• Journal of Environmental Health Sciences
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• v.35 no.6
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• pp.532-537
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• 2009

The tropospheric ozone production mechanism for the gas phase additive oxidation reaction of hydroxyl radical (OH) with isoprene (2-methyl-1,3-butadiene) has been studied using cavity ring-down spectroscopy (CRDS) at total pressure of 50 Torr and 298 K. The applicability of CRDS was confirmed by monitoring the shorter (~4%) ringdown time in the presence of hydroxyl radical than the ring-down time without the photolysis of hydrogen peroxide. The reaction rate constant, $(9.8{\pm}0.1){\times}10^{-11}molecule^{-1}cm^3s^{-1}$, for the addition of OH to isoprene is in good agreement with previous studies. In the presence of $O_2$ and NO, hydroxyl radical cycling has been monitored and the simulation using the recommended elementary reaction rate constants as the basis to OH cycling curve gives reasonable fit to the data.

• KIEE International Transactions on Electrophysics and Applications
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• v.2C no.6
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• pp.281-286
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• 2002

The temperature accelerated dielectric breakdown strength of on-wafer low-k dielectric polymer films with thicknesses ranging from 94 nm to 1141 nm is investigated by using the current-voltage characteristic measurements with MIS structures. The temperature dependence of dielectric strength is demonstrated to be Arrhenious for all thicknesses. However, the activation energy is found to be strongly thickness dependent. It follows an exponential relationship rather than being a single value, i.e., the activation energy increase significantly as film thickness increases for the thickness below 500 nm, but it is almost constant for the thickness above 500 nm. This relationship suggests that the change of the activation energy corresponding to different film thickness is closely related to the temperature dependence of the electron trapping/detrapping process in polymer thin films, and is determined by both the trapping rate and the detrapping rate. Thinner films need less energy to form a conduction path compared to thicker films. Hence, it leads to smaller activation energy in thinner films, and the activation energy increases with the increase in film thickness. However, a nearly constant value of the activation energy is achieved above a certain range of film thickness, indicating that the trapping rate and detrapping rate is almost equal and eventually the activation energy approaches the value of bulk material.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.1
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• pp.43-47
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• 2001

Plasma polymerized hexamethyldisiloxane thin film was fabricated by employing an inter-electrode capacitively coupled type apparatus under the following conditions : carrier gas flow rate of 11 sccm, reaction pressure of 0.1 torr, discharge frequency of 13.56 MHz and discharge power of 30∼90 W. Polymerization rate of thin film fabricated at the discharge power of 90W is 32.5nm/min. Relative dielectric constant and dielectric loss tangent of thin film shows 3.2∼3.8 and 2.6x10$\^$-3/∼4.51x10$\^$-3/ respectively in the frequency range of 1 kHz∼1 MHz. As the annealing temperature is increased, the relative dielectric constant gradually decreases while the dielectric loss tangent increases. The current density increase gradually with increasing annealing temperature and electric field. The electric conduction of the heaxamethyldisiloxane thin film shows Schottky effect.

• Journal of the Korean Wood Science and Technology
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• v.22 no.1
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• pp.12-19
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• 1994

An electrically heated experimental lumber dry kiln was retrofitted with a computer-based control system to control kiln conditions more precisely and monitor and record several kiln variables. Flat-sawn 2.5cm-thick Pinus densiflora boards were dried in constant temperature process(65$^{\circ}C$ & 50~60 %RH) and continuously rising temperature process, respectively. The average drying rate in continuously rising temperature process was 5.7 %/hr, which was above 3 times faster than that in constant temperature process. But, the average rate of case-hardening and moisture difference between shells and cores of boards dried in continuously rising temperature process were 82 % and 5.5 %, respectively, which were much larger than those of boards dried in constant temperature process.

• Journal of the Korean Data and Information Science Society
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• v.23 no.3
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• pp.579-585
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• 2012

Many different semi-supervised learning algorithms have been proposed for use wit unlabeled data. However, most of them focus on classification problems. In this paper we propose a semi-supervised regression algorithm called the semi-supervised local constant estimator (SSLCE), based on the local constant estimator (LCE), and reveal the asymptotic properties of SSLCE. We also show that the SSLCE has a faster convergence rate than that of the LCE when a well chosen weighting factor is employed. Our experiment with synthetic data shows that the SSLCE can improve performance with unlabeled data, and we recommend its use with the proper size of unlabeled data.

• Journal of the Korean Ceramic Society
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• v.42 no.1
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• pp.33-36
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• 2005

Effect of heating rate was studied on consolidation of the low-temperature-sinterable PMN-PT-BT powder by varying the heating rate from 5, 10, to $20^{circ}C/min$. Slow rate of $5^{circ}C/min$ showed more homogeneous microstructure than high rate of 10 or $20^{circ}C/min$ due to low PbO (m.p. $886^{circ}C$) evaporation at 850^{circ}C$. It showed sintered density of $7.93 g/cm^{3}$, room temperature dielectric constant of 15300, and dissipation factor of $0.92\%$.

• Computers and Concrete
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• v.26 no.3
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• pp.227-237
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• 2020

Strain rate investigations are needed to calibrate strain-rate-dependent material models and numerical codes. An appropriate material model, which considers the rate effects, need to be used for proper numerical modeling. The plastic concrete cut-off wall is a special underground structure that acts as a barrier to stop or reduce the groundwater flow. These structures might be subjected to different dynamic loads, especially earthquake. Deformability of a structure subjected to dynamic loads is a principal issue which need to be undertaken during the design phase of these structures. The characterization of plastic concrete behavior under different strain rates is essential for proper designing of cut-off walls subjected to dynamic loads. The Cowper-Symonds model, as one of the most commonly applied material models, complies well with the behavior of a plastic concretes in low to moderate strain rates and will be useful in explicit dynamics simulations. This paper aims to present the results of an experimental study on mechanical responses of one of the most useful types of plastic concrete and Cowper-Symonds constant determination procedures in a wide range of strain rate from 0.0005 to 107 (1/s). For this purpose, SHPB, uniaxial, and triaxial compression tests were done on plastic concrete samples. Based on the results of quasi-static and dynamic tests, the dynamic increase factors (DIF) of this material in different strain rates and stress state conditions were determined for calibration of the Cowper - Symonds material models.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.15 no.3
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• pp.179-184
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• 1982

The behavior of continuous flow culture of Lartobacillus bulgricus was investigated by application of Monod's kinetic model. The parameters obtained from Monod's chemostat theory successfully predicted the behavior of the chemostat. Then, it was found that Monod's kinetics were applicable to the growth rate dependence on glucose concentration. Under steady-state condition, the maximum growth rate, saturation constant, and wash out were found to be 0.62/hr, 7.69 g/1, 0.51/hr of continuous culture. And the optimum condition for the highest cell production was 0.41/hr in dilution rate, and at that point the cell production rate was 0.178g/1 hr.

• Geomechanics and Engineering
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• v.5 no.1
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• pp.57-70
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• 2013

Constant rate of strain (CRS) consolidation tests were conducted for undisturbed Ariake clay samples from three boreholes in Saga Plain of Kyushu Island, Japan. The coefficients of consolidation ($c_{\nu}$) were interpreted from the CRS test results by small- and large-strain theory. Large-strain theory was found to interpret smaller $c_{\nu}$ values and less strain rate effect on $c_{\nu}$ than that by small-strain theory. Comparing the theoretical strain distributions within a soil specimen to those obtained by numerical simulation shows that the small-strain theory can be used only for the dimensionless parameter $c_{\nu}/\dot{\varepsilon}H_0^2{\geq}50$ (where $\dot{\varepsilon}$ is strain rate and $H_0$ is the specimen height), and the large-strain theory can be used for a larger range of strain rates. Applying the criterion to undisturbed Ariake clay with a $c_{\nu}$ value of about $1{\times}10^{-7}\;m^2/s$, it is suggested that the large-strain theory should be adopted for calculating the $c_{\nu}$ value when $\dot{\varepsilon}$ > 0.03%/min.

• Journal of Environmental Science International
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• v.19 no.5
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• pp.565-575
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• 2010

This study is mainly focused on micellar effect of cetylpyridinium chloride(CPyCl) solution including alkylbenzimidazole(R-BI) on dephosphorylation of diphenyl-4-nitrophenylphosphinate(DPNPIN) in carbonate buffer(pH 10.7). The reactions of DPNPIN with R-BI$^{\ominus}$ are strongly catalyzed by the micelles of CPyCl. Dephosphorylation of DPNPIN is accelerated by BI$^{\ominus}$ ion in $10^{-2}M$ carbonate buffer(pH 10.7) of $4{\times}10^{-3}M$ CPyCl solution up to 100 times as compared with the reaction in carbonate buffer by no BI solution of $4{\times}10^{-3}M$ CPyCl. The value of pseudo first order rate constant($k^m_{BI}$) of the reaction in CPyCl solution reached a maximum rate constant increasing micelle concentration. Such rate maxima are typical of micellar catalyzed bimolecular reactions. The reaction mediated by R-BI$^{\ominus}$ in micellar solutions are obviously slower than those by BI$^{\ominus}$, and the reaction rate were decreased with increase of lengths of alkyl groups. It seems due to steric effect of alkyl groups of R-BI$^{\ominus}$ in Stern layer of micellar solution. The surfactant reagent, cetylpyridinium chloride(CPyCl), strongly catalyzes the reaction of diphenyl-4-nitrophenylphosphinate(DPNPIN) with alkylbenzimidazole (R-BI) and its anion(R-BI$^{\ominus}$) in carbonate buffer(pH 10.7). For example, $4{\times}10^{-3}M$ CPyCl in $1{\times}10^{-4}M$ BI solution increase the rate constant ($k_{\Psi}=1.0{\times}10^{-2}sec^{-1}$) of the dephosphorylation by a factor ca.14, when compared with reaction ($k_{\Psi}=7.3{\times}10^{-4}sec^{-1}$) in $1{\times}10^{-4}M$ BI solution(without CPyCl). And no CPyCl solution, in $1{\times}10^{-4}M$ BI solution increase the rate constant ($k_{\Psi}=7.3{\times}10^{-4}sec^{-1}$) of the dephosphorylation by a factor ca.36, when compared with reaction ($k_{\Psi}=2.0{\times}10^{-5}sec^{-1}$) in water solution(without BI). This predicts that the reactivities of R-BI$^{\ominus}$ in the micellar pseudophase are much smaller than that of BI$^{\ominus}$. Due to the hydrophobicity and steric effect of alkyl group substituents, these groups would penetrate into the core of the micelle for stabilization by van der Waals interaction with long alkyl groups of CPyCl.