• Title/Summary/Keyword: related density

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고성능 섬유형 슈퍼커패시터를 위한 탄소섬유의 표면 기능화 (Surface Functionalization of Carbon Fiber for High-Performance Fibrous Supercapacitor)

  • 이영근;안건형
    • 한국재료학회지
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    • 제32권2호
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    • pp.107-113
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    • 2022
  • Fibrous supercapacitors (FSs), owing to their high power density, good safety characteristic, and high flexibility, have recently been in the spotlight as energy storage devices for wearable electronics. However, despite these advantages, FCs face many challenges related to their active material of carbon fiber (CF). CF has low surface area and poor wettability between electrode and electrolyte, which result in low capacitance and poor long-term stability at high current densities. To overcome these limits, fibrous supercapacitors made using surface-activated CF (FS-SACF) are here suggested; these materials have improved specific surface area and better wettability, obtained by introducing porous structure and oxygen-containing functional groups on the CF surface, respectively, through surface engineering. The FS-SACF shows an improved ion diffusion coefficient and better electrochemical performance, including high specific capacity of 223.6 mF cm-2 at current density of 10 ㎂ cm-2, high-rate performance of 171.2 mF cm-2 at current density of 50.0 ㎂ cm-2, and remarkable, ultrafast cycling stability (96.2 % after 1,000 cycles at current density of 250.0 ㎂ cm-2). The excellent electrochemical performance is definitely due to the effects of surface functionalization on CF, leading to improved specific surface area and superior ion diffusion capability.

사출성형 및 열간가압 소결법으로 제작된 지르코니아 세라믹 임플란트의 소결물성 및 미세구조적 결함 (Sintered Properties and Microstructural Defects of Zirconia Ceramic Implant Fabricated by Injection Molding and Hot Isostatic Pressing (HIP))

  • 박현정;박정식;이종국
    • 열처리공학회지
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    • 제36권4호
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    • pp.215-222
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    • 2023
  • 3Y-TZP (3 mol% yttria-stabilized tetragonal zirconia polycrystals, 3Y-TZP) ceramics are emerging as dental implant materials due to their superior optical and mechanical properties as well as excellent biophysical properties, in spite of low bioactivity. In this study, we investigated to sintered properties and microstructural defects of dental zirconia implants fabricated by ceramic injection molding and post-HIP (Hot isostatic pressing) processing and analyzed the processing parameters related with the obtainment of its high sinterd density. Sintered and microstructural parameters, i.e, apparent density, grain size and phase composition of zirconia implants fabricated by injection molding were dependent on the fixtute size and implant type. Maximum sintered density of 99.2% and minimum grain size of 0.3-0.4 ㎛ were obtained from large-scaled 2-body sample. In 1-body ceramic implant, high sintered density of 99.5% was obtained, but it had a little monoclinic phase and wide grain size distribution.

토양의 물리적(物理的) 특성(特性)이 대맥의 뿌리 분포(分布)에 미치는 영향(影響) (The Effects of Soil Physical Properties on Root Distribution of Barley)

  • 조인상;김리열;최대웅;임정남;엄기태
    • 한국토양비료학회지
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    • 제16권2호
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    • pp.126-130
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    • 1983
  • 토양의 물리적(物理的) 특성(特性)이 작물(作物)의 뿌리 발달에 미치는 영향(影響)을 구명(究明)하기 위하여 배수등급(排水等級), 토성조건(土性條件)이 상이(相異)한 대맥포장에서 토양물리성과 층위별(層位別) 뿌리 분포(分布)를 조사(調査)한 결과(結果)는 다음과 같다. 1. 배수(排水)가 양호(良好)할수록 총뿌리량은 증가(增加)되고 깊게 분포(分布)하였으며 동일(同一)한 배수등급(排水等級)에서는 토양이 세립질(細粒質)일수록 총뿌리량이 많은 경향(傾向)이었다. 2. 토양의 경도(硬度)는 가비중과 밀접(密接)한 관계가 있었으며 토성(土性)이 세립질(細粒質)일수록 유의성(有意性)이 높았다. < 식토(埴土) ($r=0.837^{**}$), 식양토($r=0.678^*$), 사양토($r=0.654^*$) > 3. 심토(深土)의 가비중과 뿌리량과는 고도(高度)의 유의성(有意性)있는 부(負)의 상관($r=-0,846^{**}$)이 있었으며 가비중이 $1.4g/cm^3$이상(以上) 되면 대맥 뿌리 발달은 현저(顯著)히 떨어졌다. 4. 심토(深土)의 가비중은 배수(排水)가 불량(不良)하고 토성(土性)이 조립질(組粒質) 일수록 감소(減少)되었으며 특(特)히 배수(排水)가 약간불량(若干不良)한 경우(境遇)와 약간(若干) 양호(良好)한 식토(埴土)에서는 기상이 20% 미만(未滿)으로 작물(作物) 생육(生育)이 불량(不良)하였다. 5. 대맥의 뿌리 신장(伸長)에는 표토(表土)는 경도(硬度), 토심(土深) 10~30cm는 가비중과 기상, 30~50cm는 기상의 영향(影響)이 컸다.

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도시하천의 환경요인과 Euglena viridis의 형태 변이 및 밀도와의 관계 (Morphological Variation and Density of Euglena viridis (Euglenophyceae) Related to Environmental Factors in the Urban Drainages)

  • 김준태;부성민
    • 생태와환경
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    • 제34권3호통권95호
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    • pp.185-191
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    • 2001
  • Euglena viridis의 형태변이, 밀도 및 환경요인과의 관계를 규명하기 위하여, 무심천, 미호천, 대전천, 전주천, 광주천 및 금호강의 도시하천에서 1996년 12월 25일에서 1997년 1월 4일 사이에 E. viridis의 형태와 밀도 및 수환경 요인들을 조사하였다. 각 하천에서 Euglena viridis는 형태적으로 두 가지 형태형으로 구분되었으나, 엽록체가 별 모양인 점에서 동일종으로 동정되었다. 형태형 I은 E. viridis의 일반적인 형태와 일치하였고, 대부분의 정점에서 대발생하여 광주천에서 최대 $5386\;cells\;{\cdot}\;mL^{-1}$이었다. 형태형 I의 밀도는 암모늄과 아질산염에 각각 정의 상관관계 (r = 0.80과 0.68),질산염과는 부의 상관관계에 있었다. 형태형 II는 엽록체들의 가장자리가 거치형이며, 세포질 소립들이 불규칙하게 분산되어 있는 점 등이 특징이었다. 형태형 II의 밀도는 질산염과 정의 상관관계(r = 0.98)를 보인 반면, 암모늄이나 아질산염과는 각각 부의 상관관계에 있었다. 그러나 두 가지 형태형은 각각 인산염, 수온 및 pH는 밀도와 유의한 상관을 보이지 않았다. 이 결과는 E. viridis의 두 가지 형태형들이 서로 다른 질소성 영양염들을 이용하므로서 동 시기 및 동일 지소에서 공존하고 있다는 것을 보여준다.

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고전류밀도에서 첨가제에 따른 구리도급의 표면 특성 연구 (The Effect of Additives on the High Current Density Copper Electroplating)

  • 심진용;문윤성;허기수;구연수;이재호
    • 마이크로전자및패키징학회지
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    • 제18권1호
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    • pp.29-33
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    • 2011
  • 전류밀도는 전기도급법에서 생산성과 직접적인 연관이 있고, 생산성의 증가를 위해선 고전류밀도가 필요하다. 회전전극(RDE)의 회전 속도를 증가시키면 고유속을 얻을 수 있다. 유속 조절을 위해 회전전극과 원통형 회전 전극을 사용하였고, 전압과 전류의 관계를 알아보기 위해 정전류, 정전압 실험과 linear sweep voltammetry 실시하였다. 회전 전극의 회전 속도가 400 rpm이상 조건에서, 수소가 발생하지 않고 1000 A/$m^2$이상의 최대전류멸도가 가능하였다. $25^{\circ}C$$62^{\circ}C$ 조건에서 구리의 확산계수는 각각 $5.5{\times}10^6\;cm^2\;s^{-1}$$10.5{\times}10^6\;cm^2\;s^{-1}$로 계산되었다. 수소가 발생하지 않으면서 안정적으로 구리를 전착할 수 있는 조건은 -0.05 V (vs Ag/AgCl)이었다. 첨가제인 glue와 thiourea-를 넣음으로써 구리의 침상성장을 막을 수 있었다. 표면 거칠기는 UV-Vis Spectrophotometer를 아용하여 분석되었다. 600 nm 영역에서 반사도는 측정 되었고 표면 거철기가 개선될수록 표면 반사도가 증가하였다.

낙동강 중류 유역의 단열계 특성 및 지하수계와의 관련성 (Characteristics of Joint Systems and Their Relationship with Groundwater System in the Nakdong River Mid-basin)

  • 김득호;이종현;박규태;김성창;최유미;서유리;노경명;함세영
    • 지질공학
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    • 제18권4호
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    • pp.483-492
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    • 2008
  • 낙동강 중류 지역(함안근, 창령군, 의령군)의 백악기 퇴적암의 단열계 특성(단열 방향성과 단열계 밀도도)을 파악하고, 단열과 단층, 수계 그리고 연구지역내 지하수공의 일일 사용량과의 관련성을 분석하였다. 단열계는 JI($N90^{\circ}-110^{\circ}E$), J2($N0^{\circ}-35^{\circ}E$), J3($N0^{\circ}-35^{\circ}W$)로 분류되며, 주로 남북방향과 동서방향 단열군의 방항성이 우세하다. 연구지역의 동편과 서편의 함안층 분포지역에서는 남북방향의 단열계가 우세한 반면에, 연구지역의 중간부분인 칠곡층 분포지역에서는 동서방향의 단열계기 우세하다. 이는 연구지역의 동편과 서편에 위치하는 북북동-남남서 방향의 단층계와 관련되는 것으로 보인다. 또한 낙동강 주변에서도 단열 밀도가 높게 나타나며, 이는 동서방향의 단열계가 낙동강과 연관됨을 암시한다. 한편, 연구지역내 지하수공의 일일 사용량과 단열 밀도 간에는 약한 양의 상관성을 보이며, 지하수 비양수량과 단열 밀도간에는 음의 상관성을 보인다. 이는 단열 밀도가 지하수 산출량을 결정하는 주요 요인이 될 수 없음을 지시한다.

TiN 코팅층 집합조직의 변화에 따른 마찰, 마멸과 내부식 특성 (The Characteristics of Frictional Behavior, Wear and Corrosion Resistance of Textured TiN Coated Layer)

  • 김희동;김인수;성동영;이민구
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2003년도 춘계학술대회논문집
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    • pp.99-104
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    • 2003
  • TiN coated films show a good mechanical properties, high thermal properties and wear, erosion and corrosion resistance and are widely used as a coating materials in tools, ornaments, parts and semiconductors. In spite of these good properties, the fracture of TiN coated films occur during use. The fracture of TiN thin films is related to their microstructure. Especially, the life of TiN coated layer is related to the texture of the TiN films. One researcher suggested that the corrosion and erosion resistance of the TiN thin films is related to a uniform and dense structure of films. In this study, we studied the relationships between textures and friction coefficient, erosion and corrosion in TiN coated films. The flatness of (115) texture surface of TiN thin films is flatter than that of (111) texture surface. The friction coefficient of (115) texture surface of TiN thin films is similar with that of (111) texture surface. The wear resistance of (115) texture surface of TiN thin films is better than that of (111) texture surface. The erosion and corrosion resistance of (115) texture surface of TiN thin films is better than that of (111) torture surface. As well as texture, the wear, erosion and corrosion of TiN thin films has to consider defects such as pinholes, cracks, surface roughness and open columnar structure. The life of TiN coated products is influenced by the properties of wear, erosion, and corrosion resistance of TiN thin films and is related to texture of TiN coated films, density of pinholes and cracks, density of structure, and surface flatness.

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Relationship Between Blood Mercury Concentration and Waist-to-Hip Ratio in Elderly Korean Individuals Living in Coastal Areas

  • You, Chang-Hun;Kim, Byoung-Gwon;Kim, Jung-Man;Yu, Seung-Do;Kim, Yu-Mi;Kim, Rock-Bum;Hong, Young-Seoub
    • Journal of Preventive Medicine and Public Health
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    • 제44권5호
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    • pp.218-225
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    • 2011
  • Objectives: This study investigated the relationship between the blood mercury concentration and cardiovascular risk factors in elderly Korean individuals living in coastal areas. Methods: The sample consisted of 477 adults (164 males, 313 females) aged 40 to 65 years who visited a Busan health promotion center from June to September in 2009. The relationship between blood mercury concentration and cardiovascular risk factors including metabolic syndrome, cholesterol profiles, blood pressure, body mass index (BMI), waist circumference and waist-to-hip ratio (WHR), was investigated. Variables related to blood mercury concentration were further evaluated using multiple regression analysis. Results: The blood mercury concentration of the study population was 7.99 (range, 7.60 to 8.40) ${\mu}g$/L. In males, the blood mercury concentration was 9.74 (8.92 to 10.63) ${\mu}g$/L, which was significantly higher than that in females (7.21, [6.80 to 7.64] ${\mu}g$/L). The blood mercury concentration of the study population was related to several cardiovascular risk factors including low-density lipoprotein (LDL) cholesterol (p=0.044), high-density lipoprotein (HDL) cholesterol (p=0.034), BMI (p = 0.006), waist circumference (p = 0.031), and WHR (p < 0.001). In males, the blood mercury concentration was significantly correlated with WHR in the multiple regression analysis. Conclusions: In males, the blood mercury concentration was related to waist-to-hip ratio, which is a central obesity index and cardiovascular risk factor. Our finding suggests that cardiovascular disease risk in males was increased by mercury exposure via an obesity-related mechanism.

옷감의 질감 명명 체계 확립을 위한 질감 속성자 분류 -여성 슈트용 추동복지의 질감 속성을 중심으로- (Classification of Textural Descriptors for Establishing Texture Naming System(TNS) of Fabrics -Textural Descriptions of Women's Suits Fabrics for Fall/winter Seasons-)

  • 한은경;김은애
    • 한국의류학회지
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    • 제30권5호
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    • pp.699-710
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    • 2006
  • The objective of this study was to identify the texture-related components of woven fabrics and to develop a multidimensional perceptual structure map to represent the tactile textures. Eighty subjects in clothing and tektite industries were selected for multivariate data on each fabric of 30 using the questionnaire with 9 pointed semantic differential scales of 20 texture-related adjectives. Data were analyzed by factor analysis, hierarchical cluster analysis, and multidimensional scaling(MDS) using SPSS statistical package. The results showed that the five factors were selected and composed of density/warmth-coolness, stiffness, extensibility, drapeability, and surface/slipperiness. As a result of hierarchical cluster analysis, 30 fabrics were grouped by four clusters; each cluster was named with density/warmth-coolness, surface/slipperiness, stiffness, and extensibility, respectively. By MDS, three dimensions of tactile texture were obtained and a 3-dimensional perceptual structure map was suggested. The three dimensions were named as surface/slipperiness, extensibility, and stiffness. We proposed a positioning perceptual map of fabrics related to texture naming system(TNS). To classify the textural features of the woven fabrics, hierarchical cluster analysis containing all the data variations, even though it includes the errors, may be more desirable than texture-related multidimensional data analysis based on factor loading values in respect of the effective variables reduction without losing the critical variations.

고령인구 비율이 높은 지역 장년, 노년층의 건강.영양상태 및 이에 영향을 미치는 인자에 관한 연구 - II. 남자의 골밀도와 이에 영향을 미치는 식이요인분석 - (Nutritional Status and Related Factors of Residents Aged Over 50 in Longevity Areas - II, Effect of Dietary Factors on Bone Ultrasound Measurements in Aged Men -)

  • 최정숙;권성옥;백희영
    • Journal of Nutrition and Health
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    • 제39권2호
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    • pp.171-183
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    • 2006
  • This study was conducted to examine dietary factors affecting bone status in the rural aged men. Quantitative ultrasound measurements (QUS) of bone, that may reflect certain architectural aspects of bone, have been shown to be associated with bone mineral density and fracture. Information of diet and anthropometry was collected in 164 aged men. Dietary intake data were obtained by 24-hour recall method. Measurements of the speed of sound (SOS, m/s), at distal radius, mid-tibia, phalanx, were performed using Omnisense 7000S analyzer (Sunlight Ltd., Tel Aviv, Israel). T-scores for bone SOS measurements at distal radius, mid-tibia and phalanx were 0.60, 0.03 and -0.42 respectively. The prevalence of osteopenia by use of the WHO criteria was 17.7% at the mid-tibia and 25.3% of the subjects at the distal radius. Age were negative association with bone SOS at three sites. Osteopenia group of radius were significantly lower in total foods and vegetable intakes than normal group. After adjusted for age, vegetable intakes were significantly and positively related to bone SOS at the radius. The bone SOS of the tibia were significantly and positively related to vegetable protein, iron, folate and vegetable intakes, but negatively related to fat intakes. Multiple regression analysis showed that bone SOS of tibia was positively associated with folate intakes. Vegetable intakes were positively associated with the bone SOS at three sites. These results indicate that the consumption of vegetables, sources of folate, may have a effect on bone status of men.