• Title/Summary/Keyword: recovering process

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Recoverty of Lithium Carbonate and Nickel from Cathode Active Material LNO(Li2NiO2) of Precursor Process Byproducts (전구체 공정부산물 LNO(Li2NiO2)계 양극활물질로부터 탄산리튬 및 니켈 회수연구)

  • Pyo, Je-Jung;Wang, Jei-Pil
    • Resources Recycling
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    • v.28 no.4
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    • pp.30-36
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    • 2019
  • In this study, Li powder was recovered from the by-product of LNO ($Li_2NiO_2$) process, which is the positive electrode active material of waste lithium ion battery, through the $CO_2$ thermal reaction process. In the process of recovering Li powder, the $CO_2$ injection amount is 300 cc/min. The $Li_2NiO_2$ award was phase-separated into the $Li_2CO_3$ phase and the NiO phase by holding at $600^{\circ}C$ for 1 min. After this, the collected sample:distilled water = 1:50 weight ratio, and after leaching, the solution was subjected to vacuum filtration to recover $Li_2CO_3$ from the solution, and the NiO powder was recovered. In order to increase the purity of Ni, it was maintained in $H_2$ atmosphere for 3 hours to reduce NiO to Ni. Through the above-mentioned steps, the purity of Li was 2290 ppm and the recovery was 92.74% from the solution, and Ni was finally produced 90.1% purity, 92.6% recovery.

Study for Seperation Process of Copper from the Low-grade Copper Ore by Hydrometallrugical Process (저품위 동광으로부터 습식제련공정에 의한 구리의 분리 공정 연구)

  • Shin, Dong Ju;Joo, Sung-Ho;Lee, Dongseok;Jeon, Ho-Seok;Shin, Shun Myung
    • Resources Recycling
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    • v.30 no.5
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    • pp.57-66
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    • 2021
  • In this study, we attempted to separate and recover Cu from low-grade copper ore by a hydrometallurgical process. The leaching sample obtained after crushing and sieving by 0.355 mm of low-grade copper ore contained 1.5% Cu, 4.7% Fe, 1.0% Mn, and 0.3% Zn. The Cu in the oxide ore was very well leached into sulfuric acid and 97% Cu leaching efficiency was achieved at 80℃ and 3 M sulfuric acid (H2SO4). From the leaching solution, Cu was separated by solvent extraction from Fe, Mn, and Zn using LIX984N. The separation tendency between Cu and other metals was confirmed through the distribution ratio and separation factor. By plotting the McCabe-Thiele Diagram, the optimum condition for recovering Cu is 5 vol.% LIX984N, 2-stage counter-current solvent extraction, and an O/A ratio of 0.5. Using this method, 99% of the Cu was extracted and a CuSO4 solution was finally obtained that contained 1.6 g/L Cu after the stripping process using 2 M H2SO4.

Analysis tool for the diffusion model using GPU: SNUDM-G (GPU를 이용한 확산모형 분석 도구: SNUDM-G)

  • Lee, Dajung;Lee, Hyosun;Koh, Sungryong
    • Korean Journal of Cognitive Science
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    • v.33 no.3
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    • pp.155-168
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    • 2022
  • In this paper, we introduce the SNUDM-G, a diffusion model analysis tool with improved computational speed. Although the diffusion model has been applied to explain various cognitive tasks, its use was limited due to computational difficulties. In particular, SNUDM(Koh et al., 2020), one of the diffusion model analysis tools, has a disadvantage in terms of processing speed because it sequentially generates 20,000 data when approximating the diffusion process. To overcome this limitation, we propose to use graphic processing units(GPU) in the process of approximating the diffusion process with a random walk process. Since 20,000 data can be generated in parallel using the graphic processing units, the estimation speed can be increased compared to generating data through sequential processing. As a result of analyzing the data of Experiment 1 by Ratcliff et al. (2004) and recovering the parameters with SNUDM-G using GPU and SNUDM using CPU, SNUDM-G estimated slightly higher values for certain parameters than SNUDM. However, in term of computational speed, SNUDM-G estimated the parameters much faster than SNUDM. This result shows that a more efficient diffusion model analysis for various cognitive tasks is possible using this tool and further suggests that the processing speed of various cognitive models can be improved by using graphic processing units in the future.

Analysis of Crushing/Classification Process for Recovery of Black Mass from Li-ion Battery and Mathematical Modeling of Mixed Materials (폐배터리 블랙 매스(black mass) 회수를 위한 파쇄/분급 공정 분석 및 2종 혼합물의 수학적 분쇄 모델링)

  • Kwanho Kim;Hoon Lee
    • Resources Recycling
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    • v.31 no.6
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    • pp.81-91
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    • 2022
  • The use of lithium-ion batteries increases significantly with the rapid spread of electronic devices and electric vehicle and thereby an increase in the amount of waste batteries is expected in the near future. Therefore, studies are continuously being conducted to recover various resources of cathode active material (Ni, Co, Mn, Li) from waste battery. In order to recover the cathode active material, black mass is generally recovered from waste battery. The general process of recovering black mass is a waste battery collection - discharge - dismantling - crushing - classification process. This study focus on the crushing/classification process among the processes. Specifically, the particle size distribution of various samples at each crushing/classification step were evaluated, and the particle shape of each particle fraction was analyzed with a microscope and SEM (Scanning Electron Microscopy)-EDS(Energy Dispersive Spectrometer). As a result, among the black mass particle, fine particle less than 74 ㎛ was the mixture of cathode and anode active material which are properly liberated from the current metals. However, coarse particle larger than 100 ㎛ was present in a form in which the current metal and active material were combined. In addition, this study developed a PBM(Population Balance Model) system that can simulate two-species mixture sample with two different crushing properties. Using developed model, the breakage parameters of two species was derived and predictive performance of breakage distribution was verified.

An Analysis of Process-oriented Design in the Invited Entries of International Competition for the Master Plan of the Yongsan Park, Korea (용산공원 설계 국제공모 출품작에 나타난 프로세스적 설계 분석)

  • So, Jin;Sung, Jong-Sang;Pae, Jeong-Hann
    • Journal of the Korean Institute of Landscape Architecture
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    • v.41 no.2
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    • pp.11-26
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    • 2013
  • Designing large parks such as Yongsan Park requires the open-ended process-oriented design approach in complex layers rather than the conventional self-completed master plan method. This study aims to examine the characteristics of process-oriented design in the eight invited entries of "International Competition for the Master Plan of the Yongsan Park, Korea"(2012). For this purpose, it analyzed each entry according to three criteria: objects of process-oriented approach, time factor and its features of phasing plan, and presentation method of the process. This analysis can not only critically review the current level of the process-centered design methodology but also suggest strategic future directions for Yongsan Park. The objects of process-oriented design in the eight works were order of physical space development, restoration process of ecosystem, recovering process of publicity, and economic operation and management. Main considerations in the objects were connections to adjacent urban fabrics, links to regional green and water system, reuse of existing buildings and infrastructures in the site. The temporal criteria of the phasing plan had two aspects. One was planning a certain time and period, and the other was just establishing an order of phases. Most of the presentation method of process was the phasing plan, but some of the entries suggested a scenario plan. The eight works of "International Competition for the Master Plan of Yongsan Park" did not attempt process-oriented designs entirely and completely. Rather, they tried to introduce the phasing plan as part of a process-centered design. Also, they took an eclectic approach between master plan and process-oriented design instead of rejecting the conventional master plan approach.

A Continuous Process for Phosphorus Recovery from Swine Slurry with Forming Struvite (양돈액비에서 Struvite 형성으로 연속적 인의 회수기술)

  • Oh I.H.;Lee J.H.;Choi B.H.;Burns R.T.
    • Journal of Animal Environmental Science
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    • v.12 no.2
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    • pp.95-100
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    • 2006
  • This study was carried out to develop a continuous process for recovering phosphorus in swine slurry. Magnesium chloride ($MgCl_2$) was used in the test as a magnesium source and the pH was regulated by adding NaOH and aerating. The results showed that the recovery rate of soluble phosphorus (SP) has increased with the molar ratios increased. In case of pH regulated with NaOH, the recovery rates of SP with molar ratio of 1:1.5 were over 95% from both farms. The removal of ammonia-nitrogen was at levels of $4{\sim}9%$. With aeration treatment, the SP recovery rate was 66% and the removal rate of ammonia-nitrogen was 15%. The treatment of NaOH to increase pH showed better SP recovery efficiency than the aeation treatment. However, in case of ammonia-nitrogen removal, the treatment of aeration showed better results than the NaOH treatment.

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Recovery of phosphoric acid from the waste acids in semiconductor manufacturing process (반도체 제조공정에서 발생하는 혼산폐액으로부터 고순도 인산 회수)

  • Park, Sung-Kook;Roh, Yu-Mi;Lee, Sang-Gil;Kim, Ju-Yup;Shin, Chang-Hoon;Ahn, Jae-Woo
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2006.05a
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    • pp.90-94
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    • 2006
  • The waste solution discharged from the LCD manufacturing process contains acids like nitric, acetic and phosphoric acid and metal ions such as Al, Mo and other impurities. It is important to removal of impurities to tess than 1ppm in phosphoric acid to reuse as an etchant because the residual impurities even in sub-ppm concentration in semiconductor materials play a major role on the electronic properties. In this study, we have been clearly established that a mixed system of solvent extraction, diffusion dialysis and ion-exchange technique, which made individually the most of characteristics is developed to commercialize in an efficient system for recovering the high-purity phosphoric acid. By applying vacuum evaporation, the yield of the process are almost 99% removal of nitric acid and acetic acid was achieved. And by applying the solvent extraction method with tri-octyl phosphate(TOP) as an extractant, the removal of acetic and nitric acid from the acid mixture was achieved effectively at the ratio O/A=1/3 with four stages and the stripping of nitric acid from organic phase is attained at a ration of O/A=1 with six stages by distilled water. About 97% and 76% removal of Al and Mo were achieved by diffusion dialysis. Essentially complete less than 1ppm removal of Al, Mo by using ion exchange ion resin and purification of the phosphoric acid was obtain.

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Detection of Forest Fire and NBR Mis-classified Pixel Using Multi-temporal Sentinel-2A Images (다시기 Sentinel-2A 영상을 활용한 산불피해 변화탐지 및 NBR 오분류 픽셀 탐지)

  • Youn, Hyoungjin;Jeong, Jongchul
    • Korean Journal of Remote Sensing
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    • v.35 no.6_2
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    • pp.1107-1115
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    • 2019
  • Satellite data play a major role in supporting knowledge about forest fire by delivering rapid information to map areas damaged. This study, we used 7 Sentinel-2A images to detect change area in forests of Sokcho on April 4, 2019. The process of classify forest fire severity used 7 levels from Sentinel-2A dNBR(differenced Normalized Burn Ratio). In the process of classifying forest fire damage areas, the study selected three areas with high regrowth of vegetation level and conducted a detailed spatial analysis of the areas concerned. The results of dNBR analysis, regrowth of coniferous forest was greater than broad-leaf forest, but NDVI showed the lowest level of vegetation. This is the error of dNBR classification of dNBR. The results of dNBR time series, an area of forest fire damage decreased to a large extent between April 20th and May 3rd. This is an example of the regrowth by developing rare-plants and recovering broad-leaf plants vegetation. The results showed that change area was detected through the change detection of danage area by forest category and the classification errors of the coniferous forest were reached through the comparison of NDVI and dNBR. Therefore, the need to improve the precision Korean forest fire damage rating table accompanied by field investigations was suggested during the image classification process through dNBR.

Thermogenesis and Motor Recruitment of the Pectoral Muscle During Shivering in Arousing Bats Murina Leucogaster

  • Choi, In-Ho;Lee, Youn Sun;Oh, Yung Keun;Jung, Noh-Pal;Gwag, Byoung Joo;Shin, Hyung-Cheul
    • Animal cells and systems
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    • v.5 no.1
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    • pp.31-35
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    • 2001
  • Temperate-resident bats exhibit a circadian cycle of torpor and arousal In summer. The physiological role and selective advantage of torpor as an energy saving mechanism have been received much attention by hibernation biologists. However, despite the significance of the recovering euthermic function, the arousal process and mechanism in these animals have been poorly addressed. In this study, we investigated thermogenic and motor activities of a local bat species Murina leucogaster during arousal by simultaneously examining oxygen consumption rate, body temperature ($T_b$) and pectoral electromyography (EMG). We found that Tb of the torpid bats (12-14$^{\circ}C$) was augmented slowly by nonshivering mechanism during the initial awakening phase. The pectoral shivering, gauged by EMG activity, occurred between 17$^{\circ}C$ and 38$^{\circ}C$. Over this Tb range of shivering, heat was produced at a rate of 0.145 kcal $kg^{-1}\;min^{-1}$ to raise 1$^{\circ}C$ $T_b$ per min. Shivering was most intensive at 30-35$^{\circ}C$ where both EMG amplitude and spike frequency were the highest. Activation of the pectoral myofibers seemed to be controlled in a manner that motor units were recruited from smaller to larger sizes, with greater synchronization, as muscle shivering became intensive with increasing $T_b$.

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Separation Behavior of Paclitaxel and Its Semi-synthetic Precursor 10-Deacetylpaclitaxel from Plant Cell Cultures (식물세포배양으로부터 파클리탁셀 및 이의 반합성 전구체 10-디아세틸파클리탁셀의 분리 양상)

  • Lee, Chung-Gi;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.54 no.1
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    • pp.89-93
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    • 2016
  • In this study, we investigated the separation behavior of the anticancer agent paclitaxel and its semi-synthetic precursor 10-deacetylpaclitaxel (10-DAP) from plant cell cultures. As a result of sequential separation/purification performed by biomass extraction with solvent, liquid-liquid extraction, adsorbent treatment, hexane precipitation, and fractional precipitation, the adsorbent treatment was found to be the most effective in separating and recovering 10-DAP from paclitaxel. The optimal adsorbent type, crude extract/adsorbent ratio, and adsorbent treatment temperature were sylopute, 1:1.5 (w/w), and $20^{\circ}C$, respectively. The separation/recovery of 10-DAP from paclitaxel was 74.1% in adsorbent treatment process under optimal conditions.