• Korean Journal of Soil Science and Fertilizer
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• v.50 no.6
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• pp.574-587
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• 2017

Excessive application of nitrogen (N) fertilizer to support switchgrass growth for bioenergy production may cause adverse environmental effects. The objective of this study was to determine optimum N application rate to increase biomass yield of switchgrass and to reduce adverse environmental effects related to N. Switchgrass was planted in May 2008 and biomass yield, N uses of switchgrass, nitrate ($NO_3$) leaching, and nitrous oxide ($N_2O$) emission were evaluated from 2010 through 2011. Total N removal significantly increased with N rate despite the fact that yield did not increased with above $56kg\;N\;ha^{-1}$ of N rate. Apparent nitrogen recoveries were 4.81 and 5.48% at 56 and $112kg\;N\;ha^{-1}$ of N rate, respectively. Nitrogen use efficiency decreased into half with increasing N rate from 56 to $112kg\;N\;ha^{-1}$. Nitrate leaching and $N_2O$ emission were related to N use of switchgrass. There was no significant difference of cumulative $NO_3$ leaching between 0 and $56kg\;N\;ha^{-1}$ but, it significantly increased at $112kg\;N\;ha^{-1}$. There was no significant difference of cumulative $N_2O$ emission among N rates in crest, but it significantly increased at $112kg\;N\;ha^{-1}$ in toe. Excessive N application rate (above $56kg\;N\;ha^{-1}$) beyond plant requirement could accelerate $NO_3$ leaching and $N_2O$ emission in switchgrass field. Overall, $56kg\;N\;ha^{-1}$ might be optimum N application rate in reducing economic waste on N fertilizer and adverse environmental impacts.

• Korean Journal of Ecology and Environment
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• v.33 no.3 s.91
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• pp.295-303
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• 2000

The water clarification efficiency was examined in a shallow wetland where dense vegetation was formed naturally in an abandoned paddy field. And, also two enclosure experiments were carried out to measure the effects of materials exchange between sediment and the overlying water with the existence of vegetation and accumulated litter. The hydraulic retention time of wetland was regulated in 1.2 day. The removal rates of SS (56%) and $NO_3-N$ (61%) were high, considering its short retention time. However, removal efficiencies of VSS (28%), COD (14%), DOC (1%),and TP (0.2%) were relatively lower. This low removal efficiencies were thought to be due to the release of dissolved form of organic matter and phosphorus from the sediment. Most of constituents except nitrate were higher in the enclosure at the beginning of enclosure installation than that of the outflowing water from wetland. And then, it has fluctuated and decreased with time. The wetland was in equilibrium state of settling, accumulation of organic debris, and regeneration of dissolved material from sediment. So ultimately high primary production by dense vegetation in the wetland may be the reason of unfavorable or low treatment efficiency of wetland after many years of operation for wastewater treatment. However, the water quality of effluent from the wetland showed smaller variation and better condition than that of inflow, especially during storm events. It can be concluded that this wetland is suitable for the improvement of water quality from nonpoint sources.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.41 no.4
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• pp.399-404
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• 2021

From 1 January 2020, the limit for Sulphur in fuel oil used on board ships operating outside designated emission control areas will be reduced to 0.5 %. This regulation by international maritime organization (IMO) is able to significantly reduce the amount of Sulphur oxides (SOx) discharging from ships and should have environmental advantages and health for all over the world. To meet the regulation, in these days, wet scrubber system is being actively developed. However, this process leads to make washing wastewater. In this study, we evaluated ion exchange resin system in accordance with scrubber wastewater discharge regulation by IMO. Theoretical wastewater used as feed solution of lab scale water treatment systems. The results revealed that nitrate ion was removed selectively in spite of high TDS wash wastewater solution depending on ion exchange resin property. Moreover, it was possible to improve efficiency of the system by optimizing operating conditions.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2207-2219
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• 2018

Activated carbon (AC) was synthesized from Phoenix dactylifera stones and then modified by $CoFe_2O_4$ magnetic nanocomposite for use as a Cr(VI) adsorbent. Both $AC/CoFe_2O_4$ composite and AC were fully characterized by FTIR, SEM, XRD, TEM, TGA, and VSM techniques. Based on the surface analyses, the addition of $CoFe_2O_4$ nanoparticles had a significant effect on the thermal stability and crystalline structure of AC. Factors affecting chromium removal efficiency like pH, dosage, contact time, temperature, and initial Cr(VI) concentration were investigated. The best pH was found 2 and 3 for Cr adsorption by AC and $AC/CoFe_2O_4$ composite, respectively. The presence of ion sulfate had a greater effect on the chromium sorption efficiency than nitrate and chlorine ions. The results illustrated that both adsorbents can be used up to seven times to adsorb chromium. The adsorption process was examined by three isothermal models, and Freundlich was chosen as the best one. The experimental data were well fitted by pseudo-second-order kinetic model. The half-life ($t_{1/2}$) of hexavalent chromium using AC and $AC/CoFe_2O_4$ magnetic composite was obtained as 5.18 min and 1.52 min, respectively. Cr(VI) adsorption by AC and $AC/CoFe_2O_4$ magnetic composite was spontaneous and exothermic. In general, our study showed that the composition of $CoFe_2O_4$ magnetic nanoparticles with AC can increase the adsorption capacity of AC from 36 mg/L to 70 mg/L.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.11
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• pp.855-859
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• 2011

The main pollutants from zirconium alloy tubing manufacturing process in nuclear industry are nitrate ($NO_3-N$) and fluoride (F-)Nitric acid, and hydrofluoric acid is used for acid pickling. The process for the removal of nitrate and fluoride is composed of 1st chemical coagulation, SOD (Sulfur Oxidation Denitrification) process using sulfur-oxidizing denitrification, and 2nd chemical coagulation. The characteristic of the wastewater treatment is an application of SOD process. The SOD Process is highly received attention because it is significantly different from existing processes for sulfur denitrification. A JSC (JeonTech-Sulfur- Calcium) Pellet is unification of sulfur and alkalinity material. According to result of SOD process in wastewater treatment plant, the removal efficiency of T-N was over 91% and the average concentration of T-N from influent was 147.55 mg T-N/L and that from effluent was 12.72 mg T-N/L. Therefore, SOD process is a useful to remove nitrogen from inorganic industrial wastewater and a new development of microbial activator was shown to be stable for activation of autotrophic bacteria.

• Journal of Environmental Science International
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• v.13 no.10
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• pp.911-919
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• 2004

The purpose of this research was evaluated economical effect to apply alternative external carbon source. Conventional activated sludge process in municipal wastewater treatment plant was adapted and introduced to Biological nutrient removal processes to meet the newly enforced effluent quality standard for nutrient removal in Korea. Low $COD/NH_4^+-N$ ratio and higher nutrient concentration of influent characteristics force to inject external carbon source for denitrifying recycled nitrate. In the most case, methanol was used as external carbon source. But Methanol is expensive and very dangerous in handling. So we could find cheaper and safer external carbon source substituted methanol in last study. This alternative external carbon source is named RCS(recoverd carbon source) and a by-product of fine chemical product at chemical plant. When RCS was applied real municipal wastewater treatment plant, average $55\~65\%$ of T-N removal efficiency, 8.8mg/l of effluent T-N concentration, 11.3mg/l of effleunt COD concentration were obtained without effluent COD increase as against used methanol. To apply RCS in municipal wastewater treatment plant obtain approximately $\74.5%$ expenditure cost reduction in comparison with methanol dosage cost.

• Journal of Aquaculture
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• v.10 no.3
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• pp.335-346
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• 1997

Denitrification is one of the important processes of removing nitrate from in recirculating aquaculture systems. And this process is affected by many factors such as external organic carbon sources, hydraulic retention time (HRT), COD/NO3--N (C:N) ratio, etc. However, not many studies were done for the optimum conditions of denitrification in the recirculation system for aquaculture. Therefore, this study was conducted to find out the optimum removal condition of NO3--N using submerged denitrification biofilter. The combinations of two external organic carbon sources (glucose and methanol), two HRT (4 and 8-hour) and four differnent C : N ratios (3, 4, 5, 6) were tested. The removal efficiencies of NO3--N and total inorganic nitrogen (TIM) at 8-hour HRT were better than those at 4-hour's (P<0.05). The maximum removal efficiency of NO3--N by methanol (97.8%) was achieved at HRT and C : N ratio were 8-hour and 4.0 respectively. The efficiencies of methanol for the removal of NO3--N and TIN were always better than those of glucose (P<0.05). The maximum removal efficiencies of total inorgainc nitrogen (TIN) were gained at C : N ration of 5.0. The maximum removel efficiencies of TIN using methanol and glucose were 96.9% and 71.5% respectively. Anaerobic condition which is necessary for denitrification process was not made until the 8-hour HRT and higher C : N ratio (5.0). Removal of NO3--N at 4-hour HRT and C : N ration lower than 5.0 were inhibited by oxygen and/or low quantity of external organic carbon. Removal efficiencies of NO3--N were also inhibited by high C : N (6.0) ratio when HRT was 8-hour.

• Journal of Microbiology and Biotechnology
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• v.13 no.2
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• pp.207-216
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• 2003

A number of different sources, such as composts, leachates, and pig feces samples, were collected from different pig farms in Korea, and several microorganisms were screened for their ability to deodorize the malodorous gases. Consequently, a novel malodorous gases-deodorizing bacterial strain, KJ-108. was isolated, because it was highly abundant in nitrate-supplemented minimal medium ($MM-NO_3^-$) under anaerobic culture conditions. Airtight crimp-sealed serum bottles containing $MM-NO_3^-$ , medium were inoculated with KJ-108. Nitrate concentration was decreased rapidly after 20 h of incubation, and incubation was carried out until nitrite production reached almost zero. Taxonomic identification, including 16S rDNA base sequencing and phylogenetic analysis, indicated that the isolate had $100\%$ homology in its 165 rDNA base sequence with Lactobacillus pentosus. Among the volatile fatty acids, acetic acid contained in large amounts in fresh piggery slurry was decreased by about $40\%$ after 50 h incubation with strain KJ-108. n-Butyric acid, n-valeric acid, and isovaleric acid were gradually decreased, and isobutyric acid and capronic acid were dramatically eliminated at theinitial period with the treatment. Moreover, NH, removal efficiency reached a maximum of $98.5\%$ after 50 h of incubation, but the concentration of $H_2S$ was not changed.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.5
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• pp.480-486
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• 2006

On account of exchanging main process from chemical precipitation for MLE(Modified Ludzark-Ettinger), an external carbon source was required for supplementation of carbon source shortage that was needed biological denitrification in the S sewage treatment plant(S-STP). In this study, NUR(nitrate uptake rate), OUR(oxygen uptake rate) test and a field application test was conducted for the applicability assessment of Terephtalic acid(TPA) by-product contained about 4.7% acetate as alternative external carbon source. As the results, TPA by-product shows more rapid acclimation than methanol, 8.24 mg ${NO_3}^--N/g$ VSS/hr specific denitrification rate, 3.70 g $COD_{Cr}/g\;NO_3$ C/N ratio and 99.4% readily biodegradable COD contents. In the results of field application, the nutrient removal efficiency was high and effluent T-N concentration is 8.2 mg/L. It is concluded that TPA by-product is the proper alternative external carbon source.

• KSBB Journal
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• v.15 no.1
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• pp.14-21
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• 2000

In this study, algae cultivation using the photobioreactor has been applied to remove the nitrogen and phosphorus compounds in the wastewater of the livestock industry. The optimal ratio of nitrate and ortho-phosphate concentration was found for the enhancement of removal efficiency. To achieve the high density culture of algae, the photobioreactor consisted of optical fibers wes developed to get the sufficient light intensity. The light could be illuminated uniformly from light source to the entire reactor by the optical fibers. The structured kinetic model was proposed to describe the growth rate, consumption rate of nitrates and ortho-phosphates in algae culture. The self-organizing fuzzy logic controller incorporated with genetic algorithm was constructed to control the semi-continuous wastewater treatment system. The proposed fuzzy logic controller was applied to maintain the nitrated concentration at the given set-point with the control of wastewater feeding rate. The experimental results showed that the self-organizing fuzzy logic controller could keep the nitrate concentration and enhance algae growth.