• 한국세라믹학회지
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• 제32권4호
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• pp.471-481
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• 1995

Unirradiated UO2 pellets were pulverized by oxidation in air at 40$0^{\circ}C$, and the oxidized powders were reduced in H2 and CO atmospheres at $600^{\circ}C$. During the oxidation of UO2 at 40$0^{\circ}C$, intergranular cracks which caused the spallation were mainly developed by the volume contraction due to the formation of intermediate phase (U4O9 or U3O7). As oxidation proceeded, U3O8 finally formed. As the oxidation/reduction cycles were repeated, the powder surface became coarser, specific surface area was increased and average particle size was decreased. The sintered densities of the powder were increased by the oxidation/reduction cycle due to the characteristic changes of the powder.

• 대한화학회지
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• 제46권4호
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• pp.353-363
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• 2002

이 연구의 목적은 일반고와 과학고 학생들의 정신용량과 풀이 방법에 따른 산화 환원 반응식 완결 과정의 특성을 분석하여 산화 환원 단원의 교수학습 지도에 시사점을 얻고자 하는데 있다. 일반고 학생 79명과 과학고 학생 57명을 대상으로 하여 정신요량 검사, 산화 환원 반응식 완결 검사를 실시하였으며, 문항 유형별로 학생들의 문제 풀이 실패 유형과 성공 유형을 추출하여 분석틀을 개발하고 개발한 분석틀에 의하여 정신용량과 풀이 방법에 따라 실패 사례와 성공 사례를 분석하여 나타나는 특징을 알아보았다. 일반고 학생들과 과학고 학생들 모두 산화 환원 개념 이해 정도가 낮을수록 미정계수법을 많이 선택하였으며 미정계수법을 선택한 학생들은 정신용량이 클수록 문제 풀이의 성공률이 높았다. 또한, 산화 환원 개념 이해 정도가 높은 학생들은 산화수법이나 이온 자법을 더 많이 선택하였고 정신용량에 관계없이 문제 풀이의 성공률이 높게 나타났다. 학생들의 풀이 과정을 분석한 결과 성공 유형은 산화 환원의 개념 이해 정도가 높고 풀이 방법에 관계없이 풀이 단계 수를 줄이 학생들이었다. 실패 유형은 물이 방법에 따라 다르게 나타났다. 미정계수법을 선택한 학생들의 실패 유형은 계산 과정 중 틀린 경우, 미정방정식을 잘못 세운 경우 문제 풀이 과정중 고려해야 할 변인을 모두 고려하지 못한 경우 풀이 과정이 복잡하여 중단한 경우였다. 산화수법을 선택한 학생들의 실패 유형은 산화수를 잘못 결정한 경우 질량균형 또는 전하균형을 고려하지 않은 경우였다.

• 한국환경과학회지
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• 제29권12호
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• pp.1205-1211
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• 2020

In this study, the applicability of reduction-oxidation-linked treatment was evaluated for nitrobenzene and a by-product by analyzing the reaction kinetics. Nitrobenzene showed very low reactivity to persulfate that was activated using various methods. Nitrobenzene effectively reacted through the reduction process using Zero-Valent Iron (ZVI). However, aniline, a toxic substance, was produced as a by-product. Reduction-oxidation-linked treatment is a method that can allow the oxidative degradation of aniline after reducing nitrobenzene to aniline. The experimental results show improved reactivity and complete decomposition of the by-product. Improved reactivity and decomposition of the by-product were observed even under conditions in which the reduction-oxidation reaction was induced simultaneously. No activator was injected for persulfate activation in the process of reducing oxidant linkage, and the activation reaction was induced by ferrous iron eluted from the ZVI. This indicates that this method can be implemented relatively simply.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 추계학술대회 논문집
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• pp.159-159
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• 2009

In this work, nitrogen and oxygen functionalities was introduced to the graphite nanofibers (GNFs) and their effect on electrocatalytic performance of the GNF supports for direct methanol fuel cells (DMFCs) was invesigated. The nitrogen and oxygen groups were introduced through the urea treatments and acid treatment, respectively. And, PtRu catalysts deposited on modified GNFs were prepared by a chemical reduction method. The catalysts were characterized by means of elemental analysis, nitrogen adsorption, and X-ray photoelectron spetroscopy (XPS). The structure and morphological characteristics of the catalysts were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). As a result, the Pt-Ru nanoparticles were impregnated on GNFs with good formation in 3-5 nm. And, the cyclic voltammograms for methanol oxidation revealed that the methanol oxidation peak varied depending on changes of surface functional groups. It was thus considered that the PtRu deposition was related to the reduction of PtRu and surface characteristics of the carbon supports. The changes of surface functional groups were related to PtRu reduction, significantly affect the methanol oxidation activity of anode electrocatalysts in DMFCs.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.133-133
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• 2013

For both oxygen reduction (ORR) and hydrogen oxidation reactions (HOR) of proton electrolyte membrane fuel cells (PEMFCs), alloying Pt with another transition metal usually results in a higher activity relative to pure Pt, mainly due to electronic modification of Pt and bifunctional behaviour of alloy surface for ORR and HOR, respectively. However, activity and stability are closely related to the preparation of alloy nanoparticles. Preparation conditions of alloy nanoparticles have strong influence on surface composition, oxidation state, nanoparticle size, shape, and contamination, which result from a large difference in redox priority of metal precursors, intrinsic properties of metals, increasedreactivity of nanocrystallites, and interactions with constituents for the synthesis such as solvent, stabilizer, and reducing agent, etc. Carbon-supported Pt-Ni alloy nanoparticles were prepared by the borohydride reduction method in anhydrous solvent. Pt-Ru alloy nanoparticles supported on carbon black were also prepared by the similar synthetic method to that of Pt-Ni. Since electrocatalytic reactions are strongly dependent on the surface structure of metal catalysts, the atom-leveled design of the surface structure plays a significant role in a high catalytic activity and the utilization of electrocatalysts. Therefore, surface-modified electrocatalysts have attracted much attention due to their unique structure and new electronic and electrocatalytic properties. The carbon-supported Au and Pd nanoparticles were adapted as the substrate and the successive reduction process was used for depositing Pt and PtM (M=Ru, Pd, and Rh) bimetallic elements on the surface of Au and Pd nanoparticles. Distinct features of the overlayers for electrocatalytic activities including methanol oxidation, formic acid oxidation, and oxygen reduction were investigated.

• 웰빙융합연구
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• 제5권2호
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• pp.21-27
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• 2022

Purpose: This study is about photocatalytic technology and plasma oxidation-reduction technology. To the main cause of exposure to odor pollution, two deodorization techniques were applied to develop a module with higher removal efficiency and ozone reduction effect. Research design, data and methodology: A composite module was constructed by arranging two types of dry deodorization equipment (catalyst, adsorbent) in one module. This method was designed to increase the responsiveness to the components of complex odors and the environment. standard, unity, two types of oxidizing photo-catalyst technology and plasma dry deodorization device installed in one module to increase the potential by reduction to 76% of ozone, 100%, and 82%. Results: The complex odor disposal efficiency was 92%. Ammonia was processed with 50% hydrogen sulfide and 100% hydrogen sulfide, and ozone was 0.01ppm, achieving a target value of 0.07ppm or less. The combined odor showed a disposal efficiency of 93%, ammonia was 82% and hydrogen sulfide was 100% processed, and ozone achieved a target value of 0.07 ppm or less. Conclusions: Ozone removal efficiency was 76% by increasing Oxidation-Reduction Reaction(ORR). The H2S removal efficiency of the deodorizer was higher than that of the biofilter system currently used in sewage disposal plants.

• 한국수소및신에너지학회논문집
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• 제22권2호
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• pp.168-177
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• 2011

A set of kinetics study on the reduction with $CH_4$, oxidation with steam and oxidation with air was performed for $Fe_2O_3/ZrO_2$. $Fe_2O_3/ZrO_2$ was prepared by aerial oxidation method. The reactivity experiments were performed in a thermogravimetric analyzer (TGA) with different reacting gas concentrations and temperatures. The obtained activation energy of reduction by methane, oxidation by water and oxidation by air are 219 kJ/mol, 238 and 20 respectively.

• 한국치위생학회지
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• 제7권4호
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• pp.471-479
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• 2007

The purpose of this study was to examine the optimum condition of impulse during the anodic spark oxidation applying pulse current as well as to find the excellent condition for HA precipitation the after electrochemical hydrothermal treatment by cathode reduction method. After anodic spark oxidation, the anodized specimen and the Pt plate connected cathode and anode, respectively. Hydrothermal treatment performed at 90, 120, $150^{\circ}C$ for 2 hours in the electrolyte containing $K_2HPO_4$, $CaCl_2{\cdot}2H_2O$, Tris(Hydroxymethyl)-$(CH_2OH)_3\;CNH_2$(Aminomethane), and NaCl. The optimum impulse voltage for anodic spark oxidation was 350V. The optimum pulse cycle measured at 10 mS. The HA crystals precipitated excellently by cathode reduction at $150^{\circ}C$ for 2 hours. The phases of anatase, rutile, and HA coating on the surface of modified titanium surface immersed in Hanks' solution for 3weeks were detected by XRD measurement and the intensity of HA crystal phase has increased by temperature and time of hydrothermal treatment. According to the our experiments, we found that Pure Ti will be good materials of bioactivity and biocompatibility.

• 공업화학
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• 제28권3호
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• pp.326-331
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• 2017

캐스터오일은 수소화반응을 통해 계면활성제의 중간체 등 유용한 화학산업의 원료로 활용 가능하다. 본 연구에서는 캐스터오일의 수소화용 니켈촉매의 제조조건과 전처리 조건에 대한 영향을 연구하였다. 니켈촉매는 침전제와 pH를 다르게 하여 실리카 담체상에 침전법으로 담지되었고, 다시 산화와 환원의 반복된 전처리를 행하였다. 니켈촉매의 활성은 캐스터오일의 요오드 가를 측정하여 비교하였고, 니켈촉매의 분산도는 XRD, BET, TEM을 통하여 분석하였다. 니켈촉매의 활성을 CO산화반응실험을 통하여도 비교하였다. 산화와 환원 사이클의 반복에 의해 니켈의 재분산이 실리카 상에서 발생하였고, 이것이 캐스터오일 수소화반응 활성을 증진시키는데 기여하였다.

• 한국식품과학회지
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• 제2권2호
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• pp.34-37
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• 1970

김치(동치미) 발효기간 중 산도 pH 및 산화환원전위를 측정한 결과 다음의 사실을 얻었다. 1. 산도는 젖산으로서 3.5%에 달하고 pH는 3.4까지 저하되었다. 2. 산화환원전위는 발효초기에는 상당히 높은 값인 10이상을 나타내고 발효최성기에는 15에서 2까지 저하되며 말기에서는 도리어 약간 상승하는 경향이었다. 3. 산화환원전위를 보아 김치발효 초기가 말기보다 호기적 상태임을 알 수 있었다.