• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.5
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• pp.411-421
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• 2001

The purpose of this study is to investigate the performance of an autocascade refrigeration system by simulation and experiment using refrigerant mixtures of R744/134a and R744/290 as working fluid. Variations of mass flow rate of refrigerant, compressor work refrigeration capacity and COP with respect to mass fraction of R744/134a and R744/290 mixture were presented under different operating conditions. Performance test has been executed by ASRAE standard. Experimental results show as the composition of R744 in the refrigerant mixture increases, heating and coling capacity are enhanced, but COP trends to decrease. Experimental results are compared with those from the simulation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.12
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• pp.1049-1056
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• 2000

In this study, condensation heat transfer coefficients(HTCs) of 2 nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lower than the ideal values calculated by the mass fraction weighting of the pure components HTCs. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against the predicted ones by Colburn and Drew\`s film model and a good agreement was observed.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.6
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• pp.912-920
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• 1999

The forced convective boiling heat transfer coefficients of R-407C were measured inside a horizontal tube 6.0mm I.D. and 4.0m long. The heat transfer coefficients increased according to an increase in heat flux at constant mass flux. Because nucleation was completely suppressed in the two-phase flow region with high quality, heat transfer coefficients in forced convective evaporation were higher than those in nucleate boiling region. Average heat transfer coefficients of R-407C were about 30 percent lower than the pure refrigerant correlation, due to mass transfer resistance at the gas-liquid interface. However, the total experimental data shows an agreement with the predicted data for ternary refrigerant mixtures with a mean deviation of 30%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.4
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• pp.518-527
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• 1999

The solubility and miscibility measurement apparatus has been developed and used to obtain data for refrigerant/oil mixture. The solubility and miscibility data for R-134a/46 ISO VG Polyalkylen Glycol(PAG) oil mixture are obtained over the temperature range from -20 to 6$0^{\circ}C$ with a 1$0^{\circ}C$ interval and the oil concentration range from 0 to 90wt%. Using the experimental data, an empirical model is developed to predict the solubility relations for R-134a/PAG oil mixture at equilibrium. The average root-mean-square deviation between measured data and calculated results from the empirical model is 4.2%. Raoult's rule and Flory-Noggins theory are also used to predict mixture behavior. Immiscibility is observed for R-134a/46 ISO VG PAG oil mixture at low oil concentrations of 4.6, 10.1, and 20.4wt%.

• Journal of the Korean Professional Engineers Association
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• v.34 no.2
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• pp.23-27
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• 2001

Until 1996, CFC refrigerants haven't been used because it destroyed ozone that affecting In ecosystem. And HCFC will prohibit until 2020. In Europe, they attempt to move up its fulfillment. Until now the change have completed CFC into HFC134a and is considerated HCFC into HFC410A and HFC407C. But HFC41 OA has high condenser temperature and HFC407C is non-azeotropic refrigerant mixture and gliding temperature phenomenon. New refrigerant ell POE, PVE, PAG was also developed.

• Journal of the Semiconductor & Display Technology
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• v.21 no.2
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• pp.144-149
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• 2022

A cryogenic Mixed Refrigerant Joule-Thomson refrigeration cycle was designed to be applied to the semiconductor etching process with non-flammable constituents. 3-stage cascade refrigerator, single mixed refrigerant Joule-Thomson refrigerator, and 2-stage cascade type mixed refrigerant Joule-Thomson refrigerator are analyzed to figure out the coefficient of performance. Non-flammable mixture of argon(Ar), tetrafluoromethane(R14), trifluoromethane (R23) and octafluoropropane(R218) were utilized to analyze the refrigeration cycle efficiency. The designed refrigeration cycle was adapted to cool down the coolant of HFE7200(Ethoxy-nonafluorobutane, C₄F₉OC₂H₅) with certain constraints. Maximum coefficient of performance of the refrigeration system is obtained as 0.289 for the cooling temperature lower than -100℃. The detailed result of the coefficient of performance according to the mixture composition is discussed in this study.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.3
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• pp.136-142
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• 2002

HFC-134a is currently used as the refrigerant in automobile air-conditioner, replacing the ozone depleting refrigerant CFC-12. Although HFC-l34a has no ozone depletion potential, it has a relatively high global warming potential, approximately 1300 tins that of CO$_2$ over a 100 year time horizon. Therefore, HFC- l34a does not seem to be a perfect alternative refrigerant due to high GWP. For this reason, non-azeotrope refrigerant mixture have been proposed as a long-term and drop-in alternative to HFC-l34a in the automobile air-conditioning system which has variable operating conditions with changes in RPM and pressure ratio. In this study,OS-l2a of which thermodynamic properties are similar to those of HFC-l34a is selected among the mixed refrigerant. HFC-l34a and OS-l2a are examined experimently by the performance test in the same automobile air-conditioning system.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.22 no.12
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• pp.837-844
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• 2010

In this study, performance of R1234yf and R1234yf/R134a mixture is measured on a heat pump bench tester in an attempt to substitute R134a used widely in mobile air conditioners (MACs). The bench tester is equipped with a open type compressor providing a nominal capacity of 3.5 kW. All tests are conducted under the summer cooling and winter heating conditions of 7/4 $5^{\circ}C$ and $-7/41^{\circ}C$ in the evaporator and condenser, respectively. For R1234yf/R134a mixture, measurements are made at 5%, 10%, and 15% of R134a by mass. Test results show that the coefficient of performance (COP) and capacity of R1234yf are up to 2.7% and 4.0% lower than those of R134a, respectively. For R1234yf/R134a mixture, the COP and capacity are up to 3.9% lower and 3.6% higher than those of R134a. For R1234yf and R1234yf/R134a mixture, the compressor discharge temperature is $4.1{\sim}6.7^{\circ}C$ lower than that of R134a while the amount of charge is reduced up to 11% as compared to R134a. 90%R1234yf/10%R134a is a better refrigerant than pure R1234yf in that it is less flammable and more compatible with existing R134a system. Based upon the results, it is concluded that R1234yf and R1234yf/R134a mixture are long term environmentally friendly solutions to mobile air-conditioners due to their excellent environmental properties with acceptable performance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.2 no.3
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• pp.218-225
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• 1990

Studies on the performance of a heat pump using non-azeotropic refrigerant mixtures are done. In order to estimate the thermodynamic properties for the selected non-azeotropic refrigerant mixtures including R22/R152a, R22/R142b, R22/R114 and R13B1/R152a, Peng-Robinson equation of state is adopted. The pressure-enthalpy diagram and the temperature-entropy diagram are plotted for each refrigerant mixture. Considerations on the capacity modulation for the heat pump system using refrigerant mixtures are taken into. Results show that when the heating load varies, the possibility for the capacity modulation is found in the heat pump system using a compressor with constant volume flow rate. Under a constant heating capacity condition in the heat pump system, the coefficient of performance increases when the refrigerant mixtures are used. The volume flow rate decreases as the mass fraction of lower boiler increases in this case.

• International Journal of Air-Conditioning and Refrigeration
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• v.15 no.1
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• pp.25-33
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• 2007

The investigation has been made into the prediction of heat exchange performance of a counter flow type double-tube condenser for natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane in a smooth tube and micro-fin tube. Under various heat transfer conditions, mass flux, pressure drop and heat transfer coefficient of the mixed refrigerants were calculated using a prediction method, when the length of condensing tube, total heat transfer rate, mass flux and outlet temperature of coolant were maintained constant. Also, the predicted results were compared with those of HCFC22. The results showed that the mixed refrigerants of Propane/n-Butane or Propane/i-Butane could be substituted for HCFC22, while the pressure drop and overall heat transfer coefficient of the refrigerants were evaluated together.