• Title/Summary/Keyword: reduced-order model

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Aqueous U(VI) removal by green rust and vivianite at phosphate-rich environment

  • Sihn, Youngho;Yoon, In-Ho
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.207-215
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    • 2020
  • Vivianite (Fe32+(PO4)2·8H2O) and green rust ([Fe42+Fe23+(OH)-12][SO42-·2H2O]2-), ferrous containing minerals, could remove aqueous U(VI) in 5 min. and the efficiencies of green rust were roughly 2 times higher than that of vivianite. The zeta potential measurement results implies that the better performance of green rust might be attributed to the favorable surface charge toward uranyl phosphate species. The removal behaviors of the minerals were well fitted by pseudo-second order kinetic model (R2 > 0.990) indicating the dominant removal process was chemical adsorption. Effects of Ca2+ and CO32- at pH 7 were examined in terms of removal kinetic and capacity. The kinetic constants of aqueous U(VI) were 8 and 13 times lower (0.492 × 10-3 g/(mg·min); 0.305 × 10-3 g/(mg·min)) compared to the value in the absence of the ions. The thermodynamic equilibrium calculation showed that the stable uranyl species (uranyl tri-carbonate) were newly formed at the condition. Surface investigation on the reacted mineral with uranyl phosphates species were carried out by XPS. Ferrous iron and U(VI) on the green rust surface were completely oxidized and reduced into Fe(III) and U(IV) after 7 d. It suggests that the ferrous minerals can retard U(VI) migration in phosphate-rich groundwater through the adsorption and subsequent reduction processes.

A Study on the Fundamental Cause of Stall Stagnation Phenomena in Surges in Compressor Systems

  • Yamaguchi, Nobuyuki
    • International Journal of Fluid Machinery and Systems
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    • v.10 no.2
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    • pp.119-137
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    • 2017
  • Although the stall stagnation phenomena have often been experienced in site and also analytically in numerical experiments in surges in systems of compressors and flow paths, the fundamental causes have not been identified yet. In order to clarify the situations, behaviours of infinitesimal disturbance waves superposed on a main flow were studied in a simplified one-dimensional flow model. A ratio of the amplifying rate of the system instability to the characteristic slope of the compressor element was surveyed as the instability enhancement factor. Numerical calculations have shown the following tendency of the factor. In the situation where both the sectional area ratio and the length ratio of the delivery flow-path to the suction duct are sufficiently large, the enhancement factors are greater in magnitude, which means occurrence of ordinary deep surges. However, in the situation where the area ratio and/or the length ratio is relatively smaller, the enhancement factor tends to lessen significantly, which situation tends to suppress deep surges for the same value of the characteristic slope. It could result in the stall stagnation condition. In the domain of area ratio vs. length ratio of the delivery duct to the suction duct, contour-lines of the enhancement factor behave qualitatively similar to those of the stall stagnation boundaries of a fan analytically obtained, suggesting that a certain range of the enhancement factor values could specify the stagnation occurrence. The significant decreases in the factors are observed to accompany appearances of phase lags and travelling waves in the wave motions, which macroscopically suggests breaking down of the complete surge actions of filling and emptying of the air in the delivery duct. The strength of the action is deeply related with acoustic interferences and is evaluated in terms of the volume-modified reduced resonance frequency proposed by the author. These observations have shown the fundamental cause and the sequence of the stall stagnation in principle.

SgrA* 22GHz KaVA(+TAK) observation and its Amplitude Calibration

  • CHO, ILJE;JUNG, TAEHYUN;ZHAO, GUANG-YAO;KINO, MOTOKI;SOHN, BONGWON
    • The Bulletin of The Korean Astronomical Society
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    • v.40 no.2
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    • pp.52.2-52.2
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    • 2015
  • SgrA* located in the center of the Milky Way is of great interest to understand the physics of supermassive black hole(SMBH) and the interaction of the G2 cloud around SgrA* with the accretion flow which was expected since 2013. In order to seize this rare opportunity, KVN and VERA Array (so called, KaVA) has started an intensive monitoring program of SgrA* at 22/43 GHz where scatter broadening is reduced compared to lower frequency VLBI observations. We present the results of KaVA SgrA* observation together with Takahagi (32m) and Yamaguchi (32m) telescopes at 22 GHz on March 24, 2013. We have tested both a standard amplitude calibration methods using the Tsys and antenna gain information and a template amplitude calibration method which uses a peak of H2O maser line of nearby maser source (SgrB2), and found that the latter method is useful when an accuracy of Tsys measurement or antenna gain of a telescope is poor. In our comparison, the difference between the two methods is around 20% (~5% for the KVN and ~15% for the VERA when the elevation is above $20^{\circ}$). We also imaged SgrA* with a total flux of ~0.7 Jy at 22GHz, and fitted an elliptical Gaussian model which has a size of ~2.5mas for major axis and ~1.7mas for minor axis, respectively.

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Robust control of a heave compensation system for offshore cranes considering the time-delay (시간 지연을 고려한 해상 크레인의 상하 동요 보상 시스템의 강인 제어)

  • Seong, Hyung-Seok;Choi, Hyeong-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.41 no.1
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    • pp.105-110
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    • 2017
  • This paper introduces a heave compensation system for offshore crane when it subjected to unexpected disturbances such as ocean waves, tidal currents or winds and their external force. The dynamic model consists of a crane which is considered to behave in the same manner as a rigid body, a hydraulic driven winch, an elastic rope and a payload. To keep the payload from moving upwards and downwards, PD(Proportional-Derivative) control was applied by using linearization. In order to achieve a better performance, the sliding mode control and the nonlinear generalized predictive control algorithm was applied according to the time-delay. As a result, the oscillating amplitude of the payload was reduced by the control algorithm. Considering the time-delay involved in the system to be one second, nonlinear generalized predictive controller with a robust controller was a suitable control algorithm for this heave compensation system because it made the position of te payload reach the desired position with the minimum error. This paper presented a control algorithm using the robust control and its simulation results.

Evaluation of Factors that Can Affect Protective Immune Responses Following Oral Immunization of Recombinant Helicobacter pylori Urease Apoenzyme

  • Kim, Jang-Seoung;Chang, Ji-Hoon;Park, Eun-Jeong;Chung, Soo-Il;Yum, Jung-Sun
    • Journal of Microbiology and Biotechnology
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    • v.10 no.6
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    • pp.865-872
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    • 2000
  • Helocobacter phylori is the major cause of gastritis, peptic ulcer, and a principal risk factor for gastric cancer. As the firs step towards a vaccine against H. pylori infection, Hy.pylori urease was expressed and purified as a recombinant apoenzyme (rUrease) in E. coli. In order to develop an effective immunization protocol using rUrease, the host immune responses were evaluated after the oral immunization of mice with rUrease preparations plus cholera toxin relative to various conditions, such as the physical nature of the antigen, the frequency of the booster immunization, the dose of the antigen, and the route of administration. The protective efficacy was assessed using a quantitative culture following an H. pylori SS1 challenge. It was demonstrated that rUrease, due to its particulated nature, was more superior than the UreB subunit as a vaccine antigen. The oral immunization of rUrease elicited significant systemic and secretory antibody responses, and activated predominantly Th2-type cellular responses. The bacterial colonization was significantly reduced (~100-fold) in those mice immunized with three or four weekly oran doses of rUrease plus cholera toxin (p<0.05), when compared to the non-immunized/challenged controls. The protection correlated well with the elicited secretory IgA level against rUrease, and these secretory antibody responses were highly dependent on the frequency of the booster immunization, yet unaffected by the dose of the antigen (25-200$\mu\textrm{g}$). These results demonstrate the remarkable potential of rUrease as a vaccine antigen, thereby strengthening the possibility of developing an H. pylori vaccine for humans.

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Design and performance test of a foot for a jointed leg type quadrupedal walking robot (관절형 4족 보행로봇용 발의 설계 및 성능시험)

  • Hong, Ye-Seon;Yi, Su-Yeong;Ryu, Si-Bok;Lee, Jong-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.8
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    • pp.1250-1258
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    • 1997
  • This paper reports on the development of a new foot for a quadrupedal jointed-leg type walking robot. The foot has 2 toes, one at the front and the other at the rear side, for stable landing on uneven ground by point contact. The toes can move up and down independantly, guided by double-wishbone shaped parallel links which enable the lower leg to rotate with respect to a remote center on the ground surface. The motion of each toe is damped by a hydropneumatic shock absorber integrated in the foot in order to absorb the dynamic landing shock. Furthermore, the new foot can reduce the maximum hip joint drive torque by shortening the moment arm length between the hip joint and the landing force vector on the ground. Intensive experiments were carried out in this study by using a one-leg walking model to investigate the soft landing performance of the foot which could be hardly offered by conventional robot feet such as a flat plate with a gimbal type ankle joint. And it was confirmed that the hip joint torque of the leg walking on the flat surface could be reduced remarkably by using the new foot.

Determination of sample size to serological surveillance plan for pullorum disease and fowl typhoid (추백리-가금티푸스의 혈청학적 모니터링 계획수립을 위한 표본크기)

  • Pak, Son-Il;Park, Choi-Kyu
    • Korean Journal of Veterinary Research
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    • v.48 no.4
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    • pp.457-462
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    • 2008
  • The objective of this study was to determine appropriate sample size that simulated different assumptions for diagnostic test characteristics and true prevalences when designing serological surveillance plan for pullorum disease and fowl typhoid in domestic poultry production. The number of flocks and total number of chickens to be sampled was obtained to provide 95% confidence of detecting at least one infected flock, taking imperfect diagnostic tests into account. Due to lack of reliable data, within infected flock prevalence (WFP) was assumed to follow minimum 1%, most likely 5% and maximum 9% and true flock prevalence of 0.1%, 0.5% and 1% in order. Sensitivity were modeled using the Pert distribution: minimum 75%, most likely 80% and maximum 90% for plate agglutination test and 80%, 85%, and 90% for ELISA test. Similarly, the specificity was modeled 85%, 90%, 95% for plate agglutination test and 90%, 95%, 99% for ELISA test. In accordance with the current regulation, flock-level test characteristics calculated assuming that 30 samples are taken from per flock. The model showed that the current 112,000 annual number of testing plan which is based on random selection of flocks is far beyond the sample size estimated in this study. The sample size was further reduced with increased sensitivity and specificity of the test and decreased WFP. The effect of increasing samples per flock on total sample size to be sampled and optimal combination of sensitivity and specificity of the test for the purpose of the surveillance is discussed regarding cost.

A Study on the Triple Module Redundancy ARM processor for the Avionic Embedded System (항공용 임베디드 시스템을 위한 Triple Module Redundancy 구조의 임베디드 하드웨어 신뢰성 평가)

  • Lee, Dong-Woo;Kim, Byeong-Young;Ko, Wan-Jin;Na, Jong-Whoa
    • Journal of Advanced Navigation Technology
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    • v.14 no.1
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    • pp.87-92
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    • 2010
  • The design of avionic embedded systems requires high-dependability. In this paper, we studied the dependability of the triple modular redundancy (TMR) hardware for highly reliable aviation embedded system. In order to evaluate the dependability of the base ARM processor and the TMR ARM processor, we developed the simulation model of the reduced ARM and TMR ARM processors and performed the simulation fault injection for the analysis of the dependability of the two targets. In the fault injection experiments, we calculated the error recovery rate of the two the processor models. From the experimental results, we could confirm that the reliability of the TMR ARM processor was greater than the single ARM processor by ten times in some cases.

Effect of carbon substrate on the intracellular fluxes in succinic acid producing Escherichia coli.

  • Hong, Soon-Ho;Lee, Dong-Yup;Kim, Tae-Yong;Lee, Sang-Yup;Park, Sun-Won
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2003.10a
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    • pp.251-257
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    • 2003
  • Metabolic engineering has become a new paradigm for the more efficient production of desired bioproducts. Metabolic engineering can be defined as directed modification of cellular metabolism and properties through the introduction, deletion, and modification of metabolic pathways by using recombinant DNA and other molecular biological tools. During the last decade, metabolic flux analysis(MFA) has become an essential tool fur metabolic engineering. By MFA, the intracellular metabolic fluxes can be quantified by the measurement of extracellular metabolite concentrations in combination with the stoichiometry of intracellular reactions and mass balances. The usefulness and functionality of MFA are demonstrated by applying to metabolic pathways in E. coli. First, a large-scale in silico E. coli model is constructed, and then the effects of carbon sources on intracellular flux distributions and succinic acid production were investigated on the basis of the uptake and secretion rates of the relevant metabolites. The results indicated that succinic acid yields increased in order of gluconate, glucose and sorbitol. Acetic acid and lactic acid were produced as major products rather than when gluconate and glucose were used carbon sources. The results indicated that among three carbon sources available, the most reduced substrate is sorbitol which yields efficient succinic acid production.

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Nanotribological Properties of Chemically Modified Graphene

  • Kwon, Sangku;Ko, Jae-Hyeon;Byun, Ik-Su;Choi, Jin Sik;Park, Bae Ho;Kim, Yong-Hyun;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.159-159
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    • 2013
  • Atomically thin graphene is the ideal model system for studying nanoscale friction due to its intrinsic two-dimensional anisotropy. Furthermore, modulating its tribological properties could be an important milestone for graphene-based micro and nano-mechanical devices. Here, we report that the tribological properties can be easily altered via simple chemical modifications of the graphene surface. Friction force microscopy measurements show that hydrogenated, fluorinated, and oxidized graphenes exhibit, 2-, 6-, and 7-fold enhanced nanoscale friction on their surfaces, respectively, compared to pristine graphene. The measured nanoscale friction should be associated with the adhesive and elastic properties of the chemically modified graphenes. Density functional theory calculations suggest that, while the adhesive properties of chemically modified graphenes are marginally reduced down to ~30%, the out-of-plane elastic properties are drastically increased up to 800%. Based on these findings, we propose that nanoscale friction on graphene surfaces is characteristically different from that on conventional solid surfaces; stiffer graphene exhibits higher friction, whereas a stiffer three-dimensional solid generally exhibits lower friction. The unusual friction mechanics of graphene is attributed to the intrinsic mechanical anisotropy of graphene, which is inherently stiff in plane, but remarkably flexible out of plane. The out-of-plane flexibility can be modulated up to an order of magnitude by chemical treatmentof the graphene surface. The correlation between the measured nanoscale friction and the calculated out-of-plane flexibility suggests that the frictional energy in graphene is mainly dissipated through the out-of-plane vibrations, or the flexural phonons of graphene.

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