• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 봄 학술논문 발표대회
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• pp.305-306
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• 2023

Recently, as the radioactive waste disposal facility becomes scarce, the importance of efficient disposal of waste from nuclear power plants is increasing. This study was conducted to utilize radioactive waste concrete powder as solidifying agent for radioactive waste treatment. Paste with an age of more than one year was used with a disk mill to have a particle size of 150㎛ or less, and treated at temperatures of 500℃, 600℃ and 700℃ for 2 hours. In order to simulate the radioactive cement powder, aqueous solutions of Di-water, CsCl 1M, SrCl₂ 1M and CoCl₂ 1M were used as blending water at W/C 0.7 and to improve fluidity, polycarboxylate type superplasticizer was used at 0.4 wt.% based on the weight of recycled cement paste powder. Characterisation was carried out using vicat method, strength and density.

• 한국건축시공학회지
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• 제8권4호
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• pp.79-85
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• 2008

The purpose of this study is to evaluate the mix design of pH reducing cement concrete which can be used for environment-friendly concrete. Cement pastes and concretes are prepared with water-binder ratios and various admixtures such as blast-furnace slag, fly ash and recycled cement, and tested for compressive strength and pH. pH is measured through pore solution expressed from hydrated cement paste by special apparatus. From the test results, regardless of water-binder ratio, The pH of expressed pore solution from hydrated cement paste which is made of ordinary portland cement with blast-furnace slag, fly ash is decreased with increasing of admixtures content, and compressive strength is also slightly improved. The compressive strength of cement paste made of recycled cement which is burnt at $1000^{\circ}C$, for 2 hours is considerably increased compared with that of none-burnt recycled cement due to restoration of hydraulic property, but pH is a little higher. Porous concrete with ordinary portland cement has high pH in the range of 12.22 to 12.59, however, that is reduced to the range of 8.95 to 10.39 by carbonation at the surface of porous concrete. The pH reduction of porous concrete is possible by various admixture addition, however their degrees are very slight. Therefore, to reduce the pH considerably, carbonation method of porous concrete is better in pH reduction methods for plant survival condition of pH of 9.0 or less. In this study, it is apparent that pH for the environment-friendly porous concrete products used in the construction field can be suppressed by this carbonation method and various admixtures addition.

• 한국건설순환자원학회논문집
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• 제10권3호
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• pp.235-242
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• 2022

CNT 보강 시멘트 페이스트의 침투 임계점은 자기감지 콘크리트의 감지 성능 극대화를 위한 최적 CNT 혼입량과 밀접한 관련이 있다. 하지만 침투임계점은 사용된 시멘트, CNT 그리고 물 시멘트 비에 따라 다양한 값을 가지며, 이를 얻기 위해서는 실험기반의 다수의 시행착오가 불가피하다. 이 연구는 CNT 보강 시멘트 페이스트의 침투 임계점 예측을 위한 침투 시뮬레이션 모델을 제안하였다. 제안된 모델은 CNT 그리고 시멘트 특성을 사용하여 CNT 혼입량에 따른 침투를 시뮬레이션할 수 있으며, 이를 위해 응집된 CNT 입자 수 개념이 사용되었다. 침투 시뮬레이션 과정은 미수화 시멘트 페이스트 모델 형성, CNT 랜덤분산, 그리고 침투 조사의 순서로 구성된다. 시뮬레이션에는 물 시멘트 비가 0.4-0.6인 CNT 보강 시멘트 페이스트가 사용되었으며, 시뮬레이션 된 침투 임계점은 문헌 결과 대비 최대 7.5 %의 시뮬레이션 잔차율로 높은 정확도를 보였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2005년도 춘계 학술기술논문발표대회 논문집
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• pp.61-64
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• 2005

Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement s performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

• 한국건축시공학회지
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• 제6권4호
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• pp.61-68
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• 2006

Recently, there have been many studies about recycling cementitious powder from concrete waste(hereinafter referred to as waste powder), generated after recycle aggregate production. Previous studies showed that when the heating process of waste powder at $700^{\circ}C,\;Ca(OH)_2$ in paste is dehydrated making possible the restoration of hydraulic properties. Recycled cement with hydraulic properties restored is thought to be re-hydrated through the mechanism of hydration, which is almost similar in Portland cement. This clearly suggests that the hydrate of recycled cement is alkali in type. Like in general concrete, if recycled cement is used as a structural material, resistance performance against carbonation or neutralization by $CaCO_3$ in air probably would be most influential to the life of steel-reinforced concrete structure. Thus the purpose of this study is to make an experimental review on chemical properties of recycled cement, manufactured with concrete waste as base material, and investigate the durability of concrete using recycled cement through evaluating the cement's performance of resistance to carbonation in accordance with its accelerating age. Based on its results, further, the study seeks to provide basic information about ways of utilizing recycled cement.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2017년도 춘계학술논문요약집
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• pp.249-250
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• 2017

• 한국건설순환자원학회논문집
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• 제6권1호
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• pp.95-102
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• 2011

순환굵은골재 콘크리트에서 혼합전의 순환굵은골재에 부착되어 있었던 모르타르의 성상변화를 조사하기 위한 방법으로, 시멘트풀 속에 순환굵은골재를 투입하여 경화시킨 다음 순환굵은골재에 부착된 모르타르의 비캇경도와 공극분포를 검토하였다. 이때 순환굵은골재는 모재콘크리트의 압축강도를 3수준(25.5MPa, 41.7MPa, 60.1MPa)으로 변화시켜 제조한 것을 파쇄시킨 다음 표면건조포화상태 및 절대건조상태에서 사용되었다. 실험결과 순환굵은골재에 부착된 모르타르의 비캇경도는 순환굵은골재의 모재콘크리트의 강도가 클수록 크며, 재령이 증가할수록 크게 되는 것으로 나타났다. 또한, 시멘트풀 속에서 부착모르타르의 공극분포는 $100nm{\sim}10{\mu}m$ 크기의 공극이 감소되며, 6nm~100nm 크기의 작은 공극이 증가하는 것으로 나타났다.

• 상하수도학회지
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• 제19권2호
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• pp.125-134
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• 2005

Waste concrete powder was used to remove fluoride ions in highly concentrated fluoride wastewater. 92.6% of fluoride in 100 mg F/L wastewater was removed by 1% dose of the cement paste powder that represents characteristics of waste concrete powder, whereas the removal efficiencies of raw cement and lime were 47.3% and 96.4%, respectively. The cement paste powder was competitive to lime, common fluoride removal agent. Various Ca-bearing hydrates such as portlandite, calcium silicate hydrate, and ettringite in cement paste slurry can remove fluoride by precipitating $CaF_2$ and absorbing $F^-$ ions. In the experiments using both cement paste and lime, 50~67% of lime can be substituted by cement paste to satisfy fluoride effluent limitation of 15 mg/L. Since cement paste has higher acid neutralization capacity than lime, it can be recycled to neutralize more acid and to remove more fluoride. Therefore waste concrete powder can be more economical and viable alternative for lime in fluoride wastewater treatment.

• 한국건축시공학회지
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• 제5권3호
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• pp.109-116
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• 2005

Recently, there have been many studies seeking towards the utilization of cementitious powder from concrete waste as recycled cement. However, most of the studies actually have been researches about the reuse of mortar or paste, not concrete waste. In fact, either mortar or paste is quite different from a real concrete waste in terms of age and mixture. Thus the purpose of this study is to examine basic physical properties of recycled cement, manufactured with cementitious powder from concrete waste, and analyze differences in chemical and hydraulic properties of the cement and its tested model. As a result of the chemical analysis, recycle cement is composed mainly of CaO and $SiO_2$, and that it is even lower in the content of CaO than Portland cement, which is also supported by previous studies. But, Differently from previous studies, calcining temperature of 650 was found an optimal condition under which cementitious powder from concrete waste could restore its hydraulic properties.

• 한국건설순환자원학회논문집
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• 제5권3호
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• pp.78-83
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• 2010

본 연구에서는 SBFC의 기본 성능을 분석하고, 페이스트 및 모르터에서의 공학적 특성을 검토하여, 향후 경제적인 조강콘크리트 개발을 위한 방안으로 활용하고자 하였다. 실험결과 SBFC의 우수한 조기강도 발현 성능을 확인 할 수 있었고, 유동성을 고려했을 때 OPC와 SBFC와의 적정 혼입율을 도출하여 사용하는 것이 바람직 할 것으로 판단된다.