• Title/Summary/Keyword: reaction mode

Search Result 485, Processing Time 0.033 seconds

A Study of Size Distribution of Sulfate and Nitrate in Urban Air (都市大氣中 黃酸鹽과 窒酸鹽 關한 硏究)

  • 신상은;김승학;김희강
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.2 no.1
    • /
    • pp.33-39
    • /
    • 1986
  • Particulate matter was collected by Andersen Air Sampler in the Seoul area during February-October, 1985, in order to investigate size distribution of sulfate and nitrate in aerosol, and conversion of sulfur dioxide to sulfate and that of nitrogen dioxide to nitrate. The size distribution of sulfate and nitrate had fine mode. The ratio of fine sulfate to total sulfate in aerosol and that of fine nitrate to total nitrate showed between 54.6% and 86%, and 55.7% and 95%, respectively, which presumably originated from gaseous reaction of sulfur dioxide and nitrogen dioxide in the atmosphere.

  • PDF

The Variation of Fracture Strength and Modes in $ZrO_2/NiTi$ Bond by Changing Reaction Layer ($ZrO_2/NiTi$ 접합부 반응조직에 따른 꺽임강도 및 파괴거동 변화)

  • 김영정
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.10
    • /
    • pp.1197-1201
    • /
    • 1994
  • The fracture strength and fracture modes were studied in 3Y-TZP/NiNi bonding which change their interfacial structure with bonding condition. Average 4-point bending strength of 200 MPa to 400 MPa were achieved. The formation of Ti-oxide phase at the interface critically influenced the bonding strength and fracture mode. The fracture surface of Ti-oxide free interface contained multiphase in some case including ZrO2. From the result it was confirmed that in order to maximize the bonding strength crack deflection from interface to ceramic was required.

  • PDF

Vibration control of a framed structure by an air-pulse actuator

  • Fujimoto, T.;Fengying, Cao;Mori, Y.
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 2001.10a
    • /
    • pp.152.3-152
    • /
    • 2001
  • This paper describes an application of an air-pulse actuator for vibration control of a framed structure. Dynamic characteristics of the prototype actuator that utilizes an air-jet reaction force pulsated by an electromagnetic valve were investigated to use it as a control actuator. Using a control law based on the sliding mode control theory, experiments of the vibration control were carried out. The experimental results verified the validity of the actuator performance.

  • PDF

Attitude Control of a Vehicle under the Disturbances by Sliding Mode Controller with Reaction Jets

  • Son, Sung-Han;Kim, Jinsu;Park, Kang-Bak;Teruo Tsuji;Tsuyoshi Hanamoto
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 2001.10a
    • /
    • pp.166.6-166
    • /
    • 2001
  • An attitude control of an air vehicle based on the variable structure control is proposed. For an air vehicle, minimum weight is required. Thus, it is desired to reduce the input energy. The optimal state portrait curve using time-varying sliding surface is proposed to reduce the control energy. Tracking performance of the closed loop system is guaranteed under the existence of parameter variation and external disturbances.

  • PDF

Design Analysis of Punk Style Leather Jacket

  • Kim, Ji-Seon;Yum, Hae-Jung
    • Proceedings of the Korea Society of Costume Conference
    • /
    • 2003.10a
    • /
    • pp.69-69
    • /
    • 2003
  • In the late 1970s, Punk style that appeared according to the social reaction among labor class youngsters has reappeared till now, and also the emotion and mode are working on fashion greatly. In addition to that, as it pervades to young generation more freely, it's becoming a kind of origin in creative fashion. Especially, Punk style leather jacket has spread to high fashion and settled down as an essential item through popularization of leather jacket.

  • PDF

Nonlinear Control of an Automatic Transmission Using Sliding Mode (슬라이딩모드를 이용한 자동변속기의 비선형제어)

  • 조승호
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.19 no.3
    • /
    • pp.605-614
    • /
    • 1995
  • In the automatic transmission using planetary gear there exists nonlinearities due to the finite difference between gear ratios, which yield torque hole during shift and influence on the ride quality and life of clutch. Based on the reaction carrier and converter turbine speed sliding functions are defined. Nonlinear closed-loop control laws are derived using them. Computer simulation shows that the closed loop design is better than the open loop design and semi-closed loop design.

A Mathematical Model Development for the Nitrification-Denitrification Coupled Process

  • ;;T. Prabhakar Clement
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2003.04a
    • /
    • pp.430-433
    • /
    • 2003
  • Nitrogen pollution in urban and rural groundwater is a common problem and poses a major threat to drinking water supplies based on groundwater. In this work, the kinetics of nitrification-denitrification coupled reactions are modeled and new reaction modules for the RT3D code describing the fate and transport of nitrogen species, dissolved oxygen, dissolved organic carbon, and biomass are developed and tested. The proposed nitrogen transformations and transport model showed very good match with the results of other public codes.

  • PDF

Synthesis, Structure, and Reactivity of the [Fe4S4(SR)4]2- (R = 2-, 3-, and 4-Pyridinemethane) Clusters

  • Kim, Yu-Jin;Han, Jae-Hong
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.1
    • /
    • pp.48-54
    • /
    • 2012
  • The $[Fe_4S_4]^{2+}$ clusters with 2-, 3-, and 4-pyridinemethanethiolate (S2-Pic, S3-Pic, and S4-Pic, respectively) terminal ligands have been synthesized from the ligand substitution reaction of the $(^nBu_4N)_2[Fe_4S_4Cl_4]$ (I) cluster. The new $(^nBu_4N)_2[Fe_4S_4(SR)_4]$ (R = 2-Pic; II, 3-Pic; III, 4-Pic; IV) clusters were characterized by FTIR and UV-Vis spectroscopy. Cluster II was crystallized in the monoclinic space group C2/c with a = 24.530 (5) $\AA$, b = 24.636(4) $\AA$, c = 21.762(4) $\AA$, ${\beta}=103.253(3)^{\circ}$, and Z = 8. The X-ray structure of II showed two unique 2:2 site-differentiated $[Fe_4S_4]^{2+}$ clusters due to the bidentate-mode coordination by 2-pyridinemethanethiolate ligands. Cluster III was crystallized in the same monoclinic space group C2/c with a = 26.0740(18) $\AA$, b = 23.3195(16) $\AA$, c = 22.3720(15) $\AA$, ${\beta}=100.467(2)^{\circ}$, and Z = 8. The 3-pyridinemethanethiolate ligand of III was coordinated to the $[Fe_4S_4]^{2+}$ core as a terminal mode. Cluster IV with 4-pyridinemethanethiolate ligands was found to have a similar structure to the cluster III. Fully reversible $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ redox waves were observed from all three clusters by cyclic voltammetry measurement. The electrochemical potentials for the $[Fe_4S_4]^{2+}/[Fe_4S_4]^+$ transition decreased in the order of II, III and IV, and the reduction potential changes by the ligands were explained based on the structural differences among the complexes. The complex III was reacted with sulfonium salt of $[PhMeSCH_2-p-C_6H_4CN](BF_4)$ in MeCN to test possible radical-involving reaction as a functional model of the [$Fe_4S_4$]-SAM (S-adenosylmethionine) cofactor. However, the isolated reaction products of 3-pyridinemethanethiolate-p-cyanobenzylsulfide and thioanisole suggested that the reaction followed an ionic mechanism and the products formed from the terminal ligand attack to the sulfonium.

Design and Implementation of 150W Portable Fuel Cell Power Pack (150W급 휴대용 연료전지 Power Pack 설계 및 제작)

  • Woo, Dong-Gyun;Joo, Dong-Myoung;Kim, Yun-Sung;Oh, Jae-Gi;Lee, Byoung-Kuk
    • The Transactions of the Korean Institute of Power Electronics
    • /
    • v.17 no.6
    • /
    • pp.553-561
    • /
    • 2012
  • Existing energy sources convert chemical energy into mechanical energy, while fuel cell directly generates electricity through an electrochemical reaction between hydrogen and oxygen. Therefore, it has a lot of strong points such as high efficiency, zero emission, and etc. In addition, with the development of hydrogen preservation technique, some companies have been researching and releasing portable fuel cell power packs for specific applications like military equipment, automobile, and so on. However, there are some drawbacks to the fuel cell, high cost and slow dynamic response. In order to compensate these weak points, auxiliary energy storages could be applied to the fuel cell system. In this paper, the optimum structure for a 150W portable fuel cell power pack with a battery pack is selected considering the specification of the system, and the design process of main parts is described in detail. Here, main objectives are compact size, simple control, high efficiency, and low cost. Then, an automatic mode change algorithm, which converts the operating mode depending on the states of fuel cell stack, battery pack, and load, is introduced. Finally, performance of the designed prototype using the automatic mode change control is verified through experiments.

Finite Element Analysis and Validation for Mode I Interlaminar Fracture Behavior of Woven Fabric Composite for a Train Carbody Using CZM(Cohesive Zone Model) (CZM(Cohesive Zone Model)을 이용한 철도차량용 직물 복합재의 모우드 I 층간파괴의 해석적 연구)

  • Kim, Seung-Chul;Kim, Jung-Seol;Yoon, Hyuk-Jin;Seo, Seung-Il
    • Journal of the Korean Society for Railway
    • /
    • v.12 no.5
    • /
    • pp.719-724
    • /
    • 2009
  • In this study, DCB(double cantilever beam) specimens of woven fabric carbon/epoxy and glass/epoxy were manufactured and mode I fracture toughness of specimen was measured according to ASTM 5528-01. And FE analysis was conducted in the same condition and evaluated the behavior of delamination analytically. Mode I fracture toughness measured by test was $845.7\;J/m^2$ in the case carbon/epoxy and that of glass/epoxy was $1,042\;J/m^2$. FE analysis was conducted using cohesive elements for adhesive layer and applied measured fracture toughness. To verify the result of analysis, the reaction force measured at the end of specimen and that calculated by Timoshenko beam theory were compared. The numerical results show good agreements with the measured one.