• Computers and Concrete
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• v.23 no.6
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• pp.421-431
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• 2019

The alarming rate of depletion of natural stone based coarse aggregates is a cause of great concern. The coarse aggregates occupy nearly 60-70% by volume of concrete being produced. Research efforts are on to look for alternatives to stone based coarse aggregates from sustainability point of view. Response surface methodology (RSM) is adopted to study and address the effect of ferrochrome slag (FCS) replacement to coarse aggregate replacement in the ordinary Portland cement (OPC) based concretes. RSM involves three different factors (ground granulated blast furnace slag (GGBS) as binder, flyash (FA) as binder, and FCS as coarse aggregate), with three different levels (GGBS (0, 15, and 30%), FA (0, 15, and 30%) and FCS (0, 50, and 100%)). Experiments were carried out to measure the responses like, workability, density, and compressive strength of FCS based concretes. In order to optimize FCS replacement in the OPC based concretes, three different traditional optimization techniques were used (grey relational analysis (GRA), technique for order of preference by similarity (TOPSIS), and desirability function approach (DFA)). Traditional optimization techniques were accompanied with principal component analysis (PCA) to calculate the weightage of responses measured to arrive at the final ranking of replacement levels of GGBS, FA, and FCS in OPC based concretes. Hybrid combination of PCA-TOPSIS technique is found to be significant when compared to other techniques used. 30% GGBS and 50% FCS replacement in OPC based concrete was arrived at, to be optimal.

• Advances in concrete construction
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• v.12 no.5
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• pp.419-427
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• 2021

The overuse level of cement for civil industry has several undesirable social and ecological consequences. Substitution of cement with industrial wastes, called by-products, such as fly ash, ground granulated blast furnace slag, silica fume, metakaoline, rice husk ash, etc. as the mineral admixtures offers various advantages such as technical, economical and environmental which are very important in the era of sustainability in construction industry. The paper presents the experimental investigations for assessing the mechanical properties of the concrete made using the Pozzolanic waste materials (supplementary cementitious materials) such as fly ash and silica fume as the cement replacing materials. These materials were used in eight trial mixes with varying amount of ordinary Portland cement. These SCMs were kept in equal proportions in all the eight trial mixes. The chemical admixture (High Range Water Reducing Admixture) was also added to improve the workability of concrete. The compressive strengths for 7, 28, 40 and 90 days curing were evaluated whereas the flexural and tensile strengths corresponding to 7, 28 and 40 days curing were evaluated. The study corroborates that the Pozzolanic materials used in the present investigation as partial replacement for cement can render the sustainable concrete which can be used in the rigid pavement construction.

• Journal of Ocean Engineering and Technology
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• v.26 no.3
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• pp.26-32
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• 2012

Recently, concrete using multicomponent blended cement has been required to increase the freeze-thaw and sulfate resistances of concrete structures exposed to a marine environment. Thus, the purpose of this study was to propose the use of concrete containing multicomponent blended cement as one of the alternatives for concrete structures exposed to a marine environment. For this purpose, batches of concrete containing ordinary portland cement (OPC), binary blended cement (OPC-G, G: ground granulated blast slag), ternary blended cement (OPC-GF, F: fly ash), and quaternary blended cement (OPC-GFM, M: mata-kaolin) were made using a water-binder ratio of 50%. Then, the durability levels, including thesulfate and freeze-thaw resistances, were estimated for concrete samples containing OPC, OPC-G, OPC-GF, and OPC-GFM. It was observed from the tests that the durability levels of the concrete samples containing OPC-G and OPC-GF were found to be much better than that of the concrete containing OPC. The optimum mixing proportions were a40% replacement ratio of ground granulated blast slag for the binary blended cement and a30% replacement ratio of ground granulated blast slag and 10% fly ash for the ternary blended cement.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.190-198
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• 2002

In this research the physical properties of polymer modified mortar containing pulverized FRP(Fiber-Reinforced Plastics) wastes fine powder as a part of fine aggregate were investigated. Styrene-butadiene rubber(SBR) latex, polyacrylic ester(PAE) emulsion and ethylene-vinyl acetate(EVA) emulsion were used as Polymer modifier. Polymer modified mortars containing FRP wastes fine powder were prepared with various FRP wastes fine powder replacement(5∼30 wt％) for fine aggregate and polymer-cement ratios(5∼20 wt％). The water-cement ratio, water absorption rates and hot water immersion test, compressive and flexural strengths of polymer modified mortars were tested and the results compared to those of ordinary portland cement mortar. As the results, compressive and flexural strengths of polymer modified mortar containing FRP wastes fine powder depend on the contents of FRP wastes fine powder, type and additional amounts of polymer modifier. Some of them showed higher compressive and flexural strengths than those of ordinary portland cement mortar. Especially, SBR-modified mortar showed the highest strengths properties among three types of polymer modifier. Also water absorption rates, compressive and flexural strengths of SBR-modified mortar were more superior than those of PAE or EVA-modified mortar. The optimum mix proportions of SBR-modified mortar was 20 wt％ of polymer-cement ratio and 20 wt％ of FRP wastes fine powder replacement. Otherwise heat cured polymer modified mortar accelerated the improvement of early compressive and flexural strengths.

• Journal of the Korean Ceramic Society
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• v.53 no.2
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• pp.234-240
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• 2016

Energetically-modified material using reject fly ash (RFA), generated from thermal power plants, was manufactured to investigate the effect of the material on the physical and chemical characteristics of cement mortar. In order to modify reject fly ash, a vibration mill was used. Particle size, grain shape, and crystal structure of the ash were analyzed. Then, the compressive strength of the mortar using energetically-modified reject fly ash (ERFA) was measured. Microstructure and X-ray diffraction (XRD) patterns were also used in the analysis. As the replacement rate of ERFA increased, the value of the compressive strength tended to decrease. However, it was found that the compressive strength values of 7 and 28 days-cured specimens were higher than those of conventional ordinary Portland cement (OPC) mortar with 10 % replacement rate condition.

• Resources Recycling
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• v.33 no.3
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• pp.12-20
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• 2024

The global cement industry emits approximately 2.9 billion tons of greenhouse gases, of which 1.74-1.89 billion tons are emitted from limestone, which is the main raw material for clinkers. Therefore, the feasibility of using slag, a non-carbonated CaO-based raw material, must be investigated, and the physical properties of cement must be considered. In this study, the mixing ratios of the raw mix and properties of cement were analyzed. The CaCO₃ replacement ratio was limited when one type of slag was used; however, when the mixed slag was utilized, the CaCO₃ replacement ratio increased by more than 12 %. The compressive strength of the slag-incorporated cement was lower than that of Ordinary Portland Cement (OPC). Therefore, the lime saturation factor (LSF) of the raw mix and fineness of the cement were increased to improve the compressive strength. The compressive strength of cement with improved fineness was similar to that of OPC for a CaCO₃ replacement ratio of up to 6 %, and it decreased as the CaCO₃ replacement ratio was increased to 9 %. When both fineness and LSF were increased, the compressive strength and flow value of the cement with a CaCO₃ replacement ratio of 12 % were similar to that of OPC.

• International Journal of Concrete Structures and Materials
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• v.8 no.1
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• pp.15-26
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• 2014

In order to study the capacities of a new occurrence of Brazilian clay samples as partial replacements of cement, a bentonite sample was selected for utilization in the natural and modified forms for present study. The natural bentonite (BBT) was modified by anchorament of 3-aminopropyltrietoxisilane ($BBT_{APS}$) and 3,2-aminoethylaminopropyltrimetoxisilane (BBTAEAPS) in the surface of component minerals of bentonite sample. The original and organo-bentonite samples were characterized by elemental analysis, scanning electron microscopic and textural analyses. The values of micropore area were varying from $7.2m^2g^{-1}$ for the BBT to $12.3m^2g^{-1}$ for the $BBT_{AEAPS}$. The bentonite samples were characterized by the main variable proportion of bentonite in the natural and intercalated forms (2, 5, 10, 15, 20, 25, 30, and 35 % by weight of cement) in the replacement mode whiles the amount of cementations material. The workability, density of fresh concrete, and absorption of water decreased as the substitution of ordinary Portland cement by perceptual of natural and modified bentonite increased. The results reveal that workability decreased with decrease of the amount of natural bentonite in the concrete, same behavior is observed for bentonite functionalized, varying from 49 to 28 mm. The energetic influence of the interaction of calcium nitrate in the structure of blends was determined through the calorimetric titration procedure.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.12 no.3
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• pp.81-90
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• 1992

This study gives results of 1aboratory investigations to minimize the slump loss of concrete using high range water reducing admixture (HRWR). Various factors influencing on the slump loss such as cement type, HRWR type and dosage time are investigated. The acquired results indicated that 30 minutes delayed dosage of HRWR is very effective on reducing the slump loss though this tendency makes a difference to some extent according to cement and HRWR type. For the most part, the more usage of HRWR increases, the higher the slump loss occurs and concrete using ordinary portland cement has the highest slump loss and concrete using fly ash 20% replacement cement with HRWR of naphthalene type has the good effect on reducing the slump loss.

• Advances in concrete construction
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• v.7 no.4
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• pp.263-275
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• 2019

In the present work, Granulated Blast Furnace Slag (GBFS) and Fly ash (FA) were used as partial replacement of Natural Sand (NS) and Ordinary Portland Cement (OPC) by weight. One control mix, one with GBFS, three with FA and three with GBFS-FA combined mixes were prepared. Replacements were 50% GBFS with NS and 20%, 30% and 40% FA with OPC. Preliminary investigation on development of compressive strength was carried out at 7, 28 and 90 days to ensure sustainability of waste materials in concrete matrix at room temperature. After 90days, thermo-mechanical study was performed on the specimen for a temperature regime of $200^{\circ}-1000^{\circ}C$ followed by furnace cooling. Weight loss, visual inspection along with colour change, residual compressive strength and microstructure analysis were performed to investigate the effect of replacement of GBFS and FA. Although adding waste mineral by-products enhanced the weight loss, their pozzolanicity and formation history at high temperature played a significant role in retaining higher residual compressive strength even up to $800^{\circ}C$. On detail microstructural study, it has been found that addition of FA and GBFS in concrete mix improved the density of concrete by development of extra calcium silicate gel before fire and restricts the development of micro-cracks at high temperature as well. In general, the authors are in favour of combined replacement mix in view of high volume mineral by-products utilization as fire protection.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.115-125
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• 2015

This study investigated the fluidity, heat of hydration, setting time, strength development, and characteristics of hydration and pozzolanic reactions of high-strength high-volume ground granulated blast-furnace slag(GGBFS) blended cement pasts with the water-to-binder ratio of 20% by experiments, and analyzed the effects of the replacement ratio and fineness of GGBFS on the hydration and pozzolanic reaction. The results show that, in the high-strength mixtures with low water-to-binder ratio, the initial hydration is accelerated due to the "dilution effect" which means that the free water to react with cement increases by the replacement of cement by GGBFS, and thus, strengths at from 3 to 28 days were higher than those of plain mixtures with ordinary Portland cement only. Whereas it was found that the long term strength development is limited because the hydration reaction rates rapidly decreases with ages and the degree of pozzolanic reaction is lowered due to insufficient supply of calcium hydroxide according to large replacement of cement by GGBFS. Also, the GGBFS with higher fineness absorbs more free water, and thus it decreases the fluidity, the degree of hydration, and strength. These results are different with those of normal strength concrete, and therefore, should be verified for concrete mixtures. Also, to develop the high-strength concrete with high-volume of GGBFS, the future research to enhance the long-term strength development is needed.