• Korean Chemical Engineering Research
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• 제49권6호
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• pp.739-744
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• 2011

선택적환원 반응용 활성탄 촉매는 액정디스플레이 제조 공정에서 배출되는 붕소를 포함하는 배가스 중의 $NO_x$를 제거하는데 사용되는데, 붕소가 촉매의 세공을 막거나 활성점에 침적되어 촉매 비활성화가 발생하게 된다. 폐촉매는 다양한 계면활성제를 포함하는 수용액 중에서의 세정, 건조 및 소성에 의해 재생이 가능하였다. 세정 과정의 조건, 계면 활성제 종류, 소성 조건 등을 변화시키면서 재생 전과 후의 폐촉매의 물리화학적 성능 비교를 위하여 질소 흡착 실험, ICP에 의한 원소 분석을 수행하였다. 암모니아를 사용하는 선택적환원 반응은 고정층 촉매 반응기를 사용하여 $120^{\circ}C$에서 수행하였다. $90^{\circ}C$의 수용액에서 비이온 계면활성제를 사용하여 세정하고, 질소 분위기에서 $550^{\circ}C$에서 소성하여 재생한 활성탄 촉매는 붕소가 가장 많이 제거되어 신규 활성탄과 유사한 수준의 표면적과 $NO_x$ 제거 효율을 회복하였다.

• 한국산학기술학회논문지
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• 제22권2호
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• pp.644-650
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• 2021

본 연구는 지구 온난화의 주요 원인인 이산화탄소를 이용하여 메탄의 개질반응 특성을 수행하였다. 이산화탄소와의 메탄 분해 반응을 전이금속 촉매인 주석을 사용하여 수행되었으며, 주석의 분해 반응성은 니켈, 철과 같은 전이 금속보다 낮으며, 대부분의 분해 반응은 고체 상태 촉매하에 수행된다. 반면에 주석의 녹는점은 505.03K로 액상 촉매하에서 분해가 발생된다. 주석을 사용하는 경우 액상으로 반응하며 메탄이 분해되어 생성되는 고체상 탄소가 촉매에 침적되어 비활성화되는 것을 것을 방지하는 장점이 있다. 이산화탄소를 사용하여 메탄을 분해하는 경우 일산화탄소와 수소를 생성한다. 촉매의 활성과 수명을 높이기 위해 Ni를 사용한 경우 촉매 활성이 향상되었다. 본 연구에서는 과잉습식함침법을 이용하여 촉매를 합성하였으며, 반응 온도, 공간 속도에 따른 활성과 촉매 재생 가능성을 타진하였다. 탄소가 침적된 주석의 촉매 재생 온도는 1023 K로 나타났으며, 니켈을 조촉매로 사용하고 물을 공급하므로써 반응성이 향상되는 것으로 나타났다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1996년도 하계학술대회 논문집 A
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• pp.450-452
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• 1996

In this paper, the authors propose a DC-DC boost converter of high efficiency by partial resonant switching mode, the switching devices in a proposed circuit are operated with soft switching and the control technique of those is simplified for switch to drive in constant duty cycle. The circuit has a merit which is taken to increase of efficiency, as it makes to a regeneration at input source of accumulated energy in snubber condenser without loss of snubber inconventional circuit. The proposed converter is deemed the most suitable for high power applications where the power switching devices are used.

• 한국진공학회지
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• 제6권S1호
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• pp.59-65
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• 1997

Efficient Si(100) etching by thermal H atoms at low substrate temperatures has been achieved. Gas-phase etching product $SiH_4$(g) upon H atom bombardment resulting from direct abstraction of $SiH_3$(a) by impinging H atoms was detected with a quadrupole mass spectrometer over the substrate temperature range of 105-408 K Facile depletion of all surface silyl ($SiH_3$) groups the dissociative adsorption product of disilane ($Si_2H_6$) at 105K from Si(100)2$\times$1 by D atoms and continuous regeneration and removal of $SiD_3$(a) were all consumed. These results provide direct evidence for efficient silicon surface etching by thermal hydrogen bombardment at cryogenic temperatures as low as 105K We attribute the high etching efficiency to the formation and stability of $SiH_3$(a) on Si(100) at lowered surface temperatures allowing the $SiH_3$(a) abstraction reaction by additional H atom to produce $SiH_4$((g).

• 전력전자학회논문지
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• 제17권4호
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• pp.359-367
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• 2012

In this paper, the input split type series-parallel hybrid electric vehicle (SPHEV) is established and the interpretation of the dynamic characteristics in four kinds of HEV modes, such as electric vehicle mode, engine mode, hybrid mode, and regeneration mode, is described. For this research, the forward-facing approach simulation method is chosen, which is useful for vehicle dynamic analysis. The rating of each powertrain component is designed based on energy-based concept and electrical peaking hybrid (ELPH) method. Finally, the designed powertrain is evaluated with the developed PSiM simulator and simulation results are shown.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.917_918
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• 2009

최근 전기 구동 시스템을 갖춘 친환경적인 하이브리드 자동차 혹은 전기 자동차에 대한 관심이 늘고 있다. 본 논문에서는 비교적 구조가 간단한 자전거에 쉽게 적용될 수 있는 BLDC 모터를 기준으로, 전기자전거 주행 상황에 있어서의 슈퍼커패시터를 이용한 회생 에너지 제어에 대하여 언급한다. 회생 에너지를 최대한 슈퍼캐패시터에 전달할 수 있는 제어 방법을 제시하고 이를 컴퓨터 모의 실험을 통해 확인한다.

• 한국산업융합학회 논문집
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• 제21권4호
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• pp.149-158
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• 2018

With the propagation and spread of the new regeneration energy and increase in electricity demand, power systems tend to be decentralized, and accordingly, the use of a power system stabilizer tends to expand for the stabilization of the distribution system. Thus, typical power system stabilizer, Static Var Compensator (SVC) is developed on a variety of topologies. In addition, the trend of technology leads from SVC to Static Synchronous Compensator(STATCOM) technology development. Recently, to overcome STATCOM's conversion losses and economic disadvantages, studies of a hybrid method using STATCOM and SVC in parallel have actively been conducted. This study proposes a new Soft-Step Switching method to limit inrush current problematic in Thyristor Controlled Capacitor (TCC) method in SVC function. In addition, to reduce Statcom's capacity, groups of reactive power compensation reactor and condenser for SVC were designed.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2004년도 전력전자학술대회 논문집(2)
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• pp.556-560
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• 2004

Three-phase Matrix Converter has become an effective substitution for the conventional converter module due to generation of the feasible variety of frequency and amplitude output voltage without energy storage elements besides the advantage of unity input power factor at the power supply and the regeneration capability. This paper introduces two kinds of current controllers for the matrix converter fed induction motor. Some simulated results are carried out to verify the effectiveness of the two-proposed methods as compared with the classical method using voltage source inverter.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• 제3B권1호
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• pp.23-31
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• 2003

A novel 3D shape optimization algorithm is presented for electromagnetic devices carry-ing eddy current. The algorithm integrates the 3D finite element performance analysis and the steepest descent method with design sensitivity and mesh relocation method. For the design sensitivity formula, the adjoint variable vector is defined in complex form based on the 3D finite element method for eddy current problems. A new 3D mesh relocation method is also proposed using the deformation theory of the elastic body under stress to renew the mesh as the shape changes. The design sensitivity f3r the sur-face nodal points is also systematically converted into that for the design variables for the parameterized optimization application. The proposed algorithm is applied to the optimum design of the tank shield model of the transformer and the effectiveness is proved.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 추계학술대회 논문집
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• pp.55-58
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• 2007

To check the feasibility of SMART (Steam Methane Advanced Reforming Technology)system, an experimental investigation was conducted. A fluidized bed reactor of diameter 0.052 m was operated cyclically up to the $10^{th}$ cycle, alternating between reforming and regeneration conditions. FCR-4 catalyst was used as the reforming catalyst and calcined limestone (domestic, from Danyang) was used as the $CO_2$ absorbent. Hydrogen concentration of 98.2% on a dry basis was reached at $650^{\circ}C$ for the first cycle. This value is much higher than $H_2$ concentration of 73.6% in the reformer of conventional SMR (steam methane reforming) system. However, the hydrogen concentration decreased because the $CO_2$ capture capacity decreased as the number of cycles increased.