• Title/Summary/Keyword: redispersible

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Photoluminescence properties of core/shell-type $LnPO_4:Eu/LnPO_4$ (Ln=La, Gd) nanophosphors

  • Oh, Jae-Suk;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1551-1554
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    • 2007
  • To overcome defect due to large surface of nanoparticle, a redispersible Eu doped $LnPO_4:LnPO_4$ core/shell nanoparticles were prepared in a highboiling coordinating solvent. The particle size of the synthesized core/shell nanophosphors was estimated to be about 8 nm by TEM. In this core/shell nanoparticle, the concentration of Eu ion was optimized on the basis of the emission intensity under UV ray excitation. Also, the PL properties of the nanophosphors have been compared with those of the $LnPO_4:Eu$ nanoparticles.

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Mechanical Properties and Durability of Abrasion of EVA Concrete Reinforced Steel Fiber (강섬유 보강 EVA 콘크리트의 역학적 특성 및 내마모성)

  • Sung, Chan Yong;Nam, Ki Sung
    • Journal of The Korean Society of Agricultural Engineers
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    • v.56 no.5
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    • pp.45-54
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    • 2014
  • This study was performed to evaluate compressive strength, flexural strength, static modulus of elasticity, stress-strain ratio and durability of abrasion on EVA concrete reinforced steel fiber (SF) in order to use hydraulic structures, underground utilities, offshore structures and structures being applied soil contaminated area. It is used ordinary portland cement, crushed coarse aggregate, nature fine aggregate, EVA redispersible polymer powder, superplasticizer and deforming agent to find optimum mix design of EVA concrete reinforced steel fiber. EVA concrete reinforced SF was effected on the improvement of mechanical properties and durability of abrasion.

The Effect of Curing condition on Adhesion in Tension of Polymer-Modified Mortars (양생존건이 폴리머 시멘트 모르터의 접착강도에 미치는 영향)

  • 전우성;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.04a
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    • pp.349-356
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    • 1997
  • The purpose of this study is to evaluate the effect of curing conditions on adhesion in tension of polymer-modified mortar to cement mortar substrate in comparision with ordinary cement mortar. The polymer-modifies mortars using two polymer dispersions and a redispersible polymer power are prepared with various polymer-cement ratios, and tested for the adhesion in tension of the specimens subjected to five curing conditions. From the test results, the adhesion in tension of polymer-modified mortars tends to increase with increasing polymer-cement ratio irrespective of the polymer types and curing conditions. It is apparent that adhesion in tension of polymer-modified mortars is considerably influenced by curing conditions.

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Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Redispersible Polymer Powder with Nitrite-Type Hydrocalumite (재유화형 분말수지와 아질산형 하이드로칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Wan-Ki;Hong, Sun-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.3
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    • pp.275-283
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    • 2012
  • Nitrite-type hydrocalumite (calumite) is a material that can adsorb the chloride ions ($Cl^-$)that cause the corrosion of reinforcing bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete, and can provide a self-corrosion inhibition function to the reinforced concrete. In this study, VA/E/MMA-modified mortars with calumite were prepared with various calumite contents and polymer binder-ratios, and tested for corrosion inhibition, chloride ion penetration, carbonation and drying shrinkage. As a result, regardless of polymer-binder ratio, the replacement of ordinary Portland cement with hydrocalumite has a marked effect on the corrosion inhibiting property of the polymer-modified mortars. However, chloride ion penetration and carbonation depths are somewhat increased with higher calumite content, but can be remarkably decreased depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to increase with the polymer-binder ratio and calumite content. VA/E/MMA-Modified mortars with 10 % calumite did not satisfy KS requirements. Accordingly, a calumite content of 5 % is recommended for the VA/E/MMA-modified mortars with calumite.

Effect of Substrate Surface Water on Adhesive Properties of High Flowable VA/VeoVa-modified Cement Mortar for Concrete Patching Material (단면수복용 고유동성 VA/VeoVa 개질 시멘트 모르타르의 부착특성에 대한 피착면 표면수의 영향)

  • Do, Jeong-Yun;Kim, Doo-Kie
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.94-104
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    • 2013
  • Experiments were divided into two parts; one part is to understand the basic properties of high flowable VA/VeoVa-modified cement mortar with different polymer cement ratio (P/C) and the weight ratio of fine aggregate to cement (C:F) and the other part is to investigate the effect of surface water spread on the concrete substrate on adhesion in tension. To understand the basic performance, the specimens were prepared with proportionally mixing VA/VeoVa redispersible powder, ordinary portland cement, silica sand, superplasticizer and viscosity enhancing agent. Here, P/C were 10, 20, 30, 50 and 75% and C:F were 1:1 and 1:3. As the change of P/C and C:F unit weight, flow test, crack resistance and adhesion in tension were measured. Three specimens with good adhesion properties were selected among specimens with different P/C and C:F. The effect of surface water evenly sprayed on concrete substrate on adhesive strength is investigated. The results show that surface water on concrete substrate increases the adhesion in tension of high flowable VA/VeoVa-modified cement mortar and additionally improves the flowability compared to the non-sprayed case.

Effect of polymer addition on air void content of fine grained concretes used in TRCC

  • Daskiran, Esma Gizem;Daskiran, Mehmet Mustafa;Gencoglu, Mustafa
    • Computers and Concrete
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    • v.20 no.2
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    • pp.165-176
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    • 2017
  • Textile Reinforced Cementitious Composite (TRCC) became the most common construction material lately and have excellent properties. TRCC can be employed in the manufacture of thin-walled facade elements, load-bearing integrated formwork, tunnel linings or in the strengthening of existing structures. These composite materials are a combination of matrix and textile materials. There isn't much research done about the usage of polymer modified matrices in textile reinforced cementitious composites. In this study, matrix materials named as fine grained concretes ($d_{max}{\leq}1.0mm$) were investigated. Air entraining effect of polymer modifiers were analyzed and air void content of fine grained concretes were identified with different methods. Aim of this research is to study the effect of polymer modification on the air content of fine grained concretes and the role of defoamer in controlling it. Polymer modifiers caused excessive air entrainment in all mixtures and defoamer material successfully lowered down the air content in all mixtures. Latex polymer modified mixtures had higher air content than redispersible powder modified ones. Air void analysis test was performed on selected mixtures. Air void parameters were compared with the values taken from air content meter. Close results were obtained with tests and air void analysis test found to be useful and applicable to fine grained concretes. Air void content in polymer modified matrix material used in TRCC found significant because of affecting mechanical and permeability parameters directly.

A Study on the Development of Water-Permeable Concretes for Overlay (오버레이용 투수성 콘크리트의 개발에 관한 연구)

  • 은재기;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.223-226
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    • 1999
  • The purpose of this study is no examine the combination effect on strength preperties of water-permeable concretes mixed with redispersible polymer, silica fume and polypropylene fibers for overlay in pavement. The water-permeable concrete with a water-cement ration of 25%, polymer-cement ratios of 0 to 10%, silica fume contents of 0 to 10% and polypropylene fiver contents of 0 to 1.5% are prepared, and tested for flexural strength, compressive strength and water permeability. It is concluded concretes are obtained at a polypropylene fiber content of 1.0% and a silica fume content of 10% with a void filling ratio of 50%. And the water-permeable concretes with a flexural strength of 14.1~28.0kgf/$\textrm{cm}^2$, a compressive strength of 71.2~128.0kgf/$\textrm{cm}^2$, and a coefficient of permeability of 1.22~2.52cm/s at a void filling ratio of 30% can be prepared. Also water-permeable concretes having flexural strength of 24.9~57.9kgf/$\textrm{cm}^2$, a compressive strength of 83.8~268.5kgf/$\textrm{cm}^2$, and a coefficient of permeability of 0.24~1.04cm/s at a void filling ratio of 50% can be prepared in the consideration of the mix proportioning factors.

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Preparation and Evaluation of Vitamine A palmitate Dry Emulsion (비타민 A 팔미틴산 건조 유제의 제조 및 평가)

  • Lee, Jong-Pyo;Han, Kun
    • Journal of Pharmaceutical Investigation
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    • v.30 no.4
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    • pp.259-266
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    • 2000
  • Vitamin A palmitate, an oily drug which has low chemical stability and is poorly absorbed in the intestine, was formulated into a novel powdered dosage form. This is designated as a redispersible dry emulsion by freeze-drying technique. Before preparing a dry emulsion, vitamin A palmitate oil in solid in water (O/S/W) emulsion with soybean oil and coconut oil using Aerosil 200 as an emulsion stabilizer and polyoxyethylene-polyoxypropylene-blockcopolymer (Pluronic F68) as a surfactant was prepared. The resultants of the stability tests indicated that vitamin A palmitate O/S/W emulsion was improved on increasing the oil content of the formulation. The resultant dry emulsion particles have a good stabilities and free flow properties and readily released the oily droplets to form stable emulsions on rehydration. The drug releasing property from the resultant dry emulsion particles was dependent on factors such as amount of oily carrier(soybean oil) and surfactant(Pluronic F68) formulated. Above 80% of vitamin A palmitate content was released from the dry emulsion for 1 hour. It was deduced that vitamin A palmitate dry emulsion was definitely suitable for oral administration, since small droplets of vitamine A palmitate from the dry emulsion may alter the drug absorption profile resulting in bioavailability enhancement.

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The Compressive Strength and Durability Properties of Polypropylene Fiber Reinforced EVA Concrete (폴리프로필렌 섬유 보강 EVA 콘크리트의 압축강도 및 내구성)

  • Nam, Ki Sung;Sung, Chan Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.57 no.4
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    • pp.11-19
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    • 2015
  • The important properties of EVA (ethylene vinyl acetate) redispersible polymer was waterproof, densification of internal pore space of concrete and ball bearing and micro filler. Also, the significant role of polypropylene(PP) fiber was crack control and blockade of movement for deterioration factors. The most studies for EVA were limited in the field of mortar and PP fiber reinforced concrete had been studied in the state of being restricted unit water content, rich mix and mixing much of the fiber without considering construction site. Therefore, the control mix design were applied in ready mixed concrete using 10 % fly ash of total cement weight used in batch plant. On the basis of control mix design, EVA contents ranging from 0 % to 10 % of total cement weight and PP fiber contents ranging from 0 % to 0.5 % of EVA concrete volume were used in the mix designs. The results showed the maximum compressive strength value was measured at EVA 5.0 % and PP fiber 0.1 %, the minimum water absorption ratio was at EVA 10 % and PP fiber 0 %, the durability factor for freezing and thawing resistance was at EVA 5.0 % and PP fiber 0.3 % and the minimum weight reduction ratio of resistance to sulfuric acid attack was at EVA 10 % and PP fiber 0.5 % after curing age 42days. Meanwhile, From these results, PP fiber reinforced EVA concrete would be very benefit, if each optimal mix types were used in hydraulic structures, underground utilities and agricultural structures.

Bonding Properties of Steel-reinforced Polymer Cement Mortar Evaluated by Pull-off Test and FEM Modeling (폴리머 시멘트 모르타르의 철근부착력 평가를 위한 인발실험과 모델링)

  • Park, Dong-Cheon;Yoneda, Nobutosi;Cho, Bong-Suk
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.3
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    • pp.216-222
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    • 2014
  • Chloride attack to reinforced concrete structures located in seaside can cause a serious problem of durability and maintenance during the service life. Corrosion of reinforced steel bars in concrete decreases the bond strength and finally causes the detachment of concrete cover. Polymer cement mortar is usually adopted to repair the deteriorated RC structures because of its strong bonding property. The recovered load-carrying capacity after the repair was simulated by non-linear FEM analysis. The properties of concrete, repairing materials, bonding materials and reinforced bar were used as input data. Four types of redispersible polymer powders were used as components of polymer cement mortar. Pull-off tests were carried out to examine the bond properties such as rigidity and strength. Effects of a corrosion inhibitor and the loss of reinforced bars due to the corrosion were also considered in this study. FEM modeling and analysis were conducted to propose the universal model. Physical bonding in the relationship between repair materials and steel reinforced bar is more dominant than chemical bonding.