• Journal of Korean Society of Environmental Engineers
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• v.36 no.11
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• pp.771-780
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• 2014

In this study, the various organic supports (i.e., silicone, acrylonitrile-butadiene-styrene, epoxy, and, butadiene rubber) with great sorption capacity of organic contaminants were chosen to develop nano-ZnO/organic composites (NZOCs) and to prevent the detachment of nano-ZnO particles. The water resistance of the developed NZOCs were evaluated, and the feasibility of the developed NZOCs were investigated by evaluating the removal efficiency of 1,1,2-trichloroethylene (TCE) in the aqueous phase. Based on the results from water-resistance experiments, long-term water treatment usage of all NZOCs was found to be feasible. According to the FE-SEM, EDX, and imaging analysis, nano-ZnO/butadiene rubber composite (NZBC) with various sizes and types of porosity and crack was measured to be coated with relatively homogeneously-distributed nano-ZnO particles whereas nano-ZnO/silicone composite (NZSC), nano-ZnO/ABS composite (NZAC), and nano-ZnO/epoxy composite (NZEC) with poorly-developed porosity and crack were measured to be coated with relatively heterogeneously-distributed nano-ZnO particles. The sorption capacity of NZBC was close to 60% relative to the initial concentration, and this result was mainly attributed to the amorphous structure of NZBC, hence the hydrophobic partitioning of TCE to the amorphous structure of NZBC intensively occurred. The removal efficiency of TCE in aqueous phase using NZBC was close to 99% relative to the initial concentration, and the removal efficiency of TCE was improved as the amount of NZBC increased. These results stemmed from the synergistic mechanisms with great sorption capability of butadiene rubber and superior photocatalytic activities of nano-ZnO. Finally, the removal efficiency of TCE in aqueous phase using NZBC was well represented by linear model ($R^2{\geq}0.936$), and the $K_{app}$ values of NZBC were from 2.64 to 3.85 times greater than those of $K_{photolysis}$, indicating that butadiene rubber was found to be the suitable organic supporting materials with enhanced sorption capacity and without inhibition of photocatalytic activities of nano-ZnO.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.7
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• pp.418-425
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• 2015

Anaerobic Filters (AF) packed with porous ceramic floating media were operated at different operational conditions to identify the feasibility of the renewable bioenergy, methane production from swine wastewater and to verify the suitability of effluent from anaerobic filters for the subsequent biological nitrogen and phosphorus removal. Stepwise increase in organic loading rates (OLRs) or decrease in hydraulic retention times (HRTs) with influent TCOD concentration of 14,000 mg/L were utilized at mesophilic temperature. The maximum methane productivity of 1.74 volume of $CH_4$ per volume of reactor per day (v/v-d) was achieved at an hydraulic retention time (HRT) of 0.5 day (OLR 28 g TVS/L-d). Based on the biogas production, the highest total volatile solids (TVS) removal efficiency of 63% was obtained at an HRT of 3 days (OLR 4.67 g TVS/L-d), however based on the result from the effluent total chemical oxygen demand (TCOD) analysis, the highest TCOD removal efficiency of 75% was achieved. The effluent alkalinity concentration over the range of 2,050~2,980 mg/L as $CaCO_3$ at all operational conditions, could compensate the alkalinity destruction caused by nitrification. The effluent from the anaerobic filter operated under the HRT of 2 days showed the COD/TKN ratio of 15~35 and COD/TP ratio of 38~56. Therefore effluent C/N/P ratio is able to satisfy the optimum COD/TKN ratio of greater than 8.0 and COD/TP ratio of 33 for the subsequent biological nutrient removal.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.3
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• pp.359-370
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• 2015

This study developed an up-flow wetland providing either an eco-friendly follow-up process of medium-sized public treatment facility for livestock manure or a non-point source pollution controller near livestock farms. The four bench-scale up-flow wetlands were operated with four different bed media sets. The removal efficiencies of the wetland effluent for CODCr, TN, TP, SS were 35.2 %, 29.5 %, 31.2 % and 52.2 % for set 1(Blank, without reed, with bio-ceramic), 40.6 %, 43.4 %, 42.2 % and 55.4 % for set 2(with bio-reed & without bio-ceramic), 45.2 %, 48.7 %, 46.6 % and 66.3 % for set 3(with bio-reed & bio-ceramic), 32.9 %, 27.3 %, 29.3 % and 54.1 % for Set 4(with reed & bio ceramic), respectively. The set 3 condition having a mixture of bio-reed and bio-ceramic showed the highest efficiency in the bench-scale evaluation. This study suggests a mixture of bio-reed and bio-ceramic as suitable bed media in the construction of artificial wetlands near livestock farms. Soils including the bed media were monitored during the evaluation for trace elements. Soil analysis results were satisfied with the Korean Soil Contamination Standard. This study showed that the up-flow constructed wetland was feasible to treat the effluent livestock wastewater treatment facility.

• Journal of Wetlands Research
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• v.14 no.4
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• pp.479-488
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• 2012

This study evaluates treatment efficiencies of pollutants in Boknae bio-park constructed wetlands surrounding Juam Lake for 5 years from January 2006 to December 2010, in order to treat non-point pollutants effectively. The analysis of monthly treatment efficiency of pollutants shows that the scope of BOD is -19.11~37.72%, and of COD is 30.14~27.38%, thus the monthly deviation COD is relatively higher than BOD, and the scope of SS is -54.07~64.82%. Moreover, the analysis of seasonal treatment efficiency of pollutants shows that the treatment efficiency of TN is higher than 36.8% on average for 5 years in the spring and winter, and of TP relatively lower than other pollutants, however, the seasons don't make much difference to the treatment efficiency of TP.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.5
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• pp.378-381
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• 2009

The purpose of this research is the evaluation of removal efficiency of THMFP in BAC. The changes of four types of THMFP and total THMFP were examined in the influent and effluent of BAC filter from March to December in 2008. It turned out that the amounts of brominated THMFP were obviously higher in winter and autumn compared to the spring and summer, which also resulted in an increase of the total-THMFP levels during winter and autumn. In addition, long-term running of BAC filter shows the good removal function of chloroform formation potential, but not brominated THMFP; with further bromination, this function was declined, as it shows the formation of bromoform in BAC filter during October and December. These results were caused by changing of the proportion of $Br^-$/DOC.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.642-649
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• 2007

The effectiveness of add-on tertiary treatment processes for the polishing of the effluent of a biological nutrient removal (BNR) system from a modified $A^2/O$ process has been examined under the field condition with pilot-scale plants. The add-on treatment processes of 1) combined biofilm anoxic reactor and sand filtration, and 2) two-stage denitrification filter had been operated with various operating conditions. The experimental results indicated that two-stage denitrification filter could produced a better polished tertiary effluent. Filtration rate of $150m^3/m^2{\cdot}d$ for the 2-stage denitrifying filter could decrease the nitrate removal probably due to shorter detention time that caused insufficient reaction for denitrification. Two stage denitrification filter operated with M/N ratio of 3.0 and filtration rate of $100m^3/m^2{\cdot}d$ produced the tertiary effluent with nitrate and SS concentraitons of 2.8 mg/L and 2.3 mg/L, respectively. When the operating temperature reduced $30^{\circ}C$ to $18^{\circ}C$, $NO_3{^-}-N$ removal efficiency decreased from 73% to 68%.

• Journal of Korean Society of Water and Wastewater
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• v.23 no.5
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• pp.599-608
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• 2009

This manuscript covers the results of field investigation and lab-scale experiments to design a double-layered biofilter system to control urban storm runoff. The biofilter system consisted of a coarse soil layer (CSL) for filtration and fine soil layer (FSL) for adsorption and biological degradation. The variations of flow rate and water quality of runoff from a local expressway were monitored for seven storm events. Laboratory column experiments were performed using seven kinds of soil and mulch to maximize pollutants removal. The site mean concentration (SMC) of storm runoff from the drainage area (runoff coefficient: 0.92) was measured to be 203 mg/L for SS, 307 mg/L for $TCOD_{Cr}$, 12.3 mg/L for TN, 7.3 mg/L for ${NH_4}^+-N$, and 0.79 mg/L for TP, respectively. This study employed a new design concept, to cover the maximum rainfall intensity with one month recurrence interval. Effective storms for last ten years (1998-2007) in seoul suggested the design rainfull intensity to be 8.8 mm/hr Single layer soil column showed the maximum removal rate of pollutants load when the uniformity coefficient of CSL was 1.58 and the silt/clay contents of FSL was virtually 7%. The removal efficiency during operation of double layer soil column was 98% for SS and turbidity, 75% for TCODCr, 56% for ${NH_4}^+-N$, 87% for TP, and 73-91% for heavy metals. The hydraulic conductivity of the soil column, 0.023 cm/sec, suggested that the surface area of the biofilter system should be about 1% of the drainage area to treat the rainfall intensity of one month recurrence interval.

• Membrane Journal
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• v.27 no.1
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• pp.104-107
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• 2017

Among many methods in solving the organic contamination in the reverse osmosis operation, caustic soda (NaOH) wash method is efficient and commercially affordable. In continuation of our many organic pollution removal works, this study focused mainly on caustic soda wash with micro-bubble to removal the organic contamination of the spent membrane from reverse osmosis process. First, the membrane was forced the pollute using known organic pollutants such as Humic acid, Bovine serum albumin, Sodium alginate drug. The organic contamination on the membrane was monitored flux. The decontamination of organic contaminants was derived flux variation at individual caustic soda was injected micro-bubble methods and combined method as well. the found results explain removal of organic contaminants effective only by combined caustic soda wash with micro-bubble methods.

• Environmental Engineering Research
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• v.19 no.3
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• pp.269-274
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• 2014

On-site sanitation systems are typically installed to treat grey and toilet wastewaters in areas without sewer and centralized treatment systems. It is well known that, due to inappropriate design and operation, treatment performance of these systems in developing countries is not satisfactory in the removal of pathogens and organic matters. This research aimed to investigate the hydraulic conditions occurring in some on-site sanitation systems and the effects of hydraulic retention times (HRTs) on the system performance. The experiments were conducted with a laboratory-scale septic tank (40L in size) and an actual septic tank (600L in size), to test the hydraulic conditions by using tracer study with HRTs varying at 12, 24 and 48 hr. The experimental results showed the dispersion numbers to be in the range of 0.017-0.320 and the short-circuit ratios in the range of 0.014-0.031, indicating the reactors having a high level of sort-circuiting and approaching complete-mix conditions. The removal efficiency of $BOD_5$ was found to be 67% and the $k_{30}$ values for $BOD_5$ was $2.04day^{-1}$. A modified complete-mix model based on the relationship between $BOD_5$ removal efficiencies and HRTs was developed and validated with actual-scale septic tank data having a correlation coefficient ($R^2$) of 0.90. Therefore, to better protect our environment and minimizing health risks, new generation toilets should be developed that could minimize short-circuiting and improving treatment performance.

• Journal of Korean Society on Water Environment
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• v.37 no.6
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• pp.483-492
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• 2021

This study evaluated the removal efficiencies of methylene blue (MB) and humic acids (HA) using a rice husk (RH) biochar and powdered activated carbon (PAC). The pseudo-second-order model better presented the adsorption of MB and HA onto a RH biochar than the pseudo-first-order model. Furthermore, better description of the adsorption behavior of MB and HA by the Langmuir isotherm model (R² of the RH biochar: MB = 0.986 and HA = 0.984; R² of PAC: MB = 0.997 and HA = 0.989) than the Freundlich isotherm model (R² of the RH biochar: MB = 0.955 and HA = 0.965; R² of PAC: MB = 0.982 and HA = 0.973) supports the assumption that monolayer adsorption played key roles in the removal of MB and HA using the RH biochar and PAC. Batch experiments were performed on the effects of dosage, temperature, and pH. For all experiments, PAC showed higher efficiencies than RH biochar and MB adsorption efficiencies were higher than those of HA. Adsorption efficiencies increased with increasing amounts of adsorbents and temperature. As the pH increased, adsorption efficiencies of MB were increased while adsorption efficiencies of HA were decreased.