• Title/Summary/Keyword: reaction time

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A STUDY ON THE ADHESIVENESS OF SILICONE AND POLYURETHANE SHEET IN MAXILLOFACIAL PROSTHESES (악안면 보철용 폴리우레탄과 실리콘의 접착도에 관한 실험적 연구)

  • Cho, Sang-Jun;Lim, Ju-Hwan;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.34 no.4
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    • pp.833-849
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    • 1996
  • The material of choice for functional and esthetic reconstruction of maxillofacial defects is silicone. Silicone has appropriate physical properties for maxillofacial prosthesis but it has weak edge strength. Therefore, a proper combination of silicone and polyurethane sheet is recommended to improve this weakness. Various primers are also used to enhance the adhesive strength between silicone and polyurethane sheet. The purpose of this study was to determine the adhesive strength of silicone and polyurethane sheet. Silicone elastomer mixture was made by admixing MDX4-4210 elastomer (40%) and Silastic Medical Adhesive Type A(60%). This silicone elastomer mixture was attached to polyurethane sheet, using one of three different primers(1205, S-2260, or A-304), treated for 1, 2, 4, 6, and 8 hours. These were then polymerized in room temperature, dry-heat oven or microwave oven. Six specimens per each group, a total of 270 specimens were prepared for final test. The differences of T-peel bonding strengths were then determined by a test. The differences of T-peel bonding strengths were then determined by a test method that was recommended by American Society for Testing and Materials C794-80. The results were statistically analyzed using the ANOVA and Mutiple Range Tests(Tukey' HSD). The reults were as follow. 1. Type of primer, primer reaction time, and methods of polymerization showed significant correlation on the T-peel bonding strengths in adhesiveness between silicone and polyurethane sheet. 2. A-304 primer showed statistically higher in T-peel bonding strength than otehr type of primers except for the polymerization in microwave oven with reaction times of 2, 6 hours(p<0.05). 3. No significant differences in T-peel bonding strength were observed among the polymerization methods. 4. The effect of reaction time by the primer type and polymerization method showed statistically significant differences in bonding strength among different reaction times. And in most cases, reaction time of 1 or 2 hours showed higher T-peel bonding strength.

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Estimation of reaction forces at the seabed anchor of the submerged floating tunnel using structural pattern recognition

  • Seongi Min;Kiwon Jeong;Yunwoo Lee;Donghwi Jung;Seungjun Kim
    • Computers and Concrete
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    • v.31 no.5
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    • pp.405-417
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    • 2023
  • The submerged floating tunnel (SFT) is tethered by mooring lines anchored to the seabed, therefore, the structural integrity of the anchor should be sensitively managed. Despite their importance, reaction forces cannot be simply measured by attaching sensors or load cells because of the structural and environmental characteristics of the submerged structure. Therefore, we propose an effective method for estimating the reaction forces at the seabed anchor of a submerged floating tunnel using a structural pattern model. First, a structural pattern model is established to use the correlation between tunnel motion and anchor reactions via a deep learning algorithm. Once the pattern model is established, it is directly used to estimate the reaction forces by inputting the tunnel motion data, which can be directly measured inside the tunnel. Because the sequential characteristics of responses in the time domain should be considered, the long short-term memory (LSTM) algorithm is mainly used to recognize structural behavioral patterns. Using hydrodynamics-based simulations, big data on the structural behavior of the SFT under various waves were generated, and the prepared datasets were used to validate the proposed method. The simulation-based validation results clearly show that the proposed method can precisely estimate time-series reactions using only acceleration data. In addition to real-time structural health monitoring, the proposed method can be useful for forensics when an unexpected accident or failure is related to the seabed anchors of the SFT.

Comparison of Lower Extremity Electromyography and Ground Reaction Force during Gait Termination according to the Performance of the Stop Signal Task (정지신호과제의 수행에 따른 보행정지 시 다리 근전도 및 지면반발력 비교)

  • Koo, Dong-Kyun;Kwon, Jung-Won
    • PNF and Movement
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    • v.20 no.1
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    • pp.135-145
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    • 2022
  • Purpose: The purpose of this study was to investigate the association between cognitive and motor inhibition by comparing muscle activity and ground reaction force during unplanned gait termination according to reaction time measured through the stop-signal task. Methods: Sixteen young adults performed a stop-signal task and an unplanned gait termination separately. The subjects were divided into fast and slow groups based on their stop-signal reaction time (SSRT), as measured by the stop-signal task. Electromyography (EMG) and ground reaction force (GRF) were compared between the groups during unplanned gait termination. The data for gait termination were divided into three phases (Phase 1 to 3). The Mann-Whitney U test was used to compare spatiotemporal gait parameters and EMG and GRF data between groups. Results: The slow group had significantly higher activity of the tibialis anterior in Phase 2 and Phase 3 than the fast group (p <0.05). In Phase 1, the fast group had significantly shorter time to peak amplitude (TPA) of the soleus than the slow group (p <0.05). In Phase 2, the TPA of the tibialis anterior was significantly lower in the fast group than the slow group (p <0.05). In Phase 3, there was no significant difference in the GRF between the two groups (p >0.05). There were no significant difference between the two groups in the spatiotemporal gait parameters (p >0.05). Conclusion: Compared to the slow group, the fast group with cognitive inhibition suppressed muscle activity for unplanned gait termination. The association between SSRT and unplanned gait termination shows that a participant's ability to suppress an incipient finger response is relevant to their ability to construct a corrective gait pattern in a choice-demanding environment.

Photocatalytic-Photooxidation of Halogen Derivatives of Phenols in Aqueous Solution (방향족 탄화수소 할로겐 유도체의 광촉매-광산화)

  • 김삼혁;권규혁;정오진
    • Journal of Environmental Science International
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    • v.8 no.2
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    • pp.233-240
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    • 1999
  • Industrial waste which highly loaded by halogenide phenols was photooxidized by laboratory-scale photooxidation of these organic impurities in the presence of aerotropic and titaniumdioxide as photocatalyst. The disapperance of organic compounds was determined as a function of the irradiation time. Some contaminants such as 2-chlorophenol, 2-bromphenol, 3-bromphenol, 4-bromphenol, 2,4-dibromophenol and 2,6-dibromophenol were photodegraded separately to obtain information on the reaction rates, reactivities, and reaction mechanisms of the photooxidation, and on the stoichiometric correlation between organic reactant and inorganic products concentration in the course of the photocatalytic photoreaction.

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Sintering Behavior of Ultra-fine Hydroxyapatite Powders Synthesized by Hydrothermal Reaction (수열반응으로 합성한 Hydroxyapatite 초미분말의 소결특성)

  • 최재웅;조성원;최상홀
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1265-1270
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    • 1994
  • Ultra-fine hydroxyapatite powder were synthesized by the hydrothermal reaction at 10 atm, 3 hrs of Ca(OH)2 suspension with (NH4)2HPO4 solution, and were characterized sintering behavior. Sintered bodies of hydroxyapatite powders which synthesized by hydrothermal reaction method has less weight loss, less sintering shrinkage and superior mechanical property, and was more dense than sintered bodies of hydroxyapatite powder which synthesized by wet method. Sintered bodies were hydroxyapatite single phase. When soack in Ringer's solution for 2 weeks, hydroxyapatite powders preserved hydroxyapatite and sintered body absorbed trace of Ca2+ ion with soaked time.

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BIFURCATION ANALYSIS OF A SINGLE SPECIES REACTION-DIFFUSION MODEL WITH NONLOCAL DELAY

  • Zhou, Jun
    • Journal of the Korean Mathematical Society
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    • v.57 no.1
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    • pp.249-281
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    • 2020
  • A reaction-diffusion model with spatiotemporal delay modeling the dynamical behavior of a single species is investigated. The parameter regions for the local stability, global stability and instability of the unique positive constant steady state solution are derived. The conditions of the occurrence of Turing (diffusion-driven) instability are obtained. The existence of time-periodic solutions, the existence and nonexistence of nonconstant positive steady state solutions are proved by bifurcation method and energy method. Numerical simulations are presented to verify and illustrate the theoretical results.

Graft Copolymerization of Methyl Methacrylate on to Chloroprene Rubber (Chloroprene 고무에 대한 Methyl Methacrylate의 Graft공중합)

  • Park, Chan-Young;Kim, Byung-Kyu;Park, Tchun-Wook
    • Elastomers and Composites
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    • v.26 no.2
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    • pp.109-114
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    • 1991
  • The graft copolymerization of chloroprene rubber with methyl methacrylate in toluene solution has been carried out varying the concentration of monomer, initiator, CR, reaction time, and reaction temperature, etc.. It is observed that the grafting reaction follows conventional kinetic behavior under the present experimental conditions. Identification of grafting on to chloroprene rubber was obtained through characterization of the graft copolymer by infrared spectrometer.

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CONVERGENCE PROPERTIES OF PREDATOR-PREY SYSTEMS WITH FUNCTIONAL RESPONSE

  • Shim, Seong-A
    • Honam Mathematical Journal
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    • v.30 no.3
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    • pp.411-423
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    • 2008
  • In the field of population dynamics and chemical reaction the possibility or the existence of spatially and temporally nonhomogeneous solutions is a very important problem. For last 50 years or so there have been many results on the pattern formation of chemical reaction systems studying reaction systems with or without diffusions to explain instabilities and nonhomogeneous states arising in biological situations. In this paper we study time-dependent properties of a predator-prey system with functional response and give sufficient conditions that guarantee the existence of stable limit cycles.

Reaction process in electrochromism of tungsten oxide thin films

  • An, Il-Sin;Lee, Chang-Hyo;Lim, Won-Taeg
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.85-91
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    • 1998
  • The electrochromic behaviors of de-magnetron sputtered tungsten oxide thin films were investigated during coloration and bleach cycles using in situ real-time spectroscopic ellipsometry. Effective medium approximation and least-squares regression analyses were employed to investigate the electrochromic process. The optical properties of the tungsten oxide film were analyzed using the oscillator model and the evolution of the process using a reaction-limited model. In these analyses, we found that two different reaction rates were associated with the process. We ascribe this behavior to the microstructure of this films.

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Reaction between CH₃and H₂at Conbustion Temperatures

  • 백현주;신관수;Yang, H.;V. Lissianski;W. C. Gardiner, Jr.
    • Bulletin of the Korean Chemical Society
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    • v.16 no.6
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    • pp.543-546
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    • 1995
  • The reaction between CH3 radicals and H2 was investigated behind incident shock waves at temperatures between 1308 and 1825 K by following the consumption of CH3 using a time resolved UV absorption method at 213.9 nm. The rate coefficient expression 1.10 X 1013 exp(-7370 K/T) cm3mol-1s-1 for the reaction of CH3 with H2 was derived.