• 제목/요약/키워드: rearrangement

검색결과 816건 처리시간 0.028초

Preparation of the Polymers Containing Phenylamide and Dimethylaminoethyl Groups and their Properties as a Nagative Photoresist

  • Chae, Kyu-Ho;Kang, Jin-Koo;Kim, Su-Kyung;Chough, Sung-Hyo
    • Journal of Photoscience
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    • 제7권2호
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    • pp.47-52
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    • 2000
  • The copolymmers of N, N-dimethylaminoethyl methacrylate(DAEM) and N-arylmethacrylamide (AMA) were prepared, and their photochemical properties as a negative photoresist were studied by the measurements of insoluble fraction, and by UV and IR absorption spectral changes. These copolymers are soluble in DMF, actone, methanol, of acidic buffer solutions. Solubility of these copolymer films in the vuffer solutions increased with the amount of DAEM units in the copolymer and decreased with the pH value. The insoluble fraction of the copolymer films in the buffer solution of pH 4 of in methanol increased with irradiation time and the amount of AMA units in the copolymer. UV and IR spectral changes indicated that not only photo-crosslinking but also the photo-Fries rearrangement took place upon irradiation with a 254nm UV light.

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Disulfide 가교 견섬유의 Set 성 (Setting Properties of Disulfide-Crosslinked Silk Fiber)

  • 남성우;장병호
    • 한국염색가공학회지
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    • 제1권1호
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    • pp.1-6
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    • 1989
  • The reaction of silk with a disulfide-containing crosslinking agent, i.e. bis($\beta$-isocyanatoethyl)disulfide(BIED), was studied in an attempt to obtain disulfide-crosslinked silk. The setting properties of disulfide-crosslinked silk fibers were studied. The permanent set values of single fibers were evaluated after the set fibers were relaxed in boiling water. When single fibers were set in boiling water or in boiling alkaline solution, the permanent set values of BIED-treated silk fibers were less than those of untreated silk fibers. When the fibers were treated with 2% thioglycolic acid solution at $60^\circ{C}$ followed by oxidation, settability of BIED-treated silk was better than that of untreated silk. The rearrangement of secondary bonds faciliated by cleavage of crosslinks as well as the rearrangement of crosslinks itself seems to be an important role in the set stability.

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오디오 스테가노그래피에 자료를 숨기기 위한 개선된 LSB 기법 (Advanced LSB Technique for Hiding Messages in Audio Steganography)

  • 지선수
    • 한국산업정보학회논문지
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    • 제19권1호
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    • pp.69-75
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    • 2014
  • 오디오 스테가노그래피는 새로운 비밀통신 기술로서 발전한 은닉메시지를 기록하는 과학이며 예술이다. 그리고 오디오 스테가노그래피는 이진화 된 메시지를 이미지의 8번째 LSB 층에 숨기는 과정과 유사하다. 효과적인 스테가노그래픽 기법은 비밀자료를 많이 숨기고, 감지할 수 없게 하는 것이다. 이 논문에서는 외부적 공격으로부터 비밀 메시지를 안전하게 숨기기 위해 재배열 순서키와 수정된 LSB 기법에 의한 방법을 제안한다.

A traffic and interference adaptive DCA algorithm with rearrangement in microcellular systems

  • Kim, Seong-Lyun;Han, Youngnam
    • 한국경영과학회:학술대회논문집
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    • 대한산업공학회/한국경영과학회 1995년도 춘계공동학술대회논문집; 전남대학교; 28-29 Apr. 1995
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    • pp.724-728
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    • 1995
  • A new dynamic channel assignment (DCA) algorithm with rearrangement for cellular mobile communication systems is suggested. Our DCA algorithm is both traffic and interference adaptive, which is based on the mathematical formulation of the maximum packing under a realistic propagation model. In developing the algorithm, we adopt the Lagrangean relaxation technique that has been successfully used in the area of mathematical programming. Computational experiments of the algorithm reveal quite encouraging results. Although our algorithm primarily focuses on microcellular systems, it can be effectively applied to conventional cellular systems under highly nonuniform traffic distributions and interference conditions.

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Object Feature Extraction Using Double Rearrangement of the Corner Region

  • Lee, Ji-Min;An, Young-Eun
    • 통합자연과학논문집
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    • 제12권4호
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    • pp.122-126
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    • 2019
  • In this paper, we propose a simple and efficient retrieval technique using the feature value of the corner region, which is one of the shape information attributes of images. The proposed algorithm extracts the edges and corner points of the image and rearranges the feature values of the corner regions doubly, and then measures the similarity with the image in the database using the correlation of these feature values as the feature vector. The proposed algorithm is confirmed to be more robust to rotation and size change than the conventional image retrieval method using the corner point.

Transition Metal-Catalyzed and -Promoted Reactions via Carbene and Vinylidene Complexes Generated from Alkynes

  • Ohe, Kouichi
    • Bulletin of the Korean Chemical Society
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    • 제28권12호
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    • pp.2153-2161
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    • 2007
  • The transition metal-induced in situ generation of carbene complexes from alkynes having a carbonyl or imino group as a nucleophilic functionality has been investigated. These reactive carbenoid species are generated with high atom efficiency through a 6-endo-dig cyclization mode based on the electrocyclization of vinylidene complexes or a 5-exo-dig cyclization mode in π-alkyne complexes, and have been found to serve as versatile intermediates in catalytic carbene transfer reactions. Highlighted and reviewed in this account are the generation and preparation of pyranylidene, furylcarbene, pyrrolylcarbene, and vinylcarbene complexes and their application to [3,3]sigmatropic rearrangement of acylcyclopropylvinylidenes, catalytic cyclopropanation reactions, [2,3]sigmatropic rearrangement or condensation reactions via ylides, ring-opening and substitution reactions with heteroaromatic compounds, and catalytic isomerization of oligoynes.

A Study of Hydrogen-Induced Metal Atom Rearrangement

  • Noh, Hak;Park, Choong-Nyeon;Flanagan, Ted B.
    • 한국수소및신에너지학회논문집
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    • 제7권1호
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    • pp.111-115
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    • 1996
  • Metal atom rearrangement has been shown to take place under the influence of hydrogen-induced atomic diffusion (HIAD) in initially homogeneous fee palladiumalloys by electron microprobe analysis, optical microscopy, mechanical property tests and hydrogen isotherms. HIAD takes place in palladium alloys at moderate to elevated temperatures leading to phase segregation under conditions where segregation does not normally occur, i.e., in the absence of H over the time scale of the experiments. From these results, it is confirmed that dissolved hydrogen plays a dual role in some of these alloys, i.e. it catalyzes metal atom diffusion. This research demonstrates the potential utility of employing H-induced changes for phase diagram determination of Pd alloys and possibly for other alloy system.

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변조 차수 변경을 통한 하이브리드 자동 재전송 기법 (A Hybrid ARQ Scheme with Changing the Modulation Order)

  • 박범수
    • 한국군사과학기술학회지
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    • 제17권3호
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    • pp.336-341
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    • 2014
  • When using a higher-order modulation scheme, there are variations in bit-reliability depending on the bit position in a modulation symbol. Variations of bit-reliability in the codeword block lower the decoding performance. Also, the decoding performance increases as the sum of the bit-reliabilities in the codeword block increases. This paper presents a novel hybrid automatic repeat request scheme that increases the sum of the reliabilities of the transmitted bits by lowering the modulation order, and decreases the variations of bit-reliability in the codeword block by preferentially retransmitting bits with low reliability. The proposed scheme outperforms the constellation rearrangement scheme. Furthermore, the proposed scheme also provides a good solution in cases where the size of the retransmission block is smaller than the size of the initial transmission block.

Creep Mechanisms of Calcium-Silicate-Hydrate: An Overview of Recent Advances and Challenges

  • Ye, Hailong
    • International Journal of Concrete Structures and Materials
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    • 제9권4호
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    • pp.453-462
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    • 2015
  • A critical review on existing creep theories in calcium-silicate-hydrate (C-S-H) is presented with an emphasis on several fundamental questions (e.g. the roles of water, relative humidity, temperature, atomic ordering of C-S-H). A consensus on the rearrangement of nanostructures of C-S-H as a main consequence of creep, has almost been achieved. However, main disagreement still exists on two basic aspects regarding creep mechanisms: (1) at which site the creep occurs, like at interlayer, intergranular, or regions where C-S-H has a relatively higher solubility; (2) how the structural rearrangement evolutes, like in a manner of interlayer sliding, intra-transfer of water at various scales, recrystallization of gelled-like particles, or dissolution-diffusion-reprecipitation at inter-particle boundary. The further understanding of creep behavior of C-S-H relies heavily on the appropriate characterization of its nanostructure.

비트 재배열을 이용한 가변길이 CAN 메시지 압축 (Variable Length CAN Message Compression Using Bit Rearrangement)

  • 조경주
    • 대한전자공학회논문지SD
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    • 제48권4호
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    • pp.51-56
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    • 2011
  • 본 논문에서는 CAN 버스로드를 줄여 CAN 네트워크 비용을 줄이고 오류 확률을 낮추기 위해서 메시지를 압축하는 방법을 제안한다. 제안하는 비트 재배열 방법은 기존의 메시지 변화량만 전송하는 압축방식과 달리 각 변화량의 하위 비트들로부터 시작하여 전송데이터를 재구성하도록 하여 결과적으로 데이터가 압축되는 방법이다. 차량 CAN 로깅 파일을 이용하여 제안한 방법으로 압축한 결과 전송 데이터량이 기존 압축알고리즘에 비해 26% 더 감소함을 보였다.