• Title/Summary/Keyword: reactive behavior

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Sonochemical Synthesis and Sonocatalysis Performance Behavior of Ag2Se and Ag2Se/TiO2 Nanocomposites

  • Zhu, Lei;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.489-496
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    • 2015
  • In this study, novel $Ag_2Se$ sensitized $TiO_2$ nanocomposites were prepared by facile sonochemical assisted synthesis method. The as-prepared products were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), and N2 adsorption BET analysis. The as-prepared $Ag_2Se/TiO_2$ nanocomposites simultaneously possessed great adsorptivity for organic dyes and efficient charge separation properties. In the decolorization of rhodamine B, a significant enhancement in the reaction rate was observed for the $Ag_2Se/TiO_2$ nanocomposite compared to the cases of using pure P25 or $TiO_2$. The sonocatalysis activity was higher due to the greater formation of reactive radicals, as well as to the increase of the active surface area of the $Ag_2Se/TiO_2$ nanocomposite.

Impact Fracture Behavior of Toughened Epoxy Resin Applied Carbon Fiber Reinforced Composites (Toughened 에폭시 수지를 사용한 탄소 섬유강화 복합재료의 충격파괴 거동)

  • 이정훈;황승철;김민영;김원호;황병선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.111-114
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    • 2003
  • Thermosets are highly cross-linked polymers with a three-dimensional molecular structure. The network structure gives rise to mechanical properties, however, one major drawback of thermosets, which also results from their network structure, is their poor resistance to impact and to crack initiation. In this study, to solve this problem, the reactive thermoplastics such as amine terminated polyetherimide (ATPEI), ATPEI-CTBN-ATPEI(ABA) triblock copolymer, CTBN-ATPEI(AB) diblock copolymer, and carboxyl group modified ATPEI was synthesized, after that blended with epoxy resin, and the carbon fiber reinforced composites were fabricated. The impact load, energy, and delamination were investigated by using drop weight impact test and C-scan test. As a results, the ABA/epoxy blend system showed good impact properties.

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Effects of sputtering conditions on the growth behavior of TiN thin films on SKD 61 steel substrates (스퍼터링 증착변수에 따른 SKD 61강 기판상 TiN 박막의 증착거동 변화)

  • 김상섭;임태홍;박용범
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.314-319
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    • 1998
  • TiN thin films were deposited on SKD 61 steel substrates by reactive sputtering under various deposition conditions, and subsequently their growth characteristics and properties were studied. Deposition rate was proportionally increased with total gas pressure as well as RF input power, while the increase of nitrogen in the reaction gas induced a significant suppression of deposition rate. The resulted films exhibited hillocks on the surface. The TiN film prepared using a typical deposition condition showed a (111) preferred orientation and maintained the stoichiometry of pure TiN.

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Growing Behavior of AlN Thin Film Deposited by Asymmetric Bipolar Pulsed DC Reactive Sputtering (비대칭 펄스 직류 반응성 스퍼터링으로 증착된 AlN 박막의 성장 거동)

  • 김주형;이전국;안진호
    • Journal of the Korean Ceramic Society
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    • v.38 no.1
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    • pp.61-67
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    • 2001
  • 비대칭 펄스 직류 반응성 스퍼터링을 이용하여 상온에서 Si(100) 기판 위에 AlN 박막을 증착하였다. 100 kHz에서 200 kHz까지 펄스 주파수의 변화 및 70%에서 90%까지 duty cycle의 변화에 따른 아크 발생과 AlN 박막의 결정성 그리고 미세 조직을 관찰하였다. Duty cycle에서 양의 펄스 유지 시간이 증가함에 따라 증착 중에 아크 발생 빈도가 현저히 감소하였고 AlN 박막의 입자 크기와 결정상의 c축 배향성이 증가하였다. 반면에 펄스 주파수 변화에 따른 아크 발생은 일정한 경향을 나타내지 않았지만 전반적으로 많은 아크가 발생했다. 아크 발생 빈도가 늘어남에 따라 c축 배향성이 감소하였다. 양의 펄스 유지 시간과 펄스 주파수가 감소함에 따라 박막의 증착 속도는 증가하였으며 440$\AA$/min의 높은 증착 속도를 나타냈다.

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Computational Validation of Supersonic Combustion Phenomena associated with Hypersonic Propulsion (극초음속 추진과 관련된 초음속 연소 현상의 수치적 검증)

  • Choi Jeong-Yeol;Jeung In-Seuck;Yoon Youngbin
    • 한국전산유체공학회:학술대회논문집
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    • 1998.05a
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    • pp.117-122
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    • 1998
  • A numerical study is carried out to investigate the transient process of combustion phenomena associated with hypersonic propulsion devices. Reynolds averaged Navier-Stokes equations for reactive flows are used as governing equations with a detailed chemistry mechanism of hydrogen-air mixture and two-equation SST turbulence modeling. The governing equations are discretized by a high order accurate upwind scheme and solved in a fully coupled manner with a fully implicit time accurate method. At first, oscillating shock-induced combustion is analyzed and the comparison with experimental result gives the validity of present computational modeling. Secondly, the model ram accelerator experiment was simulated and the results show the detailed transient combustion mechanisms. Thirdly, the evolution of oblique detonation wave is simulated and the result shows transient and final steady state behavior at off-stability condition. Finally, shock wave/boundary layer interaction in combustible mixture is studied and the criterion of boundary layer flame and oblique detonation wave is identified.

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An Agent Language for Real-Time Reactive Robotic Behavior Specification (실시간 반응형 로봇 행위 지정을 위한 에이전트 언어)

  • Kwak, Byul-Saim;Byun, Moo-Hong;Lee, Jae-Ho
    • Proceedings of the Korea Information Processing Society Conference
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    • 2005.05a
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    • pp.461-464
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    • 2005
  • 본 논문에서는 실시간 반응형 로봇의 행위를 지정하기에 적합한 에이전트 언어를 소개한다. 기존의 BDI 기반의 에이전트 언어를 기반으로 실시간 반응형 로봇의 행위를 지정하는데 적합하도록 개발한 VivAce 에이전트 구조에 대해서 설명하고 이를 이용한 간단한 시뮬레이션을 수행하였다. 또한 VivAce 가 기존의 BDI 에이전트 언어에 비해서 가지는 새로운 특징인 자바 네이티브 언어 지원, 쓰레드 기반의 계획 실행, 다양한 인터페이스를 소개한다.

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Photolithographic Silicon Patterns with Z-DOL (perfluoropolyether, PFPE) Coating as Tribological Surfaces for Miniaturized Devices

  • Singh, R. Arvind;Pham, Duc-Cuong;Yoon, Eui-Sung
    • KSTLE International Journal
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    • v.9 no.1_2
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    • pp.10-12
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    • 2008
  • Silicon micro-patterns were fabricated on Si (100) wafers using photolithography and DRIE (Deep Reactive Ion Etching) fabrication techniques. The patterned shapes included micro-pillars and micro-channels. After the fabrication of the patterns, the patterned surfaces were chemically modified by coating Z-DOL (perfluoropolyether, PFPE) thin films. The surfaces were then evaluated for their micro-friction behavior in comparison with those of bare Si (100) flat, Z-DOL coated Si (100) flat and uncoated Si patterns. Experimental results showed that the chemically treated (Z-DOL coated) patterned surfaces exhibited the lowest values of coefficient of friction when compared to the rest of the test materials. The results indicate that a combination of both the topographical and chemical modification is very effective in reducing the friction property. Combined surface treatments such as these could be useful for tribological applications in miniaturized devices such as Micro/Nano-Electro-Mechanical-Systems (MEMS/NEMS).

Goal Inference of Behavior-Based Agent Using Bayesian Network (베이지안 네트워크를 이용한 행동기반 에이전트의 목적추론)

  • 김경중;조성배
    • Proceedings of the Korean Information Science Society Conference
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    • 2002.10d
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    • pp.349-351
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    • 2002
  • 베이지안 네트워크는 변수들간의 원인-결과 관계를 확률적으로 모델링하기 위한 도구로서 소프트웨어 사용자의 목적을 추론하기 위해 널리 이용된다. 행동기반 로봇 설계는 반응적(reactive) 행동 모듈을 효과적으로 결합하여 복잡한 행동을 생성하기 위한 접근 방법이다. 행동의 결합은 로봇의 목표, 외부환경, 행동들 사이의 관계를 종합적으로 고려하여 동적으로 이루어진다. 그러나 현재의 결합 모델은 사전에 설계자에 의해 구조가 결정되는 고정적인 형태이기 때문에 환경의 변화에 맞게 목표를 변화시키지 못한다. 본 연구에서는 베이지안 네트워크를 이용하여 현재 상황에 가장 적합한 로봇의 목표를 설정하여 유연한 행동선택을 유도한다. Khepera 이동로봇 시뮬레이터를 이용하여 실험을 수행해 본 결과 베이지안 네트워크를 적용한 모델이 상황에 적합하게 목적을 선택하여 문제를 해결하는 것을 알 수 있었다.

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Effect of nitrogen doping on properties of plasma polymerized poly (ethylene glycol) film

  • Javid, Amjed;Long, Wen;Lee, Joon S.;Kim, Jay B.;Sahu, B.B.;Jin, Su B.;Han, Jeon G.
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.286-288
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    • 2014
  • This study deals with the catalyst free radio frequency plasma assisted polymerization of ethylene glycol using nitrogen as reactive gas to modify the surface chemistry and morphology. The deposited film was characterized through various analysis techniques i.e. surface profilometry, Forier transform infrared spectroscopy, water contact angle and UV-visible spectroscopy to analyze film thickness, chemical structure, surface energy and optical properties respectively. The surface topography was analyzed by Atomic force microscopy. It was observed that the ethylene oxide behaviour and optical transmittance of the film were reduced with the introduction of nitrogen gas due to higher fragmentation of monomer. However the hydrophilic behavior of the film improved due to formation of new water loving functional groups suitable for biomedical applications.

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Fabrication of Aluminum/Aluminum Nitride Composites by Reactive Mechanical Alloying

  • Yu, Seung-Hoon;Shin, Kwang-Seon
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1294-1295
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    • 2006
  • Various reactions and the in-situ formation of new phases can occur during the mechanical alloying process. In the present study, Al powders were strengthened by AlN, using the in-situ processing technique during mechanical alloying. Differential thermal analysis and X-ray diffraction studies were carried out in order to examine the formation behavior of AlN. It was found that the precursors of AlN were formed in the Al powders and transformed to AlN at temperatures above $600^{\circ}C$. The hot extrusion process was utilized to consolidate the composite powders. The microstructure of the extrusions was examined by SEM and TEM. In order to investigate the mechanical properties of the extrusions, compression tests and hardness measurements were carried out. It was found that the mechanical properties and the thermal stability of the Al/AlN composites were significantly greater than those of conventional Al matrix composites.

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