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http://dx.doi.org/10.5012/jkcs.2007.51.4.361

One-Pot Efficient Beckmann Rearrangement of Ketones Catalyzed by Silica Sulfuric Acid  

Eshghi, H. (Department of Chemistry, Ferdowsi University of Mashhad)
Hassankhani, A. (Department of Chemistry, Sistan & Baluchestan University)
Publication Information
Journal of the Korean Chemical Society / v.51, no.4, 2007 , pp. 361-364 More about this Journal
Abstract
A one-pot Beckmann rearrangement for the preparation of amides from ketones is described using the silica sulfuric acid under Microwave irradiation. Advantages of this method are regioselectivity with high yields in a simple operation and short reaction time, in which the mole ratio of acid and ketone was 1:2 and it should be greener than the currently used systems.
Keywords
SilIca Sulfuric Acid; Ketones; Amides; Microwave Irradiation; Beckmann Rearrangement;
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