• 제목/요약/키워드: remediation concentration

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계면활성제를 이용한 향상된 EK 정화 시 PAH의 제거

  • 김강호;한상재;김수삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2001년도 추계학술발표회
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    • pp.127-130
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    • 2001
  • This paper presented to phenanthrene removal of electrokinetic(EK) remediation and enhanced EK remediation with bench scale test. The experiments were carried out on mixture soil with phenanthrene as the test compound. The EK remediation experiments were conducted under controlled voltage. Surfactant solution was constantly supplied at the anode reservoir with constant concentration. Results showed that phenanthrene was removed little in EK remediation. Surfactant helped phenanthrene moving and cumulated in cathode region. Moving effect was increased with surfactant concentration.

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Effect of constraint severity in optimal design of groundwater remediation

  • Ko, Nak-Youl;Lee, Kang-Kun
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.217-221
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    • 2003
  • Variation of decision variables for optimal remediation using the pump-and-treat method is examined to estimate the effect of the degree of concentration constraint. Simulation-optimization method using genetic algorithm is applied to minimize the total pumping volume. In total volume minimization strategy, the remediation time increases rapidly prior to significant increase in pumping rates. When the concentration constraint is set severer, the more wells are required and the well on the down-gradient direction from the plume hot-spot gives more efficient remediation performance than that on the hot-spot position. These results show that the more profitable strategy for remediation can be achieved by increasing the required remediation time than raising the pumping rate until the time reaches a certain limitation level. So, the remediation time has to be considered as one of the essential decision variables fer optimal remediation design.

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바이오필름 반응기상에서 수소 이용성 독립영양생물을 이용한 고농도 탈질 반응 (Autohydrogenotrophic Denitrification of High Nitrate Concentration in a Glass Bead Biofilm Reactor)

  • 박호일;김지성;김동건;박대원
    • 한국물환경학회지
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    • 제20권3호
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    • pp.236-240
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    • 2004
  • Autohydrogenotrophic denitrification of high nitrate concentration contaminated wastewater in a batch-scale biofilm reactor has been investigated. High nitrate concentration decreased as pH increased from 7.01 to 9.45. The high nitrate concentrations continuously decrease from $150mg.l^{-1}$ to $0mg.l^{-1}$. Nitrite concentrations increase at about two-thirds way through the denitrification process and thereafter it decreases with time. Autohydrogenotrophic denitrification of high nitrate concentration is passible to use drinking water as well as wastewater, and to deal with wastewater treatment by hetrotrophic denitrification.

우라늄 제거를 위한 실험실 규모 동전기 장치의 개선 방안 (Improvement of Pilot-scale Electrokinetic Remediation Technology for Uranium Removal)

  • 박혜민;김계남;김승수;김완석;박욱량;문제권
    • 방사성폐기물학회지
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    • 제11권2호
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    • pp.77-83
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    • 2013
  • 방사능 오염 토양 복원을 위해 실험실 규모의 동전기 복원장치를 제작하여 가동 하던 중 토양 내 존재하던 금속이온의 용출로 금속 산화물이 발생하여 음극의 전류 흐름을 차단하는 문제가 발생하였다. 전류의 차단으로 토양 내 우라늄 제거 능력이 상실되어 이러한 문제를 해결하는 해결 방안을 모색하여 개선된 동전기 복원 장치를 제작하였다. 개선된 실험실 규모 동전기 복원 장치를 이용하여 토양복원 실험을 25 일간 수행 하였을 때 우라늄 잔류 농도는 0.81 Bq/g으로 약 96.8%의 제거 효율을 보였으며, 초기 우라늄 농도 50 Bq/g 일 때 우라늄 규제 해제 농도인 1 Bq/g 이하로 제거 되기 까지는 34 일의 복원 기간이 필요하고, 초기 우라늄 농도 75 Bq/g, 100 Bq/g 일 때 각 42 일, 49 일이 필요한 것으로 나타났다.

Evidences of in Situ Remediation from Long Term Monitoring Data at a TCE-contaminated Site, Wonju, Korea

  • Lee, Seong-Sun;Kim, Hun-Mi;Lee, Seung Hyun;Yang, Jae-Ha;Koh, Youn Eun;Lee, Kang-Kun
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제18권6호
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    • pp.8-17
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    • 2013
  • The contamination of chlorinated ethenes at an industrial complex, Wonju, Korea, was examined based on sixteen rounds of groundwater quality data collected from 2009 to 2013. Remediation technologies such as soil vapor extraction, soil flushing, biostimulation, and pumping-and-treatment have been applied to eliminate the contaminant sources of trichloroethylene (TCE) and to prevent the migration of TCE plume from remediation target zones. At each remediation target zone, temporal monitoring data before and after the application of remediation techniques showed that the aqueous concentrations of TCE plume present at and around the main source areas decreased significantly as a result of remediation technologies. However, the TCE concentration of the plumes at the downstream area remained unchanged in response to the remediation action, but it showed a great fluctuation according to seasonal recharge variation during the monitoring period. Therefore, variations in the contaminant flux across three transects were analyzed. Prior to the remediation action, the concentration and mass discharges of TCE at the transects were affected by seasonal recharge variation and residual DNAPLs sources. After the remediation, the effect of remediation took place clearly at the transects. By tracing a time-series of plume evolution, a greater variation in the TCE concentrations was detected at the plumes near the source zones compared to the relatively stable plumes in the downstream. The difference in the temporal profiles of TCE concentrations between the plumes in the source zone and those in the downstream could have resulted from remedial actions taken at the source zones. This study demonstrates that long term monitoring data are useful in assessing the effectiveness of remediation practices.

중금속 오염 퇴적저니의 복원방안 (Remediation of Heavy Metal Contaminated Sediments)

  • 배우근;이창수;홍종철;장석규;김성진
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1999년도 추계학술발표회
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    • pp.34-38
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    • 1999
  • This paper investigated remediation options for contaminated sediments with heavy metals. Twenty three sediment samples were taken from three different depths of 0.5m, 1.5m and 2.5m. The concentration of Heavy metals Cu, Pb, and Hg were measured. The concentration of copper far exceeded the Sediment Quality Guideline in U.S.A and Interim Sediment Quality Guidelines in Canada. Therefore, remediation of the sediments is requried to protect the benthos. Two remediation options were suggested : dredging of the organic sediments as deep as about 85cm followed by surface covers with clean soil, and in-situ stabilization of tile sediments using lime or cement followed by surface cover with clean soil.

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연직배수재에 의한 토양오염물질 추출에 미치는 영향인자 분석 - 토양 및 오염유체의 물성치를 중심으로 (Analysis of Effecting Parameters on Extraction of Soil Contaminants using Vertical Drains - Focusing on Soil and Contaminants Physical Properties)

  • 이행우;장병욱;강병윤;김현태
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2005년도 학술발표논문집
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    • pp.355-360
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    • 2005
  • The properties of contaminants, contaminated soil, and the elapsed time are important factors to in-situ soil remediation. Gabr et. al. (1996) derived the solution equation of contaminant concentration ratio as initial one $(C/C_0)$ with time and spatial changes in contaminated area with vertical drains. The contaminant concentration ratio $(C/C_0)$ is analyzed with time and spatial changes as varying the effective diameter, porosity, shape factor, density of contaminated soil and temperature in ground and unit weight, viscosity of contaminants by using FLUSH1 model. Results from numerical analysis indicate that the most important factor to the in-situ soil remediation using vertical drains is the effective diameter of contaminated soil. It also shows that the viscosity of contaminants, porosity of soil, shape of soil, temperature in ground, unit weight of contaminants are, in order, affected to the soil remediation but density of soil is insignificant to the soil remediation.

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Microcosm Experiment for Evaluating Efficiency of Chemical Amendments on Remediation of Heavy Metal Contaminated Soil

  • Hong, Young Kyu;Oh, Se Jin;Oh, Seung Min;Yang, Jae E.;Ji, Won Hyun;Kim, Sung Chul
    • 한국토양비료학회지
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    • 제48권2호
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    • pp.138-145
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    • 2015
  • Heavy metal pollution in agricultural field near the abandoned metal mines is a critical problem in Korea. General remediation technique is to apply chemical amendments and soil covering. However, there is no specific guidelines for conducting soil covering. Therefore, main objective of this research was to determine optimum soil covering technique with microcosm experiment. Three different chemical amendments, lime stone (LS), steel slag (SS), and acid mine drainage sludge (AMDS), were examined and varied soil covering depth, 20, 30, 40cm, was applied to determine optimum remediation technique. Bioavailable heavy metal concentration in soil and total concentration of heavy metals in crop were monitored. Result showed that average heavy metal concentration in varied soil covering depth was ordered as 40 cm ($14.5mg\;kg^{-1}$) < 20 cm ($14.6mg\;kg^{-1}$) < 30 cm ($16.0mg\;kg^{-1}$) and also heavy metal concentration in crop was ordered as 40 cm ($100{\mu}g\;kg^{-1}$) < 30 cm ($183{\mu}g\;kg^{-1}$) < 20 cm ($190{\mu}g\;kg^{-1}$). In terms of chemical amendments, average heavy metal concentration was decreased as AMDS ($150{\mu}g\;kg^{-1}$) < SS ($151{\mu}g\;kg^{-1}$) < LS ($154{\mu}g\;kg^{-1}$). Overall, depth of soil covering should be over 30 cm to minimize bioaccumulation of heavy metals and SS and LS could be applied in heavy metal contaminated soil for remediation purposes.

토양세척법과 동전기 정화 기술을 이용한 중금속 오염지반의 원위치 정화

  • 김병일;한상재;이군택;김수삼
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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    • pp.199-202
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    • 2004
  • In this study the field-scale tests were performed in which in-situ E/K remediation technologies were applied, and then the results were present. For traditional E/K remediation method the efficiency of remediation is not large, but the enhanced method with citric acid significantly increases the removal efficiency. Also EDTA, reported as a good enhancement agent for removal of heavy metals, is similar to that of citric acid. Therefore citric acid is preferred rather than EDTA in view of the cost on the contaminant removal per unit concentration.

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불포화 자연토의 동전기 시스템에 따른 정화 특성 (The Remediation Characteristics of Natural Soil according to ElectroKinetic Remediation Systems under Unsaturated Conditions)

  • 김병일;김기년;한상재;김수삼
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2004년도 춘계학술발표회
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    • pp.873-881
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    • 2004
  • A serious of EK remediation tests on contaminated soil are performed under unsaturated conditions and analyzed for electrical potential, water content, pH and so on. The results indicated that electrical potential and pH distributions in the sample are dependent on the amount and inward/outward flow of hydrogen ion. Specially, for the closed system the water content is largely decreased with the flow of hydrogen. The maximum electrical conductivity is measured at the catholyte of CEM(Sealing) test and directly related to the remedial efficiency. Although pHs in the region near to the anode are similarly developed, the different concentration of lead is measured with the electrical gradient contrary to the lead concentration dependent on pH within the sample.

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