMA) and SNPs is very small. In this work, we detect the SNPs using field-effect transistors (FETs) which based on the detection of negative charge of DNA. We bias -0.3 V on the drain-source electrode at the target DNA hybridization process. The efficiency of hybridization and the amplitude of signal decrease by repulsive force between negative charge of DNA and negative bias on the electrode. However, the sensitivity of SNPs increases about 5 times from 1.7 mV to 8.7 mV.

A Study on the Numerical Modeling of the Fish Behavior to the Model Net - Fitness Examination of Numerical Model by the Marine Fish - (모형 그물에 대한 어군행동의 수직 모델링에 관한 연구 - 해산어에 의한 수치 모델의 적합성 검토 -)

  • Jang, Ho-Yeong;Lee, Ju-Hui
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.2
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    • pp.174-184
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    • 1998
  • In order to accumulate fundamental. data for control of fishes’ behavior at the real fishing ground, the fitness of the numerical model for describing the behavior of fishes was examined by the marine fish. Mullet, Mugil cephalus were used as experimental fishes. The numerical model of fishes’ behavior presented in our earlier paper was modified on the vertical movement of fish school. For the comparision of parameters of the modified numerical model between mullet and rainbow trout, the estimated values of parameters were identified with dimension. The fitness of the modified numerical model was examined by the comparision between experiment and simulation on the several indexes represented by fishes’ swimming characteristics. The obtained result are summarized a follows : 1. The non-dimensional parameter a’ of propulsive force and kb’ of interactive force by the experiment without model net showed a similarity, but the non-dimensional parameter k sub(c’) of schooling force for rainbow trout was lager than one for mullet and the non-dimensional parameter k sub(w’) of repulsive force for mullet was lager than one for rainbow trout. 2. The non-dimensional parameter a’ and k sub(b’) for rainbow trout by the experiment with model net were a little lager than ones for mullet, but non-dimensional parameter k sub(c’) and k sub(w’) for mullet were lager than ones for rainbow trout. 3. The non-dimensional parameter k sub(c’) and k sub(b’) showed the largest and the smallest value among the non-dimensional parameters for rainbow trout and mullet, respectively. 4. The fitness of the modified numerical model was confirmed by means of the compulsion between experiment and simulation on the swimming trajectory of fishes, the mean distance of individual from wall, the mean swimming speed, the mean swimming depth and the mean distance between the nearest individuals. Especially, the similarity of mean swimming depth was improved by using the modified numerical model.

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Pollution of Agricultural Environment I. Adsorption of Several Herbicide on Soils and Theoretical Evaluation (농업환경(農業環境)의 오염(汚染)과 그 대책(對策) 제(第) 1 보(報) 몇가지 제초제(除草劑)에 의한 토양(土壤) 흡착(吸着)의 이론적분석(理論的分析))

  • Han, Dae-Sung;Kim, Jeong-Je;Shin, Young-Oh
    • Korean Journal of Environmental Agriculture
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    • v.3 no.1
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    • pp.22-29
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    • 1984
  • The Freundlich-type adsorption isotherms were obtained in this study on the adsorption of linuron, bentazon, trifluralin and butachlor by soils. A strong correlation was shown between soil organic matter content and the adsorption of linuron. Soils with high organic matter content adsorbed more linuron. There was no significant correlation between the adsorption of bentazon and clay content. There was a tendency that increase in organic matter content acts against the adsorption of bentazon. Repulsive forces seemed to exist between negatively charged soil particle surfaces and betazon molecules which become weakly charged negative ions in soil solution. Organic matter content and cation exchange capacity appeared to be enhancing the adsorption of trifluralin and butachlor. Clay content was not significantly correlated with the adsorption of these herbicides. Trifluralin was adsorptive to the greatest extent, followed by linuron and butachlor, bentazon being the least.

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Controlled Release Behavior of Bioactive Molecules from Photo-Reactive Hyaluronic Acid-Alginate Scaffolds

  • Nam, Hye-Sung;An, Jeong-Ho;Chung, Dong-June;Kim, Ji-Heung;Chung, Chong-Pyoung
    • Macromolecular Research
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    • v.14 no.5
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    • pp.530-538
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    • 2006
  • There are three important components in tissue engineering: the cells, signaling factors (cytokines and growth factors), and scaffolds. To obtain finely engineered tissue, all three components should perform their individual functions and be fully integrated with each other. For the past few years, we have studied the characteristics of photodimerizable HA (CHA)/alginate (CA) composite materials. CHA/CA complex hydrogels, which were irradiated under UV light and, then treated with calcium ions, were found to have good biocompatibility, mechanical properties and water resistance for implantable tissue scaffolds. In this study, we introduced a cell growth factor (basic fibroblast growth factor; bFGF) into the CHA/CA scaffolds and studied its release behavior. We also introduced tetracycline hydrochloride and flurbiprofen into the same scaffolds as model activation factors and evaluated their release behaviors from the scaffolds. The drug release rate from the materials was influenced by various parameters, such as the degree of crosslinking, the cross linker type, the physico-chemical properties of the drug, and the amount of the drug in the polymer. The results indicated that the negatively charged CHA/CA composite materials showed sustained release behavior and that HA has a particularly strong negative charge, making it attractive toward tetracycline hydrochloride and bFGF, but repulsive toward flurbiprofen.

Fire Resistance of Repaired High Strength Concrete Column Damaged by Fire (화재 피해를 입은 고강도 콘크리트 기둥의 보수공법 변화에 따른 내화특성)

  • Park, Chun-Jin;Back, Dae-Hyun;In, Gi-Ho;Yeo, In-Hwan;Min, Byung-Yeol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.113-116
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    • 2009
  • This study analyzed fire-resistant characteristics according to changes in repair methods of PFH mixed high-strength concrete roof structures having undergone fire damage. The results of the study are as follows. First, as a repulsive characteristics of structures, the remaining repulsion was shown to increase following fire-resistance tests according to increases in depth of coverings. The results of the relationship between depth of coverings and remaining repulsion rates following fire-proofing tests showed a high correlation. At a covering depth of 67.3mm, remaining repulsion rate was estimated to be 100%. For fire-resistant characteristics following repairs of structure, as for spalling, severe separation was shown in the case of general plaster while general plaster + Metal Lath showed overall superior spalling prevention. For internal structure temperatures, general plaster showed max temperatures of 705℃, average temperatures of 636℃ while general plaster + metal lath showed max temperature of 660℃ and average temperature of 520℃, demonstrating lower temperature distributions than use of only general plaster. In conclusion, after removing the covering of structures damaged due to high temperatures of fires within high-strength concrete installations, the use of fire-resistant mortars and applying metal laths on surfaces of general plaster will provide superior fire-resistance performance in the occurrence of a 2nd fire.

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Omni-Directional Magnet Wheel using Magnetic Shield (자기 차폐를 이용한 전방향 자기차륜)

  • Shim, Ki-Bon;Lee, Sang-Heon;Jung, Kwang-Suk
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.9
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    • pp.72-80
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    • 2009
  • When the magnet wheel rotates over a conducting plate, it generates the traction torque as well as the repulsive force on the conducting plate. Partially-cut traction torque results in the linear force into the tangential direction. To cut the traction torque, the concept of magnetic shield is introduced. The direction change of the linear force is realized varying the shielded area of magnetic field. That is, the tangential direction of non-shielded open area becomes the direction of the linear thrust force. Specially a shape of permanent magnets composing the magnet wheel leads to various pattern of magnetic forces. So, to enlarge the resulting force density and compensate its servo property a few simulations are performed under various conditions such as repeated pattern, pole number, radial width of permanent magnets, including shape of open area. The theoretical model of the magnet wheel is derived using air-gap field analysis of linear induction motor, compared with test result and the sensitivity analysis for its parameter change is performed using common tool; MAXWELL. Using two-axial wheel set-up, the tracking motion is tested for a copper plate with its normal motion constrained and its result is given. In conclusion, it is estimated that the magnet wheel using partial shield can be applied to a noncontact conveyance of the conducting plate.

Assessing the anion type effect on the hydro-mechanical properties of smectite from macro and micro-structure aspects

  • Goodarzi, Amir R.;Akbari, Hamid R.
    • Geomechanics and Engineering
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    • v.7 no.2
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    • pp.183-200
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    • 2014
  • The expansivity of clayey soils is a complicated phenomenon which may affect the stability of geotechnical structures and geo-environmental projects. In all common factors for the monitoring of soil expansion, less attention is given to anion type of pore space solutions. Therefore, this paper is concerned with the impact of various concentrations of different inorganic salts including NaCl, $Na_2SO_4$, and $Na_2CO_3$ on the macro and microstructure behavior of the expandable smectite clay. Comparison of the responses of the smectite/NaCl and smectite/$Na_2SO_4$ mixtures indicates that the effect of anion valance on the soil engineering properties is not very pronounced, regardless of the electrolyte concentration. However, at presence of carbonate as potential determining ions (PDIs) the swelling power increases up to 1.5 times compared to sulfate or chloride ions. The samples with $Na_2CO_3$ are also more deformable and show lower osmotic compressibility than the other mixtures. This demonstrates that the barrier performance of smectite greatly decreases in case of anions with the non-specific adsorption (e.g., $Cl^-$ and $SO{_4}^{2-}$) as the salinity of solution increases. Based on the results of the X-ray diffraction and sedimentation tests, the high soil volumetric changes upon exposure to carbonate is attributed to an increase in the repulsive forces between smectite basic unit layers due to the PDI effect of $CO{_3}^{2-}$ and increasing the pH level which enhance the buffering capacity of smectite. The study concluded that the nature of anion through its influence on the re-arrangement of soil microstructure and osmotic phenomena governs the hydro-mechanical parameters of expansive clays. It seems not coinciding with the double layer theory of the Gouy-Chapman double layer model.

Selective Advertisement Transmission System Design Using Smart Sensor

  • Lim, Myung-Jae;Chung, Dong-Kun;Kim, Kyu-Dong;Kwon, Young-Man
    • International journal of advanced smart convergence
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    • v.10 no.4
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    • pp.66-71
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    • 2021
  • In this paper, we sought ways to accept and reject advertisements using the function of a smartphone gyro sensor to enable selective transmission and reception of YouTube advertisements by linking the gyro function of mobile phones. In the case of YouTube advertisements, the skip button is activated after the advertisement is played for a certain period of time (about 5 seconds) before and after the video is played. During the time the advertisement is maintained, it can be used to achieve various goals such as increased website traffic, brand awareness, and sales induction. Since this type of advertisement is not a setting in which the transition takes place immediately, it can be seen as the most suitable setting to strengthen brand awareness. However, due to the nature of the YouTube advertising system, it is often discarded through users' skipping behavior in the process of sharing and reproducing information. Therefore, in this paper, we implemented an optional advertisement transmission system that applies the principle of gyroscope to minimize wasted advertisements and selectively maintain desired advertisements in consideration of the transmission and reception aspects of advertisement broadcasts. It measures rotational repulsive force with directional stability and car wash characteristics, and uses algorithms to identify the slope and angular speed of mobile phones to ensure that advertisements are transmitted and received. Through this, it is expected that advertisement transmission can be performed on the side of an advertisement provider, and selective advertisement reception can be performed on the side of a user.