• Title/Summary/Keyword: removal properties

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Effect of Crystal Orientation on Material Removal Characteristics in Sapphire Chemical Mechanical Polishing (사파이어 화학기계적 연마에서 결정 방향이 재료제거 특성에 미치는 영향)

  • Lee, Sangjin;Lee, Sangjik;Kim, Hyoungjae;Park, Chuljin;Sohn, Keunyong
    • Tribology and Lubricants
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    • v.33 no.3
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    • pp.106-111
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    • 2017
  • Sapphire is an anisotropic material with excellent physical and chemical properties and is used as a substrate material in various fields such as LED (light emitting diode), power semiconductor, superconductor, sensor, and optical devices. Sapphire is processed into the final substrate through multi-wire saw, double-side lapping, heat treatment, diamond mechanical polishing, and chemical mechanical polishing. Among these, chemical mechanical polishing is the key process that determines the final surface quality of the substrate. Recent studies have reported that the material removal characteristics during chemical mechanical polishing changes according to the crystal orientations, however, detailed analysis of this phenomenon has not reported. In this work, we carried out chemical mechanical polishing of C(0001), R($1{\bar{1}}02$), and A($11{\bar{2}}0$) substrates with different sapphire crystal planes, and analyzed the effect of crystal orientation on the material removal characteristics and their correlations. We measured the material removal rate and frictional force to determine the material removal phenomenon, and performed nano-indentation to evaluate the material characteristics before and after the reaction. Our findings show that the material removal rate and frictional force depend on the crystal orientation, and the chemical reaction between the sapphire substrate and the slurry accelerates the material removal rate during chemical mechanical polishing.

Preparation of chitosan, sunflower and nano-iron based core shell and its use in dye removal

  • Turgut, Esra;Alayli, Azize;Nadaroglu, Hayrunnisa
    • Advances in environmental research
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    • v.9 no.2
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    • pp.135-150
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    • 2020
  • Many industries, such as textiles, chemical refineries, leather, plastics and paper, use different dyes in various process steps. At the same time, these industrial sectors are responsible for discharging contaminants that are harmful and toxic to humans and microorganisms by introducing synthetic dyes into wastewater. Of these dyes, methylene blue dye, which is classified as basic dyes, is accepted as a model dye. For this reason, methylene blue dye was selected in the study and its removal from the water was studied. In this study, two efficient biosorbents were developed from chitosan and sunflower waste, an agro-industrial waste and modified using iron nanoparticles. The biosorption efficiency was evaluated for methylene blue (MB) dye removal from aqueous solution under various parameters such as treating agent, solution pH, biosorbent dosage, contact time, initial dye concentration and temperature. We investigated the kinetic properties of dye removal from water for Chitosan-Sunflower (CS), Chitosan-Sunflower-Nanoiron (CSN). When the wavelength of MB dye was spectrophotometrically scanned, the maximum absorbance was determined as 660 nm. For the core shell biosorbents we obtained, we found that the optimum time for removal of MB from wastewater was 60 min. The pH of the best pH was determined as 5 in the studied pH. The most suitable temperature for the experiment was determined as 30℃. SEM-EDAX, TEM, XRD, and FTIR techniques were used to characterize biosorbents produced and modified in the experimental stage and to monitor the change of biosorbent after dye removal. The interactions of the paint with the surface used for removal were explained by these techniques. It was calculated that 80% of CS and 88% of CSN removed MB in optimum conditions. Also, the absorption of MB dye onto the surface was investigated by Langmiur and Frendlinch isotherms and it was determined from the results that the removal was more compatible with Langmiur isotherm.

CMP Properties of Oxide Film with Various Pad Conditioning Temperatures (CMP 패드 컨디셔닝 온도에 따른 산화막의 연마특성)

  • Choi, Gwon-Woo;Kim, Nam-Hoon;Seo, Yong-Jin;Lee, Woo-Sun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.4
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    • pp.297-302
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    • 2005
  • Chemical mechanical polishing(CMP) performances can be optimized by several process parameters such as equipment and consumables (pad, backing film and slurry). Pad properties are important in determining removal rate and planarization ability of a CMP process. It is investigated the performance of oxide CMP process using commercial silica slurry after the pad conditioning temperature was varied. Conditioning process with the high temperature made the slurry be unrestricted to flow and be hold, which made the removal rate of oxide film increase. The pad became softer and flexible as the conditioning temperature increases. Then the softer pad provided the better surface planarity of oxide film without defect.

Study on the Strength Development of Fly ash Replace Concrete by a In-situ Temperature System (온도추종 양생 장치에 의한 플라이애쉬 치환 콘크리트의 강도 발현 성상)

  • Lee, Gun-Cheol;Yoon, seung-joe;Lee, Gun-Young;Choi, Jung-Gu;Kim, Kyoung-Min
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.126-127
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    • 2014
  • At construction sites, due to the reason of inconvenience and difficulties of producing and using curing equipment and when it comes to measuring compression strength of the actual structure, strength of structure concrete according to general standards which are suggested in concrete standard specification are assessed. However, this method does not consider various variables of the sites such as kinds concretes and sizes of frame works so that it is not easy to measure proper curing period and strength. Thus, this study reviews description of strength development according to In-situ temperature system and analyzes and compares properties of strength development of the existing curing methods such as sealing curing so that it provides basic materials for period of removal of molds.

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Evaluation of Physical Properties and Adsorption Capacity of Regeneration GAC (재생 활성탄의 물성 및 흡착능 평가)

  • Mun, Ji-Young;Chae, Seon-Ha;Wang, Chang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.4
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    • pp.407-416
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    • 2009
  • The objective of this study was to evaluate the variation of physical properties and adsorption capacity after regeneration of Granular Activated Carbon (GAC). It was found that the loss rate of regenerated carbon was related to the usage time of GAC. The correlations between iodide number and loss rate also determined. Effective size and uniformity coefficient for regenerated GAC were within a similar range compared to virgin GAC. This result indicated that the function as media is recovered. Although iodide number and specific surface area for regenerated GAC were not completely recovered compared to that of virgin GAC, cumulative pore volumes of regenerated GAC were increased. Removal efficiency of organic matter in regenerated GAC was resulted the same or slightly higher than that of virgin GAC. This result indicates that the number of mesopore responsible for removal of organic matter was increased after regeneration.

Thermal Properties of Ploymide Nanocomposite (전력용 Nanocomposite의 열화학 특성)

  • Lee, Sang-Heon
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.44-45
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    • 2006
  • We have fabricated superconductor ceramics by chemical process. A high Tc superconductor with a nominal composition of ${Bi_2}{Sr_2}{Ca_2}{Cu_3}{O_y}$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductorphase may be the most important factor. The relation between electromagnetic properties of Bi HTS and external applied magnetic field was studied. The electrical resistance of the superconductor was increased by the application of the external magnetic field. But the increase in the electrical resistance continues even after the removal of the magnetic field. The reason is as followsthe magnetic flux due to the external magnetic field penetrates through the superconductor and the penetrated magnetic flux is trapped after the removal of the magnetic flux.

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Properties of Cement Mortar with Graphene-Titanium Dioxide Composite Nanowires (그래핀-이산화티탄 복합 나노와이어를 혼입한 모르타르의 물성 평가)

  • Lee, Jun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.118-119
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    • 2021
  • The properties of cement mortar with graphene-titanium dioxide composite nanowires (TiO2(G)NW) were investigated in this study. The following tests were conducted with the cement mortar : (1) setting times (2) Flow test of fresh cement mortar, (3) compressive strength and (4) acetaldehyde removal efficiency under visible light. As the increase of TiO2(G) NW, the flow value of cement mortar was decreased and the setting times of cement mortar were faster. The compressive strength and the acetaldehyde removal efficiency were increased by the increase of TiO2(G) NW.

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Comparative investigation of activated porous carbons treated by silver electroplating from aqueous solution

  • Oh, Won-Chun
    • Analytical Science and Technology
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    • v.19 no.3
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    • pp.226-238
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    • 2006
  • The electroplating of the Ag ions from aqueous solution on activated porous carbons was investigated over a wide range of plating time. The adsorption capacities of Ag metallic carbons were associated with their internal porosity and were related to physical properties such as surface area and pore size distribution. And, surface morphologies and quantitative analysis for the metal supported carbons are investigated by scanning electron microscopy (SEM) and energy disperse X-ray (EDX) measurements to explain the changes in adsorption properties. It is considered that the pH is an very important factor at the reason of water pollutant with increasing acidity in industrial field. The results of ICP-AES analysis showed that the residual concentration of Ag ions decreased with an increasing electroplating time. The metallic Ag-activated porous carbons electroplated showed microbicidal effects and strong antibacterial activity against six kinds of strains that were used. Finally, we confirmed that the presence of the electrolytic plated Ag-activated porous carbons is a determining factor in the HCl removal by chemical reaction, clarifying the surface chemical behavior.

Fabrication of carboxymethyl functionalized Euryale ferox starch-based hydrogel for efficient removal of methylene blue

  • Xue-Li Liu;Zhong-Zhu Hu;Ya-Li Sun;Chun-Feng Zhu
    • Membrane and Water Treatment
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    • v.15 no.3
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    • pp.131-137
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    • 2024
  • Euryale ferox Salisb. is an important plant resource and valuable tonic in traditional Chinese medicine. The seed of Euryale ferox Salisb. is rich in starch. There are few reports of modification and functional properties of Euryale ferox starch. In present study, the Euryale ferox starch was extracted, carboxymethyl etherified starches were synthesized, the starch-based hydrogels were prepared, and adsorptive properties were investigated. The results of investigation showed that carboxymethyl etherified Euryale ferox starch-based adsorbent has the potential for methylene blue removal. Therefore, Euryale ferox starch has an appealing application prospect in adsorption for scavenging dyes from real complex waste liquid.