• Title/Summary/Keyword: reaction time

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The Chemical Kinetics for the Reaction of O(³P) with Ethylene

  • 임종태;조경용;최창열;박호림;최중길;Simon H. Bauer
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.595-600
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    • 1995
  • The kinetics of the reaction between O(3P) and C2H4 was investigated by measuring time-dependent concentrations of OH resulting from the reaction by using the LIF detection. Oxygen atoms were generated by titrating microwave discharged N2/He with NO to the chemiluminescent end point. The operating pressures in the flow reactor ranged from 5 to 15 torr and the mixtures consisted of He/O(3/P)/C2H4 in the approximate ratios from 100/1/0.1 to 100/1/1. The controlled residence time prior to the detection were estimated to be 0.8-17 ms at the reactor pressure of 7 torr. Experimentally determined profiles both in shape and magnitude were compared with the computed OH density for a specified set of experimental parameters, allowing us to arrive at a complete mechanism for the reaction of O(3P) with ethylene.

Effects of Induction Heating Conditions on Ni-Al Based Intermetallic Compound Coating (Ni-Al계 금속간화합물 코팅에 미치는 고주파유도 가열 조건의 영향)

  • Lee, Han-Young;Kim, Tae-Jun;Cho, Yong-Jae
    • Korean Journal of Metals and Materials
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    • v.48 no.2
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    • pp.141-147
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    • 2010
  • An Ni-Al intermetallic coating has been produced by induction heating on mild steel. The effect of the induction heating conditions on the microstructure of the coating has been investigated. The reaction synthesis of the intermetallic compounds was promoted while increasing the heating rate and the holding time at reaction temperature. Especially, an NiAl phase corresponding to the initial composition of mixed powder was predominantly formed. However, the synthesis at low reaction temperatures occurred by solid state diffusion during the holding time and an Fe-Al reaction layer was formed at the interface with the substrate, regardless of the heating rate. The combustion synthesis of the intermetallic compound occurred at a temperature higher than 1023 K and resulted in an almost single phase NiAl structure.

Relations between the Perception-Rerception Time and the Phantom Phenomena on Signal Light (신호등에서의 팬텀현상과 인지반응시간의 관련성)

  • Kim, Yong-Ju;Han, Jong-Sung;Kim, Hoon
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.2
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    • pp.12-16
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    • 1999
  • Phantom phenomena on the signal light was observed and change of perception-reaction tirre of the observer was rreasured. If phantcm phernrena occurs, signal light perception-reaction time by the drivers is prolonged, the extent of which rmy disturb driving. Length of the percetopn-reaction time is affected by the luminance contrast between the turned-on and turned-off signals. Based on the rreasured results, several methods to prevent phantom phenorrena were suggested.

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A Study on the Preparation of the Fly ash Adhesion-Activated Carbon and on the Removal of Heavy Metals (석탄회부착활성탄의 제조 및 중금속 제거에 관한 연구)

  • 문옥란;신대윤;고춘남
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.1-8
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    • 1999
  • This study was aimed ultimately to develop an adsorption process treating heavy metal wastewater by utilizing activated carbon using flyash. The affecting factors in adsorption process on heavy metal by flyash adhesion-activated carbon are s follows. Factors such as pH, and quality of activated carbon, and reaction time made batch adsorption isotherm described adsorption capacity was made use of the investigation to evaluate adsorptive possibility of heavy metal.As the results of this study, H ion has influence on adsorption of heavy metal if pH is low. As reaction time is transformed, factors such as optimum reaction time is taken into consideration an adsorptive process of heavy metal because an adsorption and a reduction process occur. Adsorption isotherm of adhesion-activated carbon was generally obeyed to Freundlich formular than Langmuir formular and Freundlich constant, l/n were obtained in the range of 0.1~0.5.

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Kinetics of Thermal Dehydration of Ha-dong Kaolin (하동카오린의 열분해속도에 관한 연구)

  • 박희찬;손명모
    • Journal of the Korean Ceramic Society
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    • v.18 no.1
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    • pp.35-40
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    • 1981
  • The kinetics of the dehydration of Ha-dong kaolin was studied isothermally at various temperatures. Dehydration rate was measured by thermogravimetry method in the temperature range of 440~50$0^{\circ}C$ and the particle size range of 170~325mesh. The general equation f($\alpha$)=kt, where $\alpha$ is the fraction reacted in the time and the function f($\alpha$) depends on the reaction mechanism, was applied to this reaction. The function, f($\alpha$) was obtained by application of reduced-time plot and plot of lnln (1-$\alpha$) vs. ln (time), and expressed as (1-$\alpha$) ln (1-$\alpha$)+$\alpha$=kt. The dehydration followed the diffusion-controlled reaction model and gave activation energy of 30Kcal/mole.

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Volume Reduction of Waste Water Sludge using Electrolysis (전기분해를 이용한 하수 슬러지 감량)

  • Lee, Byungheon;Bang, Myunghwan;Kim, Geonha
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.264-270
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    • 2006
  • In this research, volume reduction of activated sludge using electrolysis was studied to find an optimum condition using lab scale experiments. Wasted sludge was treated by electrolysis with controlling current density, chloride concentration, electrode distance, and reaction time. Volume of return sludge was reduced by 9.79% in average while maximum was 16.7%. Sludge volume reduction efficiency was affected by current density and reaction time. It was reversely proportional to the electrode distance. Especially current density was effective on the system performance significantly. Electric conductivity, salinity and COD were increased by electrolysis implying sludge disintegrated and converted to COD in part. An empirical equation for total solid removal efficiency by electrolysis was proposed by multiple linear regression analysis as: $TS_{rem}$(%) = 5.534 ${\times}$ current density (A/l) + 0.178 ${\times}$ reaction time (m) + 2.758.

REACTION-TIME INFLUENCED BY SENSIBILITY BASED ON THE ORIENTAL HUMAN CONSTITUTION x (동양 체질론에 근거한 감성적 기질이 반응시간에 미치는 영향에 관한 연구)

  • 최성운;이영석
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 1999.03a
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    • pp.207-211
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    • 1999
  • Nowadays human sensibility ergonomics is spotlighted as one of trends which we have pursued for improvement of humanity. Human sensibility ergonomics is a technique making human life more convenient by applying it to many kinds of products and design for environment by measuring and estimating human sensibility more qualitatively and quantitatively. The study of human sensibility can be discovered in oriental philosophy based on human being. Therefore there is an close relationship between human sensibility ergonomics and oriental philosophy. In this study, we research the sensibility factors of diagnostics by Sasang constitutional medicine, Five element properties and biorhythm by human sensibility ergonomics, and will apply the result of this study - the analyses of the difference among reaction time by using ANOVA after measuring the reaction time depending on one's individual temperament and condition- to job design.

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Properties of Sol-Gel Materials Containing Colloidal Silica Silane (콜로이드 실리카 실란을 함유한 졸겔반응 코팅제 특성연구)

  • Kang, Dong-Pil;Ahn, Myeong-Sang;Na, Moon-Kyong;Myung, In-Hye;Kang, Young-Taec
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05b
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    • pp.33-36
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    • 2005
  • Colloidal Silica(CS)/silane sol solutions were prepared in variation with synthesizing parameters such as ratio of CS to silane and reaction time. In the case of LHSA CS/tetramethoxysilane(TMOS)/methyltrimethoxysilane(MTMS) CS/silane sol, coating film had stable contact angle with increasing reaction time excepting for 48hours. Also, the LHSA CS/TMOS/MTMS coating film had more enhanced flat surface with increasing the amount of MTMS and increasing reaction time. In the case of thermal stability, thermal dissociation of LHSA CS/MTMS sol did not occur up to $550^{\circ}C$.

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Preparation and Magnetic Properties of Ba-Ferrite Particles Using the Supercritical Water Crystallization Method

  • Nam, Sung-Chan;Kim, Kun-Joong;Park, Sang-Do
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.433-440
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    • 2000
  • Barium ferrite particles were synthesized from Ba(NO$_3$)$_2$, Fe(NO$_3$)$_3$ and KOH mixed solutions using hydrothermal crystallization in supercritical water. The experimental apparatus for production of barium ferrite is a flow-type apparatus. Fine barium ferrite particles were produced because supercritical water causes the metal hydroxides to be rapidly dehydrated before significant growth takes place. The effects of Fe/Ba ratio and reaction time on the formation, particle size, and magnetic properties of barium ferrite were studied. When Fe/Ba ratio were varied from 0.5 to 12, single-phase barium ferrite powder was only produced in the range of 0.5〈Fe/Ba〈2. Also, with elevating reaction time, the BaO.6Fe$_2$O$_3$ particle size grew smaller. Especially, uniform barium hexaferrite particles of size 100-200nm were obtained at 80sec. In this study, therefore, single-phase barium ferrite particles are highly stable and can be produced continuously in a reaction time of less then 2min.

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Safe Speed Limit of Robot Arm During Teaching and Maintenance Work (로보트 교시.정비작업시의 안전속도한계)

  • 김동하;임현교
    • Journal of the Korean Society of Safety
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    • v.8 no.1
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    • pp.64-70
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    • 1993
  • Serious injuries and deaths due to multi-jointed robot occur when a man mispercepts. especially during robot teaching and maintenance work. Since industrial robots often operate with unpredictable motion patterns, establishment of safe speed limit of robot arm is indispensable. An experimental emergency conditions were simulated with a multi-jointed robot. and response characteristics of human operators were measured. The result showed that failure type, robot arm axis. and robot arm speed had significant effects on human reaction time. The reaction time was slightly increased with robot arm speed. though it showed somewhat different pattern owing to failure type. Furthermore the reaction time to the axis which could flex or extend. acting on a workpiece directly. was fastest and its standard deviation was small. The robot arm speed limit securing a‘possible contact zone’based on overrun distance was about 25cm/sec. and in this sense the validity of safe speed limits suggested by many precedent researchers were discussed.

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