• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.925-928
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• 2012

The accurate expression for the steady-state velocity of an irreversible enzyme-catalyzed reaction obtained by Shin and co-workers (J. Chem. Phys. 2001, 115, 1455) is generalized to allow for the rebinding of the product. The amplitude of the power-law ($t^{-1/2}$) relaxation of the free- and bound-enzyme concentrations to steady-state values is expressed in terms of the steady-state velocity and the intrinsic (chemical) rate constants. This result is conjectured to be exact, even though our expression for the steady-state velocity in terms of microscopic parameters is only approximate.

• 한국연소학회:학술대회논문집
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• 2006.04a
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• pp.49-54
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• 2006

The present study conducted a numerical modeling on the diesel SCR (selective catalytic reduction) system using ammonia as a reductant over vanadium-based catalysts $(V_2O_5-WO_3/TiO_2)$. Transient modeling for ammonia adsorption/desorption on the catalyst surface was firstly carried out, and then the SCR reaction was modeled considering for it. In the current catalytic reaction model, we extended the pure chemical kinetic model based on laboratory-scale powdered-phase catalyst experiments to the chemico-physical one applicable to realistic commercial SCR reactors. To simulate multi-dimensional heat and mass transfer phenomena, the SCR reactor was modeled in two dimensional, axisymmetric domain using porous medium approach. Also, since diesel engines operate in transient mode, the present study employed an unsteady model. In addition, throughout simulations using the developed code, effects of space velocity on the DeNOx performance were investigated.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.21 no.4
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• pp.245-275
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• 2017

The present investigation deals, Dufour and heat source effects on radiative MHD slip flow of a viscous fluid in a parallel porous plate channel in presence of chemical reaction. The non-linear coupled partial differential equations are solved by using two term perturbation technique subject to physically appropriate boundary conditions. The numerical values of the fluid velocity, temperature and concentration are displayed graphically whereas those of shear stress, rate of heat transfer and rate of mass transfer at the plate are presented in tabular form for various values of pertinent flow parameters. By increasing the slip parameter at the cold wall the velocity increases whereas the effect is totally reversed in the case of shear stress at the cold wall. It is observed that the effect of Dufour and heat source parameters decreases the velocity and temperature profiles.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.11
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• pp.1046-1053
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• 2010

The objective of this study was to investigate the pyrolytic reaction characteristics of a mixed fuel of municipal solid wastes and low-grade anthracite. The reaction variables are pyrolysis condition of mixing ratio, reaction temperature, temperature increase rate. As a result, the optimum mixing ratio was 20 wt.% low-grade anthracite in MSW, which maintains for the low heating value over 3,500 kcal/kg on pyrolysis. The most high reaction velocity constant was shown at $700^{\circ}C$. Also, under the all experimental condition, the reaction velocity constant increased linearly as temperature rate increase, but pyrolysis has to be considered electric power cost and yield of char at lower temperature rate.

• Food Engineering Progress
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• v.15 no.2
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• pp.155-161
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• 2011

The aim of this study was to determine the effects of different extrusion conditions on the saccharification characteristics( initial reaction velocity, reaction rate constant, yield) of extruded corn starch. Extruded corn starch-water slurries were mixed with alpha-amylase for the enzymatic saccharification. The saccharification yield of extruded corn starch was high at lower feed moisture content and higher barrel temperature. The solubility of extrudates increased with increase in the SME input which increased with increase in the feed moisture content. Starch hydrolysates having DE 63.8 was obtained after 2 hr reaction. The initial reaction velocity of the extrudate slurry with alpha-amylase was higher with decrease in the feed moisture content. The initial reaction velocity of extruded corn starch was the highest ($2.26{\times}10^{-3}mmol/mL{\cdot}min$) at 25% feed moisture content and $120^{\circ}C$ barrel temperature, 250 rpm screw speed. The pregelatinized starch was $1.83{\times}10^{-3}mmol/mL{\cdot}min$ as a control. Reaction rate constant was a similar trend to initial reaction velocity.

• Korean Journal of Applied Biomechanics
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• v.34 no.1
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• pp.1-8
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• 2024

Objective: The aim of this study was to identify the biomechanical determination factor for improving club head speed during the driver swing in male golf players. Method: Twenty-seven golf players were participated in this study. Eight motion capture cameras (250 Hz) and two force plates (2,000 Hz) were used to collect peak angular velocity and ground reaction force data. It was performed stepwise multiple linear regression analysis and alpha set at .05. Results: The peak plantar flexion angular velocity of the left ankle joint and the peak adduction angular velocity of the right shoulder joint were statistically significant. The peak plantar flexion angular velocity of the left ankle joint and the peak adduction angular velocity of the right shoulder during downswing. Conclusion: It is suggested that applying body conditioning training aimed at improving related body functions to increase maximum plantar flexion angular velocity in the left ankle joint will be effective in improving club head speed.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.3
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• pp.669-673
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• 2011

This study explores the numerical analysis method of fluid dynamics in the reaction section to improve the gas processing efficiency in the hazardous gas removal by atmospheric thermal plasma. This study also intends to contribute in technology advance to improve the processing efficiency and make the process more stable. Numerical analysis of temperature distribution in the reaction section dependent on the change in flow velocity of Ar and plasma temperature change, which are major control variables in the cracking process of HFC-23 using arc plasma, was done. The characteristic of incoming oxygen by temperature suggested that when temperature increased to 1600K, 1700K, 1800K respectively, the range of cracking temperature 1500K increased to 75.0%, 83.3%, 90.2% respectively. The temperature change of Ar by velocity change was widest in the area higher than 1500K when the velocity was 2.5m/s; however, since there was no big difference when the velocity was 2m/s, it is believed that 2 m/s would be most proper.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2321-2326
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• 2018

We evaluated the optimal conditions for fluidization of nickel oxide (NiO) and its reduction into high-purity Ni during hydrogen reduction in a laboratory-scale fluidized bed reactor. A comparative study was performed through structural shape analysis using scanning electron microscopy (SEM); variance in pressure drop, minimum fluidization velocity, terminal velocity, reduction rate, and mass loss were assessed at temperatures ranging from 400 to $600^{\circ}C$ and at 20, 40, and 60 min in reaction time. We estimated the sample weight with most active fluidization to be 200 g based on the bed diameter of the fluidized bed reactor and height of the stocked material. The optimal conditions for NiO hydrogen reduction were found to be height of sample H to the internal fluidized bed reactor diameter D was H/D=1, reaction temperature of $550^{\circ}C$, reaction time of 60 min, superficial gas velocity of 0.011 m/s, and pressure drop of 77 Pa during fluidization. We determined the best operating conditions for the NiO hydrogen reduction process based on these findings.

• Journal of Advanced Marine Engineering and Technology
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• v.30 no.1
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• pp.140-149
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• 2006

Characteristics of a laminar diffusion flame placed near wall in microgravity have been numerically analyzed in a two-dimension. The fuel for the flame is $C_2H_4$. The flame is initiated by imposing a high temperature ignition source. The flow field, temperature field, and flame shape in microgravity diffusion flame are detailed. Especially, effects of surrounding air velocity and fuel injection velocity on the microgravity diffusion flame have been discussed accounting for standoff distance. And, the effect of curvature rate has been also studied. The results showed that velocities in a diffusion flame were overshoot because of volumetric expansion and distribution of temperature showed regularity by free-buoyancy This means that the diffusion flame in microgravity is very stable, while the flame in normal gravity is not regular and unstable due to buoyancy. Standoff distance decreases with increase in surrounding air velocity and with decrease in fuel injection velocity. With increasing curvature rate, the position of reaction rate moves away the wall.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1999.11a
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• pp.171-180
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• 1999

In this study, the burning velocity of LFG and LFG mixing fuels related with flame stabilization have been analyzed numerically using C3 reaction mechanism which consists of 92 species and 621 reaction for using LFG. The results show that the burning velocities of LFG and LFG mixing fuels are obtained as a function of CH$_4$ and LFG percent in stoichiometric conditions. Also, a correlation of the burning velocities LFG and LFG mixing fuels are obtained over a wide range of equivalence ratio. The comparison of burning velocity from correlation with that calculated numerically show good agreements. From these results, the proposed burning velocity correlations for LFG and LFG mixing fuels can be applied for the practice of LFG.