• Title/Summary/Keyword: recycling of $CO_2$

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A Study on the Fixed amount of CO2 and the estimation of production on CaCO3 of Waste Concrete Powder using the Ca(OH)2 (Ca(OH)2를 이용한 폐콘크리트 미분말의 CO2 고정량 및 CaCO3 생성량 추정에 관한 연구)

  • Ahn, Hee-Sung;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.117-118
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    • 2011
  • South Korea is a ninth greenhouse gas emission nation in the world(2007) and is certainly to perform a duty to conduct reduction role by the Kyoto Protocol in 2013. waste concrete produced in the country is 45 million tons per year and these two issues are being came to the fore as major problems of society. However, if it utilizes wet carbonation system carbon using carbon dioxide and waste concrete as raw material it can expect effect of environmental protection and resource recycling. Furthermore, it can exploit another industry production.

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Morphology of La-Co substituted SrM ferrite (La-Co치환량에 따른 스트론튬 페라이트의 미세구조)

  • Jang, Se-Dong
    • Resources Recycling
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    • v.13 no.6
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    • pp.31-36
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    • 2004
  • This experiment was carried out to examine the effects of morphology on properties of La-Co substituted SrM ferrite. The magnetic properties of calcined and sintered materials were varried with the substitutional amount of La and Co elements in Sr-ferrite. In the substituted SrM ferrite, the atomic fraction x of La is directly related to the mole ratio n of iron oxide and the atomic fraction y of Co by equation x=2ny. The Hcj values of the calcined powder were about 270 kA/m and 240 kA/m with x=0.3 and x=0.2, respectively at stoichiometry, n=6.0. Crystallites of the sintered material were grown with a plate shape, and their size decreased with increasing mole ratios. Such a shape was caused by the initial state of crystallite formed after calcination. In case of x=0.3 and n=6.0, Br was 415 mT and Hcj was 355 kA/m, and in x=0.2 and n=6.0, Br was 410 mT and Hcj was 370 kA/m. The squareness in 2nd quarter of BH curve with x=0.2 was smoothly improved to compared with x=0.3.

A Study on the Estimation of Greenhouse Gas Using Oyster Shell Recycling for Paper Filler

  • Park, Seung-Chel;Seo, Ran-Sug;Kim, Sung-Hu
    • Journal of Environmental Science International
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    • v.25 no.1
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    • pp.23-29
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    • 2016
  • This study has conducted greenhouse gas emission reduction test as using Oyster-shells originated PCC paper filler compare to non-Oyster shells used PCC. This examination was estimated and calculated in accordance with both IPCC (Intergovernmental Panel on Climate Change) and World Business Council for Sustainable Development (WBSCD). The greenhouse gas emission reduction estimation result indicates that, when oyster shells are recycled and used as paper filler, it reduces $27.97tCO_2\;per\;100\;ton$ of oyster shells. It is greenhouse gas emission $44.27tCO_2$ from PCC production changed to carbon emission reduction when replaced with oyster shell. LNG greenhouse gas emission $16.3tCO_2$ in relation to the pre-treatment with oyster shell per 100 ton is also reflected. As a result, it is assumed that roughly $0.2797tCO_2/oyster\;shell{\cdot}ton$.

Carbon Dioxide Storage and Calcium Carbonate Production through Indirect Carbonation Using Paper Sludge Ash and Chelating Reagents (제지슬러지소각재 및 킬레이트제 활용 간접탄산화 방법을 통한 이산화탄소 저장 및 탄산칼슘 생성)

  • Jeon, Junhyeok;Kim, Myoung-Jin
    • Resources Recycling
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    • v.28 no.3
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    • pp.35-44
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    • 2019
  • In this study, we conducted experiments to store $CO_2$ and produce $CaCO_3$ through indirect carbonation using paper sludge ash (PSA) and three chelating reagents (fumarate, IDA and EDTA). Fumarate and IDA used as solvents could facilitate the indirect carbonation reaction to store more $CO_2$ than water. When 0.1 M fumarate and IDA were used, $CO_2$ storage was 63 and $89kg-CO_2/ton-PSA$, respectively, and $CaCO_3$ yield was 144 and $202kg-CaCO_3/ton-PSA$. For the case of EDTA, however, the carbonation was hardly progressed. As either the concentration or Ca-ligand stabilization constant of each chelating reagent increased, the calcium extraction efficiency from PSA increased. In addition, the carbonation efficiency was influenced by the Ca-ligand stabilization constant. As the Ca-ligand stabilization constant increased, more calcium could be extracted from the PSA. With the constant larger than that of $CaCO_3$ ($10^{8.35}$), however, the carbonation reaction was not proceeded.

High Pressure Leaching of Matte Converted from Cobalt Concentrate from Democratic Republic of the Congo (콩고산 코발트 정광으로부터 제조한 매트의 고온고압침출)

  • Kim, Gunha;Kang, Ga-hee;Kim, Sookyung;Sohn, Jeongsoo;Kwon, Kyungjung
    • Resources Recycling
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    • v.24 no.4
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    • pp.32-37
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    • 2015
  • Cobalt is abundant only in some countries including Democratic Republic of the Congo. It would be necessary to secure overseas Co ores and Co extraction technology. Two kinds of matte varying the sulfur content were manufactured by smelting reduction of Co concentrate containing ~8 wt% Co, ~19 wt% Cu, and ~3 wt% Fe. The amount of Co, Cu and Fe was concentrated to 19~21 wt%, 39~41 wt%, and 7~9 wt% respectively in the resulting matte. High-pressure leaching of matte was performed in an autoclave with considering the effect of oxidizing agent, $H_2SO_4$ concentration as a lixiviant, and the amount of sulfur added to the matte. An oxidizing agent (oxygen) is necessary to improve Co leaching efficiency enabling usage of a dilute $H_2SO_4$ leaching agent. An increase in $H_2SO_4$ concentration prevents selective leaching of Co, and the sulfur content in matte has a minor influence on the Co leaching efficiency.

Separation of Co(II), Ni(II), and Cu(II) from Sulfuric Acid Solution by Solvent Extraction (황산용액에서 용매추출에 의한 코발트(II), 니켈(II) 및 구리(II) 분리)

  • Moon, Hyun Seung;Song, Si Jeong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.31 no.1
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    • pp.21-28
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    • 2022
  • The smelting reduction of spent lithium-ion batteries results in metallic alloys of cobalt, nickel, and copper. To develop a process to separate the metallic alloys, leaching of the metallic mixtures of these three metals with H2SO4 solution containing 3% H2O2 dissolved all the cobalt and nickel, together with 9.6% of the copper. Cyanex 301 selectively extracted Cu(II) from the leaching solution, and copper ions were completely stripped with 30% aqua regia. Selective extraction of Co(II) from a Cu(II)-free raffinate was possible using the ionic liquid ALi-SCN. Three-stage cross-current stripping of the loaded ALi-SCN by a 15% NH3 solution resulted in the complete stripping of Co(II). A process was proposed to separate the three metal ions from the sulfuric acid leaching solutions of metallic mixtures by employing solvent extraction.

An Adiabatic Characteristic on the Waste tyre Powders Mortar-Containing (폐타이어 분말을 혼입한 몰탈의 단열특성)

  • Choi, Jae-Nam;Son, Ki-Sang
    • Journal of the Korean Society of Safety
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    • v.20 no.2 s.70
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    • pp.105-112
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    • 2005
  • This is to find out that cement mortar mixed with waste tie particle can be applied for recycling it and enhanced to have shock absorption capacity. Therefore, architectural material specification and its related references for the disposal of it are based on for the study. Test has been performed with procedure, based on the Korea Standard insulation mortar and Compressive Strength Test has been done at K remicon factory approved by Korea Government in Korea, in order to decrease any possible error in mixing procedure. Test molds far insulation capacity and cohesive strength have been delivered to the expert agency for having more exact results. The result from the above test shows that waste tyre mixed with cement mortar has almost equal to the common concrete. This means that the recycling of the waste t)re will be demanded more and more in case of having continued development for this recycling area. And also waste t)to-using construction material can be more applied for construction area than existing material. Thus, this recycling method can be very usefully applied for solving environmental problem and for establishing economic aspect.

Recycling Energy from Mixture of Sewage Sludge and Petroleum Coke Waste

  • Lee, Ki-Hwan;Lee, Tae-Ho;Kim, Jong-In;Park, Byung-Bin;Choi, Suk-Nam;Han, Ki-Suk
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_2
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    • pp.73-77
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    • 2001
  • The disposal of sewage sludge using landfills and ocean dumping is no longer a viable option due to land scarcity and increasingly stringent environmental control regulations. As such, various efforts have been made to develop new sewage sludge recycling technologies. This work investigates the fundamental physical and chemical characteristics of rural type sewage sludge from Chungnam province in South Korea. The average moisture content, ignition loss, elementary analysis, and average heating value of the sewage sludge samples were examined. The average moisture content of the dewatered sludge was about 80%, while the organic matter was about 50% of the total solid sludge weight. The average heating value of a sewage sludge and petroleum coke waste mixture(1:1 weight ratio) was about 5,000 ㎉/kg, thereby indicating a high potential for energy recycling.

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Pyrolysis Reaction Characteristics of Biomass Fluidized Bed Reactor (기포(氣泡) 유동층(流動層) 반응기(反應器)에서 바이오매스 열분해(熱分解) 반응특성(反應特性))

  • Lee, Sun-Hoon;Yoo, Kyung-Seun;Lee, See-Hoon;Lee, Jae-Goo;Kim, Jae-Ho
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.10a
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    • pp.75-82
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    • 2005
  • Pyrolysis of biomass is one of the promising methods to obtain energy and valuable chemical stocks. Fast pyrolysis of Q. acutissima and L. letolepis has been carried out in a bubbling fluidized bed reactor to determine the optimum operating conditions of the pyrolyzer. Effects of reaction temperature, Uo/Umf, L/D ratio, and feed rate have been determined and the optimum conditions are as follows: $T\;=\;400^{\circ}C,\;U_o/U_{mf}\;=\;3.0,\;L/D\;=\;2.0$. Maximum yield of bio-oil was about 55% and the main compositions were carbohydrates, guaiacols, furans, phenols, and syringols. Product gas was consists of CO, $CO_2$, light hydrocarbons and the measured gas yield using the compositions agreed with the calculated value.

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Preparation and Characterization of Activated Carbon Derived from Leather Waste Discharged from Shinpyung Changrim Industrial Complex (신평 장림공단 피혁폐기물(皮革廢棄物)을 이용한 활성탄(活性炭) 제조(製造) 및 특성(特性))

  • Park, Seung-Cho;Nam, Jeong-Kwang;Kim, Jung-Sup
    • Resources Recycling
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    • v.17 no.1
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    • pp.20-28
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    • 2008
  • Leather waste discharged from Shinpyung Changrim Industrial Complex contained 46.3 percent of carbon, and weight loss of leather waste about 50 percent was observed at $500^{\circ}C$ by thermogravimetric analysis. Chemically activated carbon [LW4AC] was made at activation temperature of $800^{\circ}C$ during 30 minutes in electric furnace. Iodine value and decoloration of methylene blue was 968 mg/g and 158 mL/g, respectively. We found that pore volume was more developed according to the increase in the ratio of $K_2CO_3/LW$.