• Title/Summary/Keyword: recycling of $CO_2$

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Preparation and Characterization of Activated Carbon Derived from Leather Waste Discharged from Shinpyung Changrim Industrial Complex (신평 장림공단 피혁폐기물(皮革廢棄物)을 이용한 활성탄(活性炭) 제조(製造) 및 특성(特性))

  • Park, Seung-Cho;Nam, Jeong-Kwang;Kim, Jung-Sup
    • Resources Recycling
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    • v.17 no.1
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    • pp.20-28
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    • 2008
  • Leather waste discharged from Shinpyung Changrim Industrial Complex contained 46.3 percent of carbon, and weight loss of leather waste about 50 percent was observed at $500^{\circ}C$ by thermogravimetric analysis. Chemically activated carbon [LW4AC] was made at activation temperature of $800^{\circ}C$ during 30 minutes in electric furnace. Iodine value and decoloration of methylene blue was 968 mg/g and 158 mL/g, respectively. We found that pore volume was more developed according to the increase in the ratio of $K_2CO_3/LW$.

Calculation and Projection of Methane Emissions from Waste Landfill for GHG Emission Reduction: Case Study of Puerto Cortes Landfill in Honduras (폐기물 매립지의 온실가스 감축을 위한 메탄가스 배출량 평가: 온두라스 Puerto Cortes 매립장 사례 분석)

  • Choong Gon Kim
    • Journal of the Korea Organic Resources Recycling Association
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    • v.32 no.1
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    • pp.13-19
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    • 2024
  • The objective of this study was to assess the feasibility of a landfill project aimed at reducing greenhouse gas (GHG) from Puerto Cortes Landfill in Honduras ("Project"). The feasibility study involved surveying the status, composition and amount of waste entering the landfill, and projecting GHG emissions from the landfill. A projection of the GHG emissions with the IPCC model and based on the survey results indicated that the period 2027 to 2041 would see a total GHG emission reduction of 506,835 ton-CO2/year, with a mean yearly GHG emission reduction of 33,789 ton-CO2, assuming landfill gas collection is implemented, The findings of the study are expected to serve as basic data for deciding about whether and how to proceed with the Project.

Study of Using Carbon Dioxide for Obtaining Potassium Chloride from Cement By-Pass Dust (시멘트 바이패스 더스트 내 염화칼륨 수득을 위한 이산화탄소 적용 연구)

  • Kim, Kyoungseok;Chu, Yongsik
    • Resources Recycling
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    • v.26 no.6
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    • pp.38-44
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    • 2017
  • As by-pass dust (BPD) made from cement manufactured process is designated waste, it is required to bury as high cost. The main component of BPD is potassium chloride (KCl), and used for the fertilizer. For using KCl to the fertilizer, the pH value of KCl is required as neutral or weak acid. However, it is not suitable to apply BPD into the fertilizer directly without any other treatment because BPD's pH value is shown 12.0~12.5; a high base. In this study, the carbon dioxide ($CO_2$) was used for removing calcium oxide (CaO) and reducing pH value during manufacturing process of KCl. We fixed inner condition of the carbon test chamber as $25^{\circ}C$-50RH%, and retained 0~7 hours under the 20 vol% of $CO_2$ atmosphere. After experiment, we analyzed the content of CaO and pH value from each samples. The more time exposed to $CO_2$, the content of CaO and pH value are shown. Furthermore, pH value exposed in 6 hours nearly reached 7.

Fabrication of Rubber Block by using Recycled Waste Tires (폐타이어 재활용 고무보도블럭의 제조에 관한 연구)

  • 김진국
    • Resources Recycling
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    • v.4 no.4
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    • pp.70-75
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    • 1995
  • Waste tires arc used as landifill, combustion and recycling. Rccenllg. lhc recycling of waste tires received a great attentmu fiam all industries. Thc rccgcling methods for w s l e tires are classified inla three culegoljz, a whole tirc, cmmb rubha and energy. T h ~ ssl iidy invesligvled the pruduclion ol Lhc ruhhcr block by using clumh cubbel oI wasle Ires. The process 01 manulacluring the ~uhher block was co~lsislerl ol several slepc: collecting lilts, ctuilnng and grinding hrcs, mixing crumh ruhher wlth bmder. and shaping under heat and pressure The effccl ol binder on ll~e ~uecl~ilnicaplr opcrlics o l r uhher hlock war also investigalcd. The economic feaqihility of a surface treiilmcnl and multilayas on the rubber block was dclcimincd

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Production of Fine Cobalt Metal Powders from Superalloy Scrap(1) (Treating Superalloy Scrap with Zinc) (Superalloy 스크랩으로부터 Co 미분말의 제조(1) (Superalloy 스크랩의 아연처리))

  • 박문경;이영근
    • Resources Recycling
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    • v.4 no.1
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    • pp.52-59
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    • 1995
  • Treating bulk superalloy scrap with molten zinc has been studled to facililate recycling and recovery- of cobalt.Superalloys investigated were the cobalt-base Mar-M-509 and X45 and the nickel-base Rene 80. Charges withZnlscrap ratlos of 1.5-6.5 were heated to 750-9002 far 1-7.5 hours in a nitrogen atmosphere. The moltenzinc dissolved superalloy scrap and zinc was removed by vacuum distillation at 850-Wk for 4-6 hours. Ithas been concluded that the optimum conditions of decomposition for Mar-M-509 and Rene 80 \"ere dissolutiontemperature of about 850k, Znlscrap ratlo of about 5, and dissalution time of about 5.5 hours. The zinc-treatedsuperalloy prouducts were friable and reacted rapidly with acid solutions. Leaching 9mm pieces of unalloyedMar-M-509 or Rene 80 with 5 times the stolchlometric amount oi 6N HCI at 90t ior 3 hours dissolved about1.5-7.270, while leachmg of the minus 20-mesh products dissolved about 89.0-93.0%.ved about 89.0-93.0%.

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Evaluation of Recycling Resources in Discarded Information and Communication Technology Devices (Smartphones, Laptop computers) (폐 정보통신기기(스마트폰, 노트북 PC)의 자원화 가치 분석)

  • Park, Seungsoo;Jung, Minuk;Kim, Seongmin;Han, Seongsoo;Jung, Insang;Park, Jihwan;Park, Jaikoo
    • Resources Recycling
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    • v.27 no.3
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    • pp.16-29
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    • 2018
  • In this study, metal and nonmetal contents and their economic values in ICT devices such as smart phones and laptop computers were evaluated. The electronic devices made by LG and Samsung were disassembled into 5 parts, which are printed circuit board assembly, battery, display, case and other electronic components. Metal and nonmetal contents in these parts were analyzed, and their economic values were calculated via multiplying the materials' contents by metal price obtained from KOMIS or nonmetal exchange price acquired from Korean recycling markets. Finally, the materials' contents and values according to each electronic parts and electronic devices were calculated. The results showed that the value of the smartphones and laptop computers of LG are 4,449.6 KRW (28,506 KRW/kg) and 6,830.2 KRW (7,053 KRW/kg), and those of Samsung are 1,849.3 KRW (13,499 KRW/kg) and 6,667.5 KRW (4,831 KRW/kg), respectively. It was also found that most of the value was concentrated in batteries and printed circuit board assemblies. In addition, Co, Au and Cu were found to be the most valuable resources in the devices.

A Study on the Cementation of Cu, Ni and Co Ions with Mn Powders in Chloride Solution (염산용액중에서 망간분말에 의한 구리, 니켈 및 코발트 이온의 세멘테이션에 관한 연구)

  • 안재우;안종관;박경호
    • Resources Recycling
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    • v.9 no.3
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    • pp.3-12
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    • 2000
  • A Study on the cementation for the recovery of Cu, Ni and Co with Mn metallic powders in leaching solution from the manganese nodule that have removed Fe ions was studied. The results showed that the recovery efficiencies of metal ions with Mn powders increased when the temperature, pH and the concentration of chloride ions were increased in mixed solution. And the recovery efficiencies of Cu was 98% and not changed with the addition amounts of Mn powders but, in case of Co and Ni, the recovery efficiencies were increased with the addition amounts. The particle size of precipitate was about $5\mu\textrm{m}$. From the results of experiment we proposed the two-step cementation process for the recovery of Cu, Ni and Co with Mn powders.

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Recovery of Copper from Sludge of Copper Electro-Plating Plant (동전해도금공장 Sludge로부터 동의 회수)

  • Young-Gil Hwang;Youn-Soo Kim;Jae-Il Kim
    • Resources Recycling
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    • v.5 no.3
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    • pp.31-36
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    • 1996
  • The metallic copper was recovered from sludge of the copper electro-plating plant by pyrometallurgical process. The reducing agent was Pyrolysized from waste tires and the flux was a mixture $Na_2CO_3$, $NaB_4O_7$, and glass. The green sludge contained 87.5% moisture and 12.5% solid with 56.5% Cu and 1.59% Fe. The sludge dried at $100^{\circ}C$ was analyized to be $Cu_4SO_4(OH)_6{\cdot}2H_2O$ and CuO by XRD analysis. The former was 84% and the latter 16%, However, the calcined sludge at $500^{\circ}C$ was 49% $Cu_2O(SO_4)$ and 51% CuO. The sludge could by smelted at $1100^{\circ}C$ for two hours with 6 to 8 moles carbon with respect to copper to produce metallic copper (>90%) with recovery of 9% above.

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The Efficacy Assessment and Manufacture of Kitchen Garden Soil Using Livestock Manure for an Urban Agriculture (가축분뇨를 활용한 도시텃밭 재배용토 제조 및 효능성 평가)

  • Lee, Jong-Jin;Chang, Ki Woon;Han, Ki-Pil;Hong, Joo-Hwa;Lee, Dong-Soek;Kim, Young-Jun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.2
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    • pp.61-66
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    • 2015
  • In this study, manufacture of kitchen garden soil and its application on the growth of Lettuce has been performed. The optimal ratio of various raw materials for pH, total nitrogen, phosphate, cations, and salt content was found to be 49 : 35 : 10 : 5 : 1(w/w) in peatmoss, livestock manure, cocopeat, zeolite, and microbial fertilizer, respectively. In the growth experiment using Lettuce, the manufactured soil obtained 21% & 20% increase in leaf length and width, 17% increase in chlorophyll, and 22% in biomass, compared to the control.

Lithium Recovery from NCM Lithium Ion Battery by Hydrogen Reduction Followed by Water Leaching (NCM계 리튬이온 배터리 양극재의 수소환원과 수침출에 의한 리튬 회수)

  • So-Yeong Lee;So-Yeon Lee;Dae-Hyeon Lee;Ho-Sang Sohn
    • Resources Recycling
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    • v.33 no.1
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    • pp.15-21
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    • 2024
  • The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H2O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.