• Resources Recycling
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• v.15 no.1 s.69
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• pp.20-27
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• 2006

PVC is the thermoplastic offering excellent material properties. PVC has been used in wide variety of applications, however, it causes environmental problems when it is discarded because of its high chlorine content. Since dechlorination reaction of PVC is taking place at relatively low temperature compared to the pyrolysis temperature of plastics, study on the dechlorination reaction has been carried out as a pre-treatment process. Twin screw reactor which shows excellent mixing capabilities is employed. Experimental variables are the first and second reactor temperature, PVC content in mixed plastics, viscosity of mixed plastics, feeding rate, rotational speed or the second reactor. Over $90\%$ of dechlorination ratio can be obtained under proper operation conditions. Chlorine gas evolved from reactor is absorbed in water and can be recovered as a hydrochloric acid. Analysis had been done on chlorine flows by taking material balance over realtor.

• Journal of Environmental Science International
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• v.21 no.5
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• pp.597-603
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• 2012

Non-thermal plasma processing using a dielectric barrier discharge (DBD) has been investigated as an alternative method for the degradation of non-biodegradable organic compounds in wastewater. The active species such as OH radical, produced by the electrical discharge may play an important role in degrading organic compound in water. The degradation of N, N-Dimethyl-4-nitrosoaniline (RNO) was investigated as an indicator of the generation of OH radical. The DBD plasma reactor of this study consisted of a plasma reactor, recycling pump, power supply and reservoir. The effect of diameter of external reactor (15 ~ 40 mm), width of ground electrode (2.5 ~ 30 cm), shape (pipe, spring) and material (copper, stainless steel and titanium) of ground electrode, water circulation rate (3.1 ~ 54.8 cm/s), air flow rate (0.5 ~ 3.0 L/min) and ratio of packing material (0 ~ 100 %) were evaluated. The experimental results showed that shape and materials of ground were not influenced the RNO degradation. Optimum diameter of external reactor, water circulation rate and air flow rate for RNO degradation were 30 mm, 25.4 cm/s and 4 L/min, respectively. Ground electrode length to get the maximum RNO degradation was 30 cm, which was same as reactor length. Filling up of glass beads decreased the RNO degradation. Among the experimented parameters, air flow rate was most important parameters which are influenced the decomposition of RNO.

• 한국전기화학회:학술대회논문집
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• 2004.06a
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• pp.103-108
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• 2004

The present paper relates to an apparatus in which all carbonaceous material such as coal, oil, plastics and any substance having carbon atoms as part of its constituents are reformed(gasified) into syngas at temperature above $1,200^{\circ}C$(KR patent No.0391121, and PCT/KR2001/01717 and PCT/KR2004/001020). It comprises a single-stage reforming reactor without catalyst and a syngas burner as shown in Fig.2. syngas is combusted with $O_2$ gas in the syngas bunter to produce $M_2O$ and $CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevate the temperature of reactor above $1,200^{\circ}C$, and reaction products reduce carbonaceous material down to CO and $H_2$ gases. Reactants and heat necessary for the reaction are provided through the syngas burner only, Neither $O_2$ gas nor steam are injected into the reforming reactor. Reformer is made of ceramic inner lining and sst outer casing. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and a portion of the product syngas is recycled into syngas burner. The present reformer as shown in Fig.2 is suitable to gasify carbonaceous wastes without secondary pollutants formed from oxidation. Further, it can be miniaturized to accompany a fuel cell system as shown in Fig.3 The output syngas may be used to drive a fuel cell and a portion of electrical power generated in a fuel cell is used to heat a compact reformer up to $1,200^{\circ}C$ so that gas/liquid fossil fuel can efficiently reformed into syngas. The fuel cell serves as syngas burner in Fig.2. The reformation reaction is sustained through recycling a portion of product syngas into a fuel cell and using a portion of electric power generated to heat the reformer for continuous operation. Such reforming reactor may be miniaturized into a size of PC, then you have a Personal Reformer(PR).

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.12 no.1
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• pp.1-10
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• 2016

The number of nuclear power plants operating in Korea was 24 as of year 2015. Nine units out of 24 units have been operated for a period over 20 years. Kori unit 1 has been in operation for 40 years, and an extended operation for Wolsong unit 1 was decided in 2015. There has been reported some crackings in reactor internals in PWR have been reported in Europe, USA, Japan and Korea, and some of them were replaced with new one. Repair and replacement technologies for the reactor internals have been developing in order to meet the regulatory requirements for long term operation in Korea. The technologies will also be used for the exported nuclear units. It is required to review degradation history of the reactor internals worldwide as a part of the degradation management program development. Schematics of reactor internals designed and supplied by Westinghouse, Framatome and Combustion Engineering are described herein. Materials degradation history of reactor internals of PWR plants in USA, Japan and Europe is surveyed and summarized. Some events from Korean plants are also described. Aging management strategy for the internals is suggested.

• Nuclear Engineering and Technology
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• v.47 no.3
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• pp.253-259
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• 2015

The fast neutron reactor BOR-60 is one of the key experimental facilities worldwide to perform large-scale tests of fuel, absorbing, and structural materials for advanced reactors. The BOR-60 reactor was put into operation in December 1969, and by the end of 2014 it had been operating on power for ~265,000 hours. BOR-60 still demonstrates potential capabilities to extend the lifetime of sodium-cooled fast reactors. The BOR-60 lifetime should have expired at the end of 2014. Over the past few years, a great scope of work has been performed to justify the possibility of extending its lifetime. The work included inspection of the equipment conditions, calculations and experimental research on operating parameters and the conditions of nonremovable components, investigation of the structural material samples after their long-term operation under irradiation, etc. Based on the results of the work performed, the residual lifetime was evaluated and the reactor operator made a decision to extend the lifetime period of the BOR-60 reactor. After considering both a set of documents about the reactor conditions and the positive decision of independent experts, the Regulatory Authority of the Russian Federation extended the BOR-60 operating license up to 2020.

• Nuclear Engineering and Technology
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• v.48 no.6
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• pp.1338-1348
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• 2016

A novel fully passive small modular superheated water reactor (SWR) for underwater deployment is designed to produce 160 MWe with steam at $500^{\circ}C$ to increase the thermodynamic efficiency compared with standard light water reactors. The SWR design is based on a conceptual 400-MWe integral SWR using the internally and externally cooled annular fuel (IXAF). The coolant boils in the external channels throughout the core to approximately the same quality as a conventional boiling water reactor and then the steam, instead of exiting the reactor pressure vessel, turns around and flows downward in the central channel of some IXAF fuel rods within each assembly and then flows upward through the rest of the IXAF pins in the assembly and exits the reactor pressure vessel as superheated steam. In this study, new cladding material to withstand high temperature steam in addition to the fuel mechanical and safety behavior is investigated. The steam temperature was found to depend on the thermal and mechanical characteristics of the fuel. The SWR showed a very different transient behavior compared with a boiling water reactor. The inter-play between the inner and outer channels of the IXAF was mainly beneficial except in the case of sudden reactivity insertion transients where additional control consideration is required.

• Nuclear Engineering and Technology
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• v.51 no.5
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• pp.1355-1364
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• 2019

A recently published nuclear forensics methodology for source discrimination of separated weapons-grade plutonium utilizes intra-element isotope ratios and a maximum likelihood formulation to identify the most likely source reactor-type, fuel burnup and time since irradiation of unknown material. Sensitivity studies performed here on the effects of random measurement error and the uncertainty in intra-element isotope ratio values show that different intra-element isotope ratios have disproportionate contributions to the determination of the reactor parameters. The methodology is robust to individual errors in measured intra-element isotope ratio values and even more so for uniform systematic errors due to competing effects on the predictions from the selected intra-element isotope ratios suite. For a unique sample-model pair, simulation uncertainties of up to 28% are acceptable without impeding successful source-reactor discrimination. However, for a generic sample with multiple plausible sources within the reactor library, uncertainties of 7% or less may be required. The results confirm the critical role of accurate reactor core physics, fuel burnup simulations and experimental measurements in the proposed methodology where increased simulation uncertainty is found to significantly affect the capability to discriminate between the reactors in the library.

• Nuclear Engineering and Technology
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• v.53 no.3
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• pp.741-751
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• 2021

There has been a deep interest in trying to find better-performing fuel clad motivated by the desire to decrease the likelihood of the reactor barrier failure like what happened in Fukushima in recent years. In this study, the effect of move towards accident tolerant fuel (ATF) cladding as the most attracting concept for improving reactor safety is investigated for SMART modular reactor. These reactors have less production cost, short construction time, better safety and higher power density. The SiC and FeCrAl materials are considered as the most potential candidate for ATF cladding, and the results are compared with Zircaloy cladding material from reactor physics point of view. In this paper, the calculations are performed by generating PMAX library by DRAGON lattice physics code to be used for further reactor core analysis by PARCS code. The differential and integral worth of control and safety rods, reactivity coefficient, power and temperature distributions, and boric acid concentration during the cycle are analyzed and compared from the conventional fuel cladding. The rod ejection accident (REA) is also performed to study how the power changed in response to presence of the ATF cladding in the reactor core. The key quantitative finding can be summarized as: 20 ℃ (3%) decrease in average fuel temperature, 33 pcm (3%) increase in integral rod worth and cycle length, 1.26 pcm/℃ (50%) and 1.05 pcm/℃ (16%) increase in reactivity coefficient of fuel and moderator, respectively.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.1116-1123
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• 2024

-In recent years, unmanned underwater vehicles (UUV) have been vigorously developed, and with the continuous deepening of marine exploration, traditional energy can no longer meet the energy supply. Nuclear energy can achieve a huge and sustainable energy supply. The heat pipe reactor has no flow system and related auxiliary systems, and the supporting mechanical moving parts are greatly reduced, the noise is relatively small, and the system is simpler and more reliable. It is more favorable for the control of unmanned systems. The use of heat pipe reactors in unmanned underwater vehicles can meet the needs for highly compact, long-life, unmanned, highly reliable, ultra-quiet power supplies. In this paper, a heat pipe reactor scheme named UPR-S that can be applied to unmanned underwater vehicles is designed. The reactor core can provide 1 MW of thermal power, and it can operate at full power for 5 years. UPR-S has negative reactive feedback, it has inherent safety. The temperature and stress of the reactor are within the limits of the material, and the core safety can still be guaranteed when the two heat pipes are failed.

• Journal of the Korea Safety Management & Science
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• v.16 no.2
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• pp.237-246
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• 2014

Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.