• 대한화학회지
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• 제51권4호
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• pp.361-364
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• 2007

Microwave irradiation하에서 황산 실리카를 사용한 케톤에서 아미드의 합성을 관한 one-pot Beckmann자리옮김 반응에 대한 보고이다. 산과 케톤의 몰비율이 1:2인 이 방법의 장점은 간단한 조작과 짧은 반응시간으로 높은 수율을 가진 위치선택적 반응이고, 최근에 사용되었던 방법보다 더 친환경적이다.

• 한국경영과학회지
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• 제33권2호
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• pp.75-86
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• 2008

A remarshalling is one of the operational strategies considered importantly at a port container terminal for the fast ship operations and heighten efficiency of slacking yard. The remarshalling rearranges the containers scattered at a yard block in order to reduce the transfer time and the rehandling time of container handling equipments. This Paper deals with the rearrangement problem, which decides to where containers are transported considering time value of each operations. We propose the mixed integer programming model minimizing the weighted total operation cost. This model is a NP-hard problem. Therefore we develope the heuristic algorithm for rearrangement problem to real world adaption. We compare the heuristic algorithm with the optimum model in terms of the computation times and total cost. For the sensitivity analysis of configuration of storage and cost weight, a variety of scenarios are experimented.

• 한국CDE학회논문집
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• 제16권3호
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• pp.207-215
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• 2011

Due to its large size, a ship is first divided into scores of blocks and then each block is constructed through various shops, such as the assembly shop, the painting shop, and the outfitting shop. However, each block may not be directly moved to the next shop and may be temporarily laid on a block stockyard because the working time in each shop is different. If blocks are laid on the block stockyard without any planning, the rearrangement of the blocks by a transporter are required because the blocks have the different in and out time. In this study, an optimal layout method based on the genetic algorithm was proposed in order to minimize the rearrangement of the blocks in the block stockyard. To evaluate the applicability of the proposed method, it was applied to a simple layout problem of the block stockyard.

• 대한전자공학회논문지TC
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• 제46권5호
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• pp.19-25
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• 2009

본 논문은 물리 계층에서의 HARQ방식에서 사용하는 체이스 결합 기반의 재전송 방법에서 재전송시 신호 성상점 재배치방법에 따른 성능 분석 결과를 제시한다. 성능 분석은 16QAM 변조방식에 국한하여 가산형 백색 가우스 잡음 (AWGN) 환경에서 모의실험을 통해 이루어진다. 터보 부호와 길쌈 부호의 두 가지 채널 부호화 방법에 따른 성능 분석 결과를 제시한다.

• Bulletin of the Korean Chemical Society
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• 제31권9호
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• pp.2479-2482
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• 2010

Using a pinhole-type glass nozzle equipped for a corona-excited supersonic expansion (CESE), precursor 2,6-dichlorotoluene seeded in a large amount of inert carrier gas helium was discharged to produce jet-cooled but electronically excited benzyl-type radicals. The visible vibronic emission spectrum was recorded with a long-path monochromator to observe vibronic bands in the $D_1{\rightarrow}D_0$ electronic transition of benzyl-type radicals. The spectral analysis revealed the generation of not only the 2,6-dichlorobenzyl radical as a typical product, but also the o-chlorobenzyl radical as an unexpected species, which indicates the possible molecular rearrangement in eliminating a chlorine atom from the benzene ring. A possible mechanism is proposed for the formation of the o-chlorobenzyl radical from the precurs or in the gas phase.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.54-58
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• 2013

Licochalcones, derived from the dried roots of Glycyrrhiza inflata, have been reported to show various biological activities including antitumor, antiparasitic, antileishmanial, antioxidative, superoxide scavenging, antibacterial, and PTP1B activity. Licochalcone D has an allyl group on ring A instead of ring B, however, most other natural licochalcones possess the group on ring B. Total synthesis of licochalcone D has not been reported even possessing the strongest anti-inflammatory activity. Therefore, the first total synthesis of licochalcone D has been developed by using water-accelerated [3,3]-sigmatropic rearrangement method.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.585-589
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• 2013

Optically active N-benzyl-2-methyl-2H-benzo[b][1,4]oxazin-3(4H)-ones and N-benzyl-2-methyl-2H-benzo[b][1,4]thiazin-3(4H)-ones with potential synthetic and pharmacological interest were prepared via Smiles rearrangement in conventional as well as microwave irradiation conditions in one-pot from inexpensive (S)-2-chloropropionic acid. Most of the compounds displayed good inhibition against Gram positive bacteria and fungi in the antibiotic test.

• Bulletin of the Korean Chemical Society
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• 제34권2호
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• pp.394-398
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• 2013

An efficient process for the synthesis of N-azaaryl anilines via Smiles rearrangement as a tool. A variety of N-azaaryl anilines were generated by the reaction of substituted phenols, substituted anilines, aminopyridines and chloroacetyl chloride or pyridols, under base condition in good to excellent yields.

• 항공우주기술
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• 제9권1호
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• pp.98-105
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• 2010

고속푸리에변환(Fast Fourier Transform)은 이산푸리에변환(Discrete Fourier Transform)의 주기적으로 반복되는 연산을 생략하여 그 속도를 향상시킨 연산방법이다. Radix-2 FFT는 그 정의에 따라 함수 재귀호출에 의해 구현될 수 있는데 이 방법은 스택복사 과정의 시간소모 때문에 고속동작이 어렵게 된다. 이를 극복하기 위해 신호점을 연산순서에 맞게 미리 재배열하고 배열된 신호점을 나비연산하는 방법으로 고속연산을 구현할 수 있다. 이 논문은 신호점 재배열 방법에 의한 Radix-2 FFT의 고속연산에 착안하여 Radix-3 FFT에 신호점 재배열 방식을 적용해 보고 그 타당성에 관해 고찰하였다.

• Bulletin of the Korean Chemical Society
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• 제19권4호
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• pp.444-449
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• 1998

The kinetics of the formation of triplex $poly(dA){\cdot}[poly(dT)]_2$ from poly(dA)·poly(dT) and poly(dT) is examined by various optical spectroscopic methods, including absorption, circular and linear dichroism (LD) spectroscopy. In the pseudo first order condition, where the poly(dT) concentration is kept lower than that of duplex, the association of the poly(dT) is enhanced by the presence of ethidium; the rate constant is proportional to the amount of ethidium in the mixture. When the concentration of the duplex and the single strand is the same, a spectral change is explained by double exponential curves, indicating that at least two steps are involved, the fast association and slow rearrangement steps. In contrast to the pseudo first order kinetics, the association step in an equimolar condition is not affected by the presence of ethidium. In the rearrangement step, the magnitude of LD decreases with an increase in ethidium concentration, suggesting that the bending of polynucleotide around the intercalation site occurs in the rearrangement step.