• Title/Summary/Keyword: recycling efficiency

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Crosslinking of $\beta$-Cyclodextrin on Cholesterol Removal from Milk

  • Kim, S.H.;Ahn, J.;Kwak, H.S.
    • Archives of Pharmacal Research
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    • v.27 no.11
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    • pp.1183-1187
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    • 2004
  • This study was designed to develop crosslinking of $\beta$-cyclodextrin ($\beta$-CD), and determine the optimum conditions of different factors (mixing time, mixing temperature, and mixing speed) on cholesterol reduction from milk. Crosslinked $\beta$-CD was prepared with epichlorohydrin. When milk was treated with different conditions, the cholesterol removal rate was in the range of 79.4 to 83.3% with 1 % crosslinked $\beta$-CD addition, which were not significantly different among treatments. After cholesterol removal from milk, the used crosslinked $\beta$-CD was washed for cholesterol dissociation and reused. For recycling study, the cholesterol removal rate in first trial was 81.8%, which was mostly same as that using new crosslinked $\beta$-CD. With five trials repeatedly using the same sample, the mean cholesterol removal rate was 81.2%. The present study indicated that the optimum conditions on cholesterol removal using crosslinked $\beta$-CD were 10 min mixing with 400 rpm speed at $5^{\circ}C$ with about 80% cholesterol removal. In addition, crosslinked $\beta$-CD resulted in the effective recycling efficiency almost 100%.

An Application of High-Power Ultrasound to Rubber Recycling

  • Hong, Chang-Kook;Isayev, A.I.
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.103-121
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    • 2003
  • The application of powerful ultrasound to rubber recycling is a very recent field of study. An ultrasonic field creates high frequency extension-contraction stresses by acoustic cavitation. The breakdown of rubber network occurs primarily around pulsating cavities due to the highest level of strain produced by high-power ultrasound. Stronger reductions of cross-link density were observed at a higher pressure, indicating an important role of pressure during ultrasonic recycling. Visible bubbles were observed during ultrasonic treatment as a proof of acoustic cavitation. Shearing effect has a significant influence on improving the efficiency of ultrasonic treatment. After the ultrasonic treatment, the cross-link densities of NR/SBR blends were lower than those of NR and SBR due to the reduced degree of unsaturation and chemical reactions. Carbon black fillers increase the probability of bond scission during ultrasonic treatment, due to the restricted mobility. The mechanical properties of ground tire rubber (GRT)/HDPE blends were improved by ultrasonic treatment and dynamic revulcanization. Ultrasonic treatment of GRT in the presence of HDPE matrix was found to give better mechanical properties due to the chemical reactions between rubber and plastic phases.

A Study on Desulfurization Efficiency of Limestone Sludge with Particle Size (석회석 슬러지의 입도제어에 따른 배연탈황효율에 관한 연구)

  • Seo, Sung Kwan;Chu, Yong Sik;Shim, Kwang Bo
    • Resources Recycling
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    • v.24 no.6
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    • pp.17-23
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    • 2015
  • Flue gas desulfurization(FGD) is the technique to remove $SO_2$ gas from stack gases of coal-fired plants. Many researcher have studied to replace the desulfurizing agent because FGD systems use a lot of limestone and energy. In this study, we use the limestone sludge which is a by-product of steel industry in order to replace desulfurizing agent of FGD system by control the particle size of limestone sludge. And desulfurization performance test is implemented by investigating $SO_2$ gas removal properties upon the characteristic of the limestone sludge with various particle size.

A Study on Simulation of Chip Recycling System for the Management of Cutting Chip in 5-Axis FMS Line (5축 FMS라인의 절삭 칩 처리를 위한 칩 회수처리장치 시뮬레이션에 관한 연구)

  • Lee, In-Su;Kim, Hae-Ji;Kim, Deok-Hyun;Kim, Nam-Kyung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.6
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    • pp.175-181
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    • 2013
  • The primary element of machining automation is to maximize the utilization of machine tools, which determines the output and lead-time. In particular, 95% of raw materials for wing ribs are cut into chips and 0.6 ton of chips are generated every hour from each machine tool. In order to verify the chip recycling system that controls the chips from the machines in five-axis FMS line, a simulation of the virtual model is constructed using the QUEST simulation program. The optimum speed of the chip conveyor and its operating conditions that directly affect the efficiency of the FMS line are presented including the chip conveyor speed, the maximum capacity of the hopper, and the number of chip compressors.

Effect of Oxidation Behavior of (Nd,Dy)-Fe-B Magnet on Heavy Rare Earth Extraction Process

  • Park, Sangmin;Nam, Sun-Woo;Lee, Sang-Hoon;Song, Myung-Suk;Kim, Taek-Soo
    • Journal of Powder Materials
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    • v.28 no.2
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    • pp.91-96
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    • 2021
  • Rare earth magnets with excellent magnetic properties are indispensable in the electric device, wind turbine, and e-mobility industries. The demand for the development of eco-friendly recycling techniques has increased to realize sustainable green technology, and the supply of rare earth resources, which are critical for the production of permanent magnets, are limited. Liquid metal extraction (LME), which is a type of pyrometallurgical recycling, is known to selectively extract the metal forms of rare earth elements. Although several studies have been carried out on the formation of intermetallic compounds and oxides, the effect of oxide formation on the extraction efficiency in the LME process remains unknown. In this study, microstructural and phase analyses are conducted to confirm the oxidation behavior of magnets pulverized by a jaw crusher. The LME process is performed with pulverized scrap, and extraction percentages are calculated to confirm the effect of the oxide phases on the extraction of Dy during the reaction. During the L ME process, Nd is completely extracted after 6 h, while Dy remains as Dy2Fe17 and Dy-oxide. Because the decomposition rate of Dy2Fe17 is faster than the reduction rate of Dy-oxide, the importance of controlling Dy-oxide on Dy extraction is confirmed.

Application and evaluation for effluent water quality prediction using artificial intelligence model (방류수질 예측을 위한 AI 모델 적용 및 평가)

  • Mincheol Kim;Youngho Park;Kwangtae You;Jongrack Kim
    • Journal of Korean Society of Water and Wastewater
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    • v.38 no.1
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    • pp.1-15
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    • 2024
  • Occurrence of process environment changes, such as influent load variances and process condition changes, can reduce treatment efficiency, increasing effluent water quality. In order to prevent exceeding effluent standards, it is necessary to manage effluent water quality based on process operation data including influent and process condition before exceeding occur. Accordingly, the development of the effluent water quality prediction system and the application of technology to wastewater treatment processes are getting attention. Therefore, in this study, through the multi-channel measuring instruments in the bio-reactor and smart multi-item water quality sensors (location in bio-reactor influent/effluent) were installed in The Seonam water recycling center #2 treatment plant series 3, it was collected water quality data centering around COD, T-N. Using the collected data, the artificial intelligence-based effluent quality prediction model was developed, and relative errors were compared with effluent TMS measurement data. Through relative error comparison, the applicability of the artificial intelligence-based effluent water quality prediction model in wastewater treatment process was reviewed.

Characteristics of Copper-catalyzed Cyanide Decomposition by Electrolysis (전해법에 의한 구리함유 시안의 분해특성)

  • Lee Jin-Yeung;Yoon Ho-Sung;Kim Sung-Don;Kim Chul-Joo;Kim Joon-Soo;Han Choon;Oh Jong-Kee
    • Resources Recycling
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    • v.13 no.1
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    • pp.28-38
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    • 2004
  • The characteristics of cyanide decomposition in aqueous phase by electric oxidization have been explored in an effort to develop a process to recycle waste water. Considering current efficiency and voltage, the free cyanide decomposition experiment by electric oxidization indicated that 5 V of voltage and copper catalytic Cu/CN mole ratio 0.05 was the most appropriate condition, where current efficiency was 26%, and decomposition speed was 5.6 mM/min. High voltage and excess copper addition increased decomposition speed a little bit but not current efficiency. The experiment of free cyanide density change proves that high density cyanide is preferred because speed and current efficiency increase with density. Also, the overall decomposition reaction could be represented by the first order with respcect to cyanide with the rate constant of $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ The mass transfer coefficient of electric oxidization of cyanide came out as $2.42${\times}$10^{-5}$ $min^{-1}$ Furthermore, the Damkohler number was calculated as 5.7 in case of 7 V and it was found that the mass transfer stage was the rate determining step.

Effect of Wet Milling on Scum Generation and Solubilization in Batch Ozone Reaction Using Digested Sludge (소화슬러지를 이용한 회분식 오존반응 시 습식분쇄가 스컴 생성과 가용화에 미치는 영향)

  • Hong, Seong-Min;Lee, Dong-Hoon;Kim, Choong-Gon;Shin, Hyun-Gon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.2
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    • pp.13-18
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    • 2019
  • Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

A Study on the Collection and Transportation Processes of Used Oil Containers by Integrated Management System (통합관리 시스템을 이용한 윤활유 페빈용기 회수 ㆍ 처리에 관한 연구)

  • 김청균
    • Tribology and Lubricants
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    • v.19 no.2
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    • pp.94-101
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    • 2003
  • Used motor oil contains pollutants, including organic chemicals and meta]s. When disposed of improperly - in the trash, on the ground or in a sewer system - the pollutants may reach rivers, lakes or the ground water. Thus, all the waste oil products such as waste motor oil, waste oil container, and waste oil filter should be collected and transported for recycling or disposal by waste oil regulations. Because waste oil container is a valuable resource, waste oil containers can be reused, cleaned, buried, and burned for recycling processes. This paper presents the integrated management system that may increase the efficiency and productivity for collecting and reprocessing waste oil containers such as steel can and plastic container. The integrated management system consists of collection and transportation process management system and confirmation and certification process management system for waste oil containers.

Dry Separation of PVC Film from Plastic Film Mixture by Using Air Table

  • Song, Young-Jun;Hiroki Yotsumoto;Lee, Gye-Seung
    • Resources Recycling
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    • v.11 no.1
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    • pp.37-42
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    • 2002
  • This study was conducted in order to remove Poly vinyl chloride(PVC) from the waste plastic film mixture. The fittings of Air Table was modified to increase the separation efficiency of PVC and PE(poly ethylene). PE and PVC was successfully separated from PVC-PE film mixture with the yield of PE 90% or more and with his grade of 99% or more, using the improved Air Table. The details of the separation condition and results will be discussed in this paper. Dry separation, Waste plastic film, PVC, Air Table. The details of the separation condition and results will be discussed in this paper.