• 제목/요약/키워드: rate constant(k)

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Rheological Properties of Cooked Noodles with Different Starch Content Using Tensile Tests

  • Kim, Su-Kyoung;Lee, Seung-Ju
    • Food Science and Biotechnology
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    • v.18 no.4
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    • pp.1013-1018
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    • 2009
  • Several rheological terms were introduced to estimate the properties of cooked noodles with different starch content using tensile tests. Ring-shaped specimens were prepared by connecting both ends of the noodle strip before cooking. Hencky strain and rate, as well as true stress were applied in constant deformation tests. The elastic region on the curves of strain vs. stress was not clearly identified. Strain hardening in the subsequent plastic region was more prominent in low-starch noodles. Elongational viscosities at lower strain rates were used to differentiate noodles with different starch content, representing the dominant effect of protein content in the range of lower strain rates. In stress relaxation tests, the reciprocal of Peleg's constant $K_1$ (initial decay rate) and $K_2$ (asymptotic level) increased and decreased respectively, with an increase in starch content. This indicated that addition of starch contributed to the noodles becoming viscous liquid rather than elastic solid.

Evaluation of Sulfite Solution to Predict Oxygen Transfer Rates in Artificial Lung (인공폐에서의 산소전달 속도를 예측하기 위한 아황산용액의 평가)

  • Lee, S.C.;Kim, K.B.;Jheong, G.R.
    • Proceedings of the KOSOMBE Conference
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    • v.1998 no.11
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    • pp.237-238
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    • 1998
  • The kinetics of sulfite oxidation must be fast and the concentration of sulfite must be low to emulate oxygen uptake by blood. The kinetics were studied yielding a first order rate constant in sulfile, zero order in oxygen. Limitations of the technique were evaluated using the experimental rate constant and an adaptation of Lightfoot's approximation, while the reaction of hemoglobin is reversible and essentially instantaneous, that for sulfite is irreversible and finite. Thus if the approach to saturations not monotonic or if the mass transfer resistance is significantly lowered, e. g. when blood film thicknesses are thinner than a few hundred microns, deviations may occur.

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Stydies on the Substitution of the Activated Aromatic Chloride with Alkoxy Group. (방향족 활성 Chloro화합물의 Alkoxy기 치환에 관한 연구)

  • 조윤상;공영식
    • YAKHAK HOEJI
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    • v.19 no.2
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    • pp.101-110
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    • 1975
  • p-Chloronitrobenzene(substrate) and p-nitrophenetole (product) were quantitatively analyzed to know the degree of extent of reaction in the process of time. The calibration curve was prepared by the internal satndard method in gaschromatography. 2,6-Dimethyl-naphthalene was used as internal standard. The rate constant(k), the reaction velocity in various concentrations of NaOH altered, and the formation of byproducts(azo-compound and p-nitrophenol) with the amounts of MnO$_{2}$ and NaOH altered, were studied. From the results of these of MnO$_{2}$ and NaOH altered, were studied. From the results of these experiments, this reaction was second order and the rate constant was k=10.3 $\times$ 10$^{-3}$ mole$^{-21$. When p-chloronitrobenaene 1 pt. NaOH 0.56pts. MnO$_{2}$ 0.5pts. and ethanol 25 pts-were reacted about 10 hours, p-nitrophenetole was nearly quantitatively obtained without byproducts.

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Effects of environmental flow velocity on the evaporation of free droplets (자유액적의 증발에 미치는 분위기 속도의 영향)

  • Jeong, Seong-Sik;Ha, Jong-Ryul;Lee, Jung-Sun;Lee, Sang-Seok;Kawaguchi, O
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.6
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    • pp.2036-2045
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    • 1996
  • An experimental study has been performed to obtain the effect of relative velocity between droplet and environmental gas on the evaporation of a n-heptane free droplet of 180 $\mu$m in diameter flying in a hot and normal pressure air flow. Measurement of droplet diameter and velocity was conducted in a series of time by an electrically controlled optical system. From the experimental results, an empirical equation associated with the relation between evaporation rate constant and relative velocity was obtained.

Loss of HCN from the Pyrimidine Molecular Ion: A Computational Study

  • Yim, Min Kyoung;Jung, Sun Hwa;Kim, Myung Soo;Choe, Joong Chul
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4098-4102
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    • 2012
  • The potential energy surface (PES) for the loss of HCN from the pyrimidine molecular ion has been explored using quantum chemical calculations. Possible reaction pathways to form five $C_3H_3N^{+{\bullet}}$ isomers have been obtained with Gaussian 4 model calculations. The rate constant for the HCN loss and the product branching ratio have been calculated using the Rice-Ramsperger-Kassel-Marcus theory on the basis of the obtained PES. The resultant rate constant agrees with the previous experimental result. By a kinetic analysis, it is proposed that the formation of $CH=CHC{\equiv}NH^{+{\bullet}}$ is favored near the dissociation threshold, while the formation of $CH=CHN{\equiv}CH^{+{\bullet}}$ is favored at high energies.

A Statistical Analysis of Fatigue Crack Growth under Constant-Amplitude Loads (일정진폭하중하의 피로균열전파의 통계적 특성)

  • Jeong, Hyeon-Cheol;Lim, Young-Kyu;Kim, Seon-Jin
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2002.05a
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    • pp.104-109
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    • 2002
  • In this paper, a statistical analysis of fatigue crack growth behavior under constant amplitude loads has been carried out. Fatigue crack growth tests were conducted on sixteen pre-cracked compact tension (CT) specimens of the pressure vessel (SPV50) steel in controlled identical load and environmental conditions. The assessment of the statistical distribution of fatigue crack growth experimental data obtained from SPV50 steel was studied and also the correlation of the parameter C and m in the Paris-Erdogan law was discussed. The probability distribution function of fatigue crack growth life seems to follow the 3-parameter Weibull. The fatigue crack growth rate seems to follow the 3-parameter Weibull and the log-normal distribution. The coefficient of variation (COV) of fatigue crack growth life was observed to decrease as the crack grows. A strong negative linear correlation exists between the coefficient C and the exponent m in Paris model. Fatigue crack growth rate data shows a normal distribution for both m and logC.

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Variation of a Triangular Pattern Shape due to Shrinkage in the Repeated UV Imprint Process (반복적인 UV 임프린트 공정에서 수축에 따른 삼각 단면을 가진 패턴의 형상 변화)

  • Jeong, Jiyun;Choi, Su Hyun;Cho, Young Tae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.19 no.7
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    • pp.67-73
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    • 2020
  • Shrinkage is inevitable in the curing of resins during the nanoimprint process. The degree of shrinkage that occurs as the resin transforms from a viscous liquid to solid differs depending on the type of resin. However, if the cured material is repeatedly cured using the same material, constant shrinkage can be confirmed. In this study, the pattern of change was observed by repeatedly performing the nanoimprint process using a resin with a constant shrinkage rate. The observed pattern for the change of shape was made using a triangular pyramid-shaped aluminum master mold and a flexible replica mold made from the master. Shrinkage that results from the nanoimprint process occurs linearly in the longitudinal direction of the pattern and can be predicted by simple calculations. The change of the pattern due to shrinkage occurred as expected. If the shrinkage rate remains constant, various patterns can be manufactured with high accuracy by correcting these changes before producing a specific shape. This study confirms that the pattern of the desired angle can be obtained by performing the repeated imprint without having to manufacture a master mold.

Effect of Fast Charging Mode on the Degradation of Lithium-Ion Battery: Constant Current vs. Constant Power (정전류/정출력 고속충전 방식에 따른 리튬이온전지의 열화 비교 연구)

  • Park, Sun Ho;Oh, Euntaek;Park, Siyoung;Lim, Jihun;Choi, Jin Hyeok;Lee, Yong Min
    • KEPCO Journal on Electric Power and Energy
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    • v.6 no.2
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    • pp.173-179
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    • 2020
  • Electric vehicles (EVs) using lithium secondary batteries (LIBs) with excellent power and long-term cycle performance are gaining interest as the successors of internal combustion engine (ICE) vehicles. However, there are few systematic researches for fast charging to satisfy customers' needs. In this study, we compare the degradation of LIB where its composition is LiNi0.5Co0.2Mn0.3/Graphite with the constant current and constant power-charging method. The charging speed was set to 1C, 2C, 3C and 4C in the constant current mode and the value of constant power was calculated based on the energy at each charging speed. Therefore, by analyzing the battery degradation based on the same charging energy but different charging method; CP charging method can slow down the battery degradation at a high rate of 3C through the voltage curve, capacity retention and DC-IR. However, when the charging rate was increased by 4C or more, the deviation between the LIBs dominated the degradation than the charging method.

Efficient Optimum Design of Reinforced Concrete Structures using the Mixed-Discrete Optimization Method

  • Kim, Jong-Ok
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.39 no.2
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    • pp.32-43
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    • 1997
  • Abstract A series of permeability tests was performed on the mixtures with specific mixing rates of sand and bentonite using modified rigid-wall permeameter. Sand-bentonite mixtures were permeated by organics, ethanol and TCE. Permeability of bentonite with several mixing rates had a tendency to decrease up to initial one pore volume and permeability was thereafter converged to a constant value. When sand-bentonite mixtures was permeated by water, permeability was decreased at the beginning but it was thereafter converged to a constant. Among several mixing rates, permeability was greatly decreased at 15% of mixing rate. When sand-bentonite mixtures with 15% mixing rate was permeated by ethanol, permeability was about 10 times larger value than permeability of water. Peameability was shown greater values when permeated by TCE (TrichloroEthylene) followed by ethanol. Suitable mixing rate of sand-bentonite for a liner of waste landfills was detected.

The Absolute Rate Measurement by Light Modulation-ESR Technique (Light Modulation-전자상자성공명법을 이용한 절대속도상수의 결정)

  • Choo Kwang Yul;Gaspar Peter P.
    • Journal of the Korean Chemical Society
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    • v.21 no.4
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    • pp.270-275
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    • 1977
  • A rate constant is deduced for the reaction of tert-butoxy radicals and trimethylsilane from the measurement of the phase shift between the modulated light source and the ESR signal of trimethylsilyl radical. The rate constant was found to $3{\times}10^{-2}M^{-1}{\cdot}sec^{-1}$ at $-50^{\circ}C$.

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