• 제목/요약/키워드: rate constant(k)

검색결과 3,148건 처리시간 0.034초

Rheological Properties of Cooked Noodles with Different Starch Content Using Tensile Tests

  • Kim, Su-Kyoung;Lee, Seung-Ju
    • Food Science and Biotechnology
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    • 제18권4호
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    • pp.1013-1018
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    • 2009
  • Several rheological terms were introduced to estimate the properties of cooked noodles with different starch content using tensile tests. Ring-shaped specimens were prepared by connecting both ends of the noodle strip before cooking. Hencky strain and rate, as well as true stress were applied in constant deformation tests. The elastic region on the curves of strain vs. stress was not clearly identified. Strain hardening in the subsequent plastic region was more prominent in low-starch noodles. Elongational viscosities at lower strain rates were used to differentiate noodles with different starch content, representing the dominant effect of protein content in the range of lower strain rates. In stress relaxation tests, the reciprocal of Peleg's constant $K_1$ (initial decay rate) and $K_2$ (asymptotic level) increased and decreased respectively, with an increase in starch content. This indicated that addition of starch contributed to the noodles becoming viscous liquid rather than elastic solid.

인공폐에서의 산소전달 속도를 예측하기 위한 아황산용액의 평가 (Evaluation of Sulfite Solution to Predict Oxygen Transfer Rates in Artificial Lung)

  • 이삼철;김기범;정경락
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1998년도 추계학술대회
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    • pp.237-238
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    • 1998
  • The kinetics of sulfite oxidation must be fast and the concentration of sulfite must be low to emulate oxygen uptake by blood. The kinetics were studied yielding a first order rate constant in sulfile, zero order in oxygen. Limitations of the technique were evaluated using the experimental rate constant and an adaptation of Lightfoot's approximation, while the reaction of hemoglobin is reversible and essentially instantaneous, that for sulfite is irreversible and finite. Thus if the approach to saturations not monotonic or if the mass transfer resistance is significantly lowered, e. g. when blood film thicknesses are thinner than a few hundred microns, deviations may occur.

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방향족 활성 Chloro화합물의 Alkoxy기 치환에 관한 연구 (Stydies on the Substitution of the Activated Aromatic Chloride with Alkoxy Group.)

  • 조윤상;공영식
    • 약학회지
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    • 제19권2호
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    • pp.101-110
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    • 1975
  • p-Chloronitrobenzene(substrate) and p-nitrophenetole (product) were quantitatively analyzed to know the degree of extent of reaction in the process of time. The calibration curve was prepared by the internal satndard method in gaschromatography. 2,6-Dimethyl-naphthalene was used as internal standard. The rate constant(k), the reaction velocity in various concentrations of NaOH altered, and the formation of byproducts(azo-compound and p-nitrophenol) with the amounts of MnO$_{2}$ and NaOH altered, were studied. From the results of these of MnO$_{2}$ and NaOH altered, were studied. From the results of these experiments, this reaction was second order and the rate constant was k=10.3 $\times$ 10$^{-3}$ mole$^{-21$. When p-chloronitrobenaene 1 pt. NaOH 0.56pts. MnO$_{2}$ 0.5pts. and ethanol 25 pts-were reacted about 10 hours, p-nitrophenetole was nearly quantitatively obtained without byproducts.

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자유액적의 증발에 미치는 분위기 속도의 영향 (Effects of environmental flow velocity on the evaporation of free droplets)

  • 정성식;하종률;이중순;이상석
    • 대한기계학회논문집B
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    • 제20권6호
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    • pp.2036-2045
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    • 1996
  • An experimental study has been performed to obtain the effect of relative velocity between droplet and environmental gas on the evaporation of a n-heptane free droplet of 180 $\mu$m in diameter flying in a hot and normal pressure air flow. Measurement of droplet diameter and velocity was conducted in a series of time by an electrically controlled optical system. From the experimental results, an empirical equation associated with the relation between evaporation rate constant and relative velocity was obtained.

Loss of HCN from the Pyrimidine Molecular Ion: A Computational Study

  • Yim, Min Kyoung;Jung, Sun Hwa;Kim, Myung Soo;Choe, Joong Chul
    • Bulletin of the Korean Chemical Society
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    • 제33권12호
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    • pp.4098-4102
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    • 2012
  • The potential energy surface (PES) for the loss of HCN from the pyrimidine molecular ion has been explored using quantum chemical calculations. Possible reaction pathways to form five $C_3H_3N^{+{\bullet}}$ isomers have been obtained with Gaussian 4 model calculations. The rate constant for the HCN loss and the product branching ratio have been calculated using the Rice-Ramsperger-Kassel-Marcus theory on the basis of the obtained PES. The resultant rate constant agrees with the previous experimental result. By a kinetic analysis, it is proposed that the formation of $CH=CHC{\equiv}NH^{+{\bullet}}$ is favored near the dissociation threshold, while the formation of $CH=CHN{\equiv}CH^{+{\bullet}}$ is favored at high energies.

일정진폭하중하의 피로균열전파의 통계적 특성 (A Statistical Analysis of Fatigue Crack Growth under Constant-Amplitude Loads)

  • 정현철;임영규;김선진
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2002년도 춘계학술대회 논문집
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    • pp.104-109
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    • 2002
  • In this paper, a statistical analysis of fatigue crack growth behavior under constant amplitude loads has been carried out. Fatigue crack growth tests were conducted on sixteen pre-cracked compact tension (CT) specimens of the pressure vessel (SPV50) steel in controlled identical load and environmental conditions. The assessment of the statistical distribution of fatigue crack growth experimental data obtained from SPV50 steel was studied and also the correlation of the parameter C and m in the Paris-Erdogan law was discussed. The probability distribution function of fatigue crack growth life seems to follow the 3-parameter Weibull. The fatigue crack growth rate seems to follow the 3-parameter Weibull and the log-normal distribution. The coefficient of variation (COV) of fatigue crack growth life was observed to decrease as the crack grows. A strong negative linear correlation exists between the coefficient C and the exponent m in Paris model. Fatigue crack growth rate data shows a normal distribution for both m and logC.

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반복적인 UV 임프린트 공정에서 수축에 따른 삼각 단면을 가진 패턴의 형상 변화 (Variation of a Triangular Pattern Shape due to Shrinkage in the Repeated UV Imprint Process)

  • 정지윤;최수현;조영태
    • 한국기계가공학회지
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    • 제19권7호
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    • pp.67-73
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    • 2020
  • Shrinkage is inevitable in the curing of resins during the nanoimprint process. The degree of shrinkage that occurs as the resin transforms from a viscous liquid to solid differs depending on the type of resin. However, if the cured material is repeatedly cured using the same material, constant shrinkage can be confirmed. In this study, the pattern of change was observed by repeatedly performing the nanoimprint process using a resin with a constant shrinkage rate. The observed pattern for the change of shape was made using a triangular pyramid-shaped aluminum master mold and a flexible replica mold made from the master. Shrinkage that results from the nanoimprint process occurs linearly in the longitudinal direction of the pattern and can be predicted by simple calculations. The change of the pattern due to shrinkage occurred as expected. If the shrinkage rate remains constant, various patterns can be manufactured with high accuracy by correcting these changes before producing a specific shape. This study confirms that the pattern of the desired angle can be obtained by performing the repeated imprint without having to manufacture a master mold.

정전류/정출력 고속충전 방식에 따른 리튬이온전지의 열화 비교 연구 (Effect of Fast Charging Mode on the Degradation of Lithium-Ion Battery: Constant Current vs. Constant Power)

  • 박선호;오은택;박시영;임지훈;최진혁;이용민
    • KEPCO Journal on Electric Power and Energy
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    • 제6권2호
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    • pp.173-179
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    • 2020
  • 전기자동차의 보급이 확대됨에 따라, 소비자의 고속충전에 요구가 높아지고 있으나 관련 연구는 미흡한 실정이다. 본 연구에서는 LiNi0.5Co0.2Mn0.3O2/Graphite 18650 실린더형 리튬이온전지를 이용하여, 정전류와 정출력 충전방식에 따른 전지 열화현상을 비교한다. 정전류모드의 충전속도를 1C, 2C, 3C, 4C로 설정하고, 각 충전속도에서의 에너지를 기반으로 정출력값을 산정하였다. 따라서, 동일 충전 에너지를 기반하여, 두 충전방식에 따른 전지 열화를 분석한 결과, 3C의 높은 율속에서 정출력 충전방식이 전지의 열화를 늦출 수 있음이 전압곡선, 용량유지율, 직류저항값으로 확인되었다. 그러나, 충전속도를 4C 이상 높이면, 충전방식보다 전지간 편차가 열화 거동을 지배하였다.

Efficient Optimum Design of Reinforced Concrete Structures using the Mixed-Discrete Optimization Method

  • Kim, Jong-Ok
    • 한국농공학회지
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    • 제39권2호
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    • pp.32-43
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    • 1997
  • Abstract A series of permeability tests was performed on the mixtures with specific mixing rates of sand and bentonite using modified rigid-wall permeameter. Sand-bentonite mixtures were permeated by organics, ethanol and TCE. Permeability of bentonite with several mixing rates had a tendency to decrease up to initial one pore volume and permeability was thereafter converged to a constant value. When sand-bentonite mixtures was permeated by water, permeability was decreased at the beginning but it was thereafter converged to a constant. Among several mixing rates, permeability was greatly decreased at 15% of mixing rate. When sand-bentonite mixtures with 15% mixing rate was permeated by ethanol, permeability was about 10 times larger value than permeability of water. Peameability was shown greater values when permeated by TCE (TrichloroEthylene) followed by ethanol. Suitable mixing rate of sand-bentonite for a liner of waste landfills was detected.

Light Modulation-전자상자성공명법을 이용한 절대속도상수의 결정 (The Absolute Rate Measurement by Light Modulation-ESR Technique)

  • 주광열
    • 대한화학회지
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    • 제21권4호
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    • pp.270-275
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    • 1977
  • Modulated light signal과 trimethylsilyl 유리기의 전자상자성 공명 signal과의 phase shift를 측정함으로써 t-butoxy 유리기와 trimethylsilane의 절대 반응속도 상수는 $-50^{\circ}C$에서 $3{\times}10^{-2}M^{-1}{\cdot}sec^{-1}$으로 얻을 수 있었다.

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