• Title/Summary/Keyword: reactive black

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Effect of Neutral Salts on the Reactive Dyeing of Silk(I) -Effect of Cations- (중성염이 견의 반응염색에 미치는 영향(I) - 양이온의 영향-)

  • 도성국;박찬헌;권지윤
    • Textile Coloration and Finishing
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    • v.12 no.6
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    • pp.372-379
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    • 2000
  • Four kinds of neutral salts with different cations, LiCl, NaCl, KCl, and CsCl, were added to the dye bath to accurately understand the effect of cations on the reactive dyeing of silk with C. I. Reactive Black 5. The cations of salts added lowered the negative surface potential of the silk, improving equilibrium adsorption and the accessibility of the dyestuff to the fiber greatly and speeding up the dyeing rate in the order of $Li^+>Na^+>K^+>Cs^+$. The activation energy$(E_a)$ for the dyeing was in the order of$Li^+>Na^+>K^+>Cs^+$ but the activation free energy$(\Delta{G}^*)$, or the real energy barrier for the reaction, was in the order of $Li^+>Na^+>K^+>Cs^+$ because the degree of the contribution of E$^{a}$ to the activation entropy$(\Delta{S}^*)$ was $Li^+>Na^+>K^+>Cs^+$. It was found from this result that LiCl had the strongest lowering effect on the negative surface potential of silk. The decrease in $\Delta{S}^*$ should be attributed to the loosely bonded activated complex of dyestufffs, cations and fiber molecules at transition state. It was clarified from the Bronsted equation that salts had the ionic strength effect and the specific salt effect on the reactive dyeing.

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Antioxidant effect of garlic and aged black garlic in animal model of type 2 diabetes mellitus

  • Lee, Young-Min;Gweon, Oh-Cheon;Seo, Yeong-Ju;Im, Ji-Eun;Kang, Min-Jung;Kim, Myo-Jeong;Kim, Jung-In
    • Nutrition Research and Practice
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    • v.3 no.2
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    • pp.156-161
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    • 2009
  • Hyperglycemia in the diabetic state increases oxidative stress and antioxidant therapy can be strongly correlated with decreased risks for diabetic complications. The purpose of this study is to determine antioxidant effect of garlic and aged black garlic in animal model of type 2 diabetes. The antioxidant activity of garlic and aged black garlic was measured as the activity in scavenging free radicals by the trolox equivalent antioxidant capacity (TEAC) assay. Three week-old db/db mice were fed AIN-93G diet or diet containing 5% freeze-dried garlic or aged black garlic for 7 weeks after 1 week of adaptation. Hepatic levels of lipid peroxides and activities of antioxidant enzymes were measured. TEAC values of garlic and aged black garlic were $13.3{\pm}0.5$ and $59.2{\pm}0.8{\mu}mol/g$ wet weight, respectively. Consumption of aged black garlic significantly decreased hepatic thiobarbituric acid reactive substances (TBARS) level compared with the garlic group which showed lower TBARS level than control group (p<0.05). Activities of superoxide dismutase (SOD) and glutathione peroxidase (GSH-Px) of garlic and aged black garlic group were significantly elevated compared to the control group. Catalase (CAT) activity of aged black garlic group was increased compared with the control group. These results show that aged black garlic exerts stronger antioxidant activity than garlic in vitro and in vivo, suggesting garlic and aged black garlic, to a greater extent, could be useful in preventing diabetic complications.

Quality Comparison between Korean Native Black Ground Pork and Modern Genotype Ground Pork during Refrigerated Storage (재래종과 개량종 세절 돼지고기의 저장 중 품질 특성 비교)

  • Lee Sung Ki;Ju Myung Kyu;Kim Yong Sun;Kang Sun-Moon;Choi Yeom-Soon
    • Food Science of Animal Resources
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    • v.25 no.1
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    • pp.71-77
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    • 2005
  • This study was carry out to investigate the quality characteristics of Korean native black ground pork compared with modern genotype ground pork during refrigerated storage. Korean native black pig and modern genotype pig were slaughtered at 75 kg and 105 kg of live weight, and for 240 days and 210 days of feeding periods, respectively. The ground lean pork (M. semimembranosus) was stored for 9 days at 4℃. The crude fat and crude protein contents were significantly (p<0.05) higher in Korean native black pork. The pH value after 5 days of storage was significantly (p<0.05) lower in Korean native black pork than in modern genotype pork. WHC of Korean native black pork was significantly (p<0.05) higher than that of modern genotype pork over time. The Korean native black pork maintained black reddish color because it had lower CIE L/sup */ value and higher CIE a/sup */ value than the modern genotype pork. CIE L/sup */, b/sup */, C/sup */ and h/sup O/ values decreased as storage time increased. TBARS (thiobarbituric acid reactive substance), POV (peroxide value) and FOX (ferrous oxidation xylenol orange) tended to increase as storage time increased in all of the groups, in particular, those values increased more rapidly in Korean native black pork. Total saturated fatty acid and stearic acid contents had significantly higher in Korean native black pork (p<0.05).

Analysis Of The Primary Restorative Transmission System To Prevent Self-excitation (자기여자(Self-Excitation) 방지를 고려한 시송전 선로에 관한 연구)

  • Lee, Hung-Jae;Kim, Sang-Seop;Park, Sung-Min;Hwang, Bong-Hwan;Lee, Nam-Ho
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.44-46
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    • 2002
  • Service restoration following a complete or partial collapse starts with reenergize a transmission line from black-start generators. Voltage problems can arise by Ferranti effect as unloaded transmission line is reenergized. This paper presents analytical results on the primary restorative transmission system focused on the voltage problem during the early restoration process. Methodologies to handle load pick-up compensating Ferranti effect. and terminal voltage and reactive capability limitation of black-start generators about self-excitation are presented. An algorithm for static analysis about these methodologies is developed, and EMTDC simulation for verifying the efficiency of the algorithm is performed.

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Development of the Primary Restorative Transmission System Analyser to Restore Massive Blackout (광역정전 복구를 위한 시송전 계통 분석시스템 개발)

  • Lee, Nam-Ho;Song, In-Jun;Kim, Kyeong-Ho;Ghoo, Jin-Boo
    • Proceedings of the KIEE Conference
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    • 2002.11b
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    • pp.161-163
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    • 2002
  • Service restoration following a complete or partial collapse starts with reenergizing a transmission line from black-start generators. Voltage problems can arise from Ferranti effect as unloaded transmission line is reenergized. This Paper presents system analyser to develop for verifying the primary restorative transmission system. The algorithm which has been used in the analyser is to handle load pick-up compensating Ferranti effect. and terminal voltage and reactive capability limitation of black-start generators about self-excitation.

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Methacrylamide graft polymerization on silk fibroin dyed with reactive dyestuffs (반응염색견(反應染色絹)의 Methacrylamide graft 중합(重合))

  • Rhee, In Jeon;Lee, Dong Soo
    • Current Research on Agriculture and Life Sciences
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    • v.12
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    • pp.83-95
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    • 1994
  • Fixation rate of reactive dyes on silk fibroin showed the same tendency to absorption rate. Fixation rate of Yellow 179 and Blue 71 was quite slow and Black 5, Blue 49, Blue 4, Blue 19 and Blue 21 was relatively fast. Weight increase by MAA graft polymerization onto filk fibroin was decreased, on the whole, according to the the increase of dye fixation, but weight increase of silk fibroin dyed with Blue 71 and Blue 21 was much higher than that of silk fibroin. And weight increase of silk fibroin dyed with Yellow 179 was similar to that of silk fibroin and in case of Blue 19, weight increase was about 12%, constantly. Weight increase of silk fibroin dyed with Blue 71 and Blue 21 was higher and the others were lower than of silk fibroin. And weight increase was diminished according as the dyeing temperature rises. The color was a little changed by MAA graft polymerization.

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Development of New Algorithm for the Analysis of Self-Excitation in Primary Restorative Transmission Systems (시송전 계통에서 자기여자 현상의 새로운 해석 알고리즘 개발)

  • Park S.M.;Lee K.S.;Bai J.C.;Hwang B.H.;Song I.J.;Lee N.H.;Lee H.J.
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.54 no.3
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    • pp.117-121
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    • 2005
  • Power system restoration following a massive blackout starts with re-energizing primary transmission lines at first. Some factors such as Ferranti effect, and line charging reactive power should be considered in this stage. Severe overvoltage may be induced by the Ferranti effect at the lines since it would be usually no load condition. And lack of capacitive reactive power will cause the self-excitation. This paper presents a new precise algorithm to analyze the primary restorative transmission system focused on the two major static overvoltage problems during the early restoration process.

Influence of atmospheric pressure plasma on the melanogenesis in melanoma cells

  • Ali, Anser;Lee, SeungHyun;Attri, Pankaj;Choi, Eun Ha
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.161.2-161.2
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    • 2015
  • Melanin is a black pigment, responsible for hair and skin color. In order to find the melanin stimulatory technique which prove useful for a gray and a white hair-preventive agent or tanning agent, we developed atmospheric pressure plasma jet (APPJ) and tested for tyrosinase activity and melanin production in melanoma (B16F10) cells in vitro. We found plasma dose dependent increase in melanin production. To explore the contributing mechanism in melanin synthesis, intracellular reactive oxygen species (ROS) and MAP kinase signaling pathways were studied. Furthermore, the development of plasma technology for melanin synthesis and planning for in-vivo future studies will be discussed.

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A Stable Black-Start Strategy for a Stand-Alone DC Micro-Grid

  • Cha, Jae-Hun;Han, Yoon-Tak;Park, Kyung-Won;Oh, Jin-Hong;Choi, Tae-Seong;Ko, Jae-Hun;MAHIRANE, Philemon;An, Jae-Yun;Kim, Jae-Eon
    • Journal of Electrical Engineering and Technology
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    • v.13 no.1
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    • pp.30-37
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    • 2018
  • Unlike an AC system, a DC system does not cause problems with synchronization, stability, reactive power, system losses, and cost. However, more research is still required for the application of DC Systems. This paper proposes a stable black-start strategy for a stand-alone DC micro-grid, which consists of an energy storage system, photovoltaic generator, wind-turbine generator, diesel generator, and DC loads. The proposed method is very important for avoiding inrush current and transient overvoltage in the power system equipment during restoration after a blackout. PSCAD/EMTDC software was used to simulate, analyze, and verify the method, which was found to be stable and applicable for a stand-alone DC micro-grid.

Black rice extract protected HepG2 cells from oxidative stress-induced cell death via ERK1/2 and Akt activation

  • Yoon, Jaemin;Ham, Hyeonmi;Sung, Jeehye;Kim, Younghwa;Choi, Youngmin;Lee, Jeom-Sig;Jeong, Heon-Sang;Lee, Junsoo;Kim, Daeil
    • Nutrition Research and Practice
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    • v.8 no.2
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    • pp.125-131
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    • 2014
  • BACKGROUND/OBJECTIVES: The objective of this study was to evaluate the protective effect of black rice extract (BRE) on tert-butyl hydroperoxide (TBHP)-induced oxidative injury in HepG2 cells. MATERIALS/METHODS: Methanolic extract from black rice was evaluated for the protective effect on TBHP-induced oxidative injury in HepG2 cells. Several biomarkers that modulate cell survival and death including reactive oxygen species (ROS), caspase-3 activity, and related cellular kinases were determined. RESULTS: TBHP induced cell death and apoptosis by a rapid increase in ROS generation and caspase-3 activity. Moreover, TBHP-induced oxidative stress resulted in a transient ERK1/2 activation and a sustained increase of JNK1/2 activation. While, BRE pretreatment protects the cells against oxidative stress by reducing cell death, caspase-3 activity, and ROS generation and also by preventing ERKs deactivation and the prolonged JNKs activation. Moreover, pretreatment of BRE increased the activation of ERKs and Akt which are pro-survival signal proteins. However, this effect was blunted in the presence of ERKs and Akt inhibitors. CONCLUSIONS: These results suggest that activation of ERKs and Akt pathway might be involved in the cytoprotective effect of BRE against oxidative stress. Our findings provide new insights into the cytoprotective effects and its possible mechanism of black rice against oxidative stress.