• Title/Summary/Keyword: rate constant(k)

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Optimal Pumping Rate of a Water Well at Imgokri, Sangju City (상주시 임곡리 굴착공의 적정양수량 결정)

  • Cho, Byong-Wook;Yun, Uk;Moon, Sang-Ho;Lee, Byeong-Dae;Cho, Soo-Young;Kim, YongCheol;Hwang, Seho;Shin, Jehyun;Ha, Kyoochul
    • The Journal of Engineering Geology
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    • v.27 no.3
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    • pp.255-265
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    • 2017
  • We have determined the optimal pumping rate of the PW-2 water well (depth=100 m) at Imgokri, Sangju City. Cutting analysis and geophysical logging data reveal water-producing horizons at 26.1-26.5, 28.0-30.0, 33, 58, and 71 m. For pumping rates of 40, 55, 70, 90, and $132m^3/d$ over 70 days, the estimated drawdown from the PW-2 well was 6.48, 11.56, 18.07, 28.99 and 60.26 m, respectively. During a constant-rate pumping test at a rate of $117m^3/d$, the cone of depression intersected an impermeable boundary after 120-150 min of pumping. Therefore, we consider the critical pumping rate for well PW-2 to be $90m^3/d$. After pumping at $90m^3/d$ for 70 days, the calculated drawdown was 28.82-31.27 m. We suggest an optimal pumping rate for well PW-2 of $70-90m^3/d$, as the optimal pumping rate should be similar to the critical pumping rate. Sharp increases in the slope of the time-drawdown relationship, dissolved oxygen concentrations, and oxidation-reduction potential during the constant-rate pumping test indicate the limited development of bedrock aquifers around PW-2.

A Study on the Morpholgies and Mechanical Properties of Sn-Zn Eutectic Alloys (Sn-Zn 공정합금(共晶合金)의 응고속도(凝固速度)에 따른 조직(組織)과 기계적(機械的) 성질(性質)에 관한 연구(硏究))

  • Lee, J.H.;Lee, K.W.
    • Journal of Korea Foundry Society
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    • v.5 no.4
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    • pp.258-270
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    • 1985
  • The structures and mechanical properties of undirectionally solidified Sn-Zn eutectic alloys have been examined over the growth range 7mm/h to 6,000mm/h. The structures of unidirectionally solidified Sn-Zn eutectic alloys were primarily broken-lamellar at growth rates below 760mm/h and became fibrous at higher growth rates above that. At a growth rate 3,084mm/h the structures were fibrouse only. There is no dendrites at any growth rates, but occasionally ribbon-like morphologies were seen. The under cooling increased parabolically with growth rate increase. The hardness of specimes increased with growth rates increase but heat-treated specimen decreased after growth rates 760mm/h and became constant value. The effect of heat-treatment was good at lower growth rate. At room temperature tensile strength increased with growth rates up to R=990mm/h and then tensile strength became near-constant value. The effect of heat-treatment was well at lower growth rate.

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Studies on the Colouring matters for Rubber Industry [I] -Kinetics of the Coupling reaction of H-acid- (고무용(用) azo계(系) 착색제(着色劑)에 관한 연구(硏究) -H-산(酸)의 Coupling반응(反應)에 관한 속도론적(速度論的) 고찰(考察)-)

  • Park, Heung-Cho
    • Elastomers and Composites
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    • v.12 no.1
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    • pp.27-32
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    • 1977
  • The kinetics of azo-coupling reaction of N-acetyl-H-acid (1-acetamino-8-hydroxynaphthalene-3, 6-disulfonic acid) with several heterocyclic diasonium compounds such as diazotiged 3-aminopyridine, 3-aminoquinoline, 8-aminoauinoline and aniline was studied. It was found that reactions proceeded at remarkably different rate. Reaction rate was in increasing order; 3-aminopyridine, 3-aminoquinoline, 8-aminoauinoline and aniline. And the activation energies were 9.62, 10.10, 10.39, 10.70 Kcal/mole, respectively. Especially, the rate constant of 3-aminopyridine was 100 times larger than that of benzene diasonium compound even in strong acidity. Hammett plot was also made of the rate constants obtained against the heterocyclic substituent constants reported in the literature. A good linear relationship was obtained and the reaction constant of N-acetyl H-acid was calculated to be 3.14.

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Improvement of the Accuracy in Cornering Cut Using End Mill (엔드밀의 코너 가공시 가공 정밀도 향상에 관한 연구)

  • Kim, Yong-Hyeon;Go, Seong-Rim
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.3
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    • pp.399-407
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    • 2001
  • The Surface, generated by end milling operation, is deteriorated by tool runout, vibration, friction, tool deflection, etc. Especially in cornering cut, surface accuracy is usually determined by varying cutting forces, which causes tool deflections. Cutting conditions like feed rate is usually kept constant during machining a part, which causes dimensional error in severe cutting. Cornering cut is a typical example of deterioration of surface accuracy when constant feed rate is applied. Therefore it becomes important to develop NC post processor module to determine optimal cutting conditions in various cutting situations. In this paper, cutting force is predicted in cornering cut with flat end mill and feed rate is determined by constraining constantly resultant force. Also some control characteristics of CNC machining center are evaluated.

Transmission Performance of Application Traffic on LTE Networks (LTE 네트워크에서 응용 트래픽의 전송 성능)

  • Kim, Young-Dong
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2017.05a
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    • pp.641-644
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    • 2017
  • Usage of LTE(Long Term Evolution) technology is expanded to industrial an emergency service field beyond commercial communications of mobile internet focused on smartphone. In this paper, transmission performance of LTE technology be supplied to various service area is analyzed on the level of application traffics. Performance is evaluated with compter simulation based NS(Network Simulator)-2, CBR(Constant Bit Rate), VBR(Variable Bit Rate File) traffic is used as simulation target. Results and methods of this paper can be used for research and developmemt of LTE based networks.

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The Pressure Dependence of the Rate Constant for the t-Butoxy Radical Decomposition Reaction

  • Park, Jung-Mee;Song, Nam-Woong;Choo, Kwang-Yul
    • Bulletin of the Korean Chemical Society
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    • v.11 no.4
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    • pp.343-347
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    • 1990
  • A thermal decomposition of the tert-butoxy radical has been studied in the gas phase over the pressure range of 1-200 torr at $413_{\circ}K$ using di-tert-butyl peroxide + trimethylsilane mixtures. The relative rate constants were obtained by studying the competitive reactions between tert-butoxy radical decomposition 4(t-BuO·→ CH_3COCH_3 + CH_3·)$ and hydrogen abstraction reaction from trimethylsilane $(t-BuO·+ HSi(CH_3)_3 → t-BuOH + Si(CH_3)_3)·).$ The conventional RRKM calculations were carried out to compare the observed fall-off behavior of the decomposition rate constant $({\kappa}_d)$ with the theoretical predictions using reasonable values of input parameters. In all cases the calculated half-rate pressure $(P_{1/2})$ were significantly higher than those observed. The failure of RRKM to reproduce the fall-off behavior led us to suggest that not all of vibrational modes contribute to excitation (leading to decomposition) on the same time scale.

A study on the Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives (Vanillylidene imine 유도체의 가수분해 반응에 관한 속도론적 연구)

  • Sung, Ki-Chun;Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.145-150
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    • 1995
  • The Kinetics velocity for hydrolysis reaction of vanillylidene imine derivatives has been measured by ultra-violet ray spectrophotometer in 20wt% $dioxane-H_2O$ at $25^{\circ}C$. It was measured the reaction rate Constant of vanillylidene imine derivatives that can be applied widely following to pH-change at $25^{\circ}C$. Final products that hydrolyzed the vanillylidene imine certified in vanillin and aniline derivative, and the effect of substitution radical that has affected on hydrolysis reaction was largely promoted to reaction rate by electron attrating group in acidity and electron donoring group in basic. From the results of rate constant to hydrolysis reaction, substituent radical effect and final products. It has certified the hydrolysis reaction mechanism of vanillylidene imine derivatives.

Effect of Diethylphthalate on the Release of Salicylic Acid from Ethylcellulose Films (소수성 가소제 Diethylphthalate가 Ethylcellulose 필름으로부터의 살리씰산 방출에 미치는 영향)

  • 이승용;신상철;이민화;심창구
    • YAKHAK HOEJI
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    • v.28 no.3
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    • pp.169-177
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    • 1984
  • Release characteristics of salicylic acid from ethylcellulose(EC) films containing varying ratio of dieththylphthalate (DEP) were studied. Mathematical analysis of the release data showed that the release behavior actually conforms with the Higuchi's diffusion-controlled model. The release rate constants(k) were independent from the film thickness and the pH of release medium, but were proportional to the concentration of salicylic acid itself. The logarithm of the release rate constant (log k) increased as the concentration of DEP was increased. In conclusion, hydrophobic plastisizer DEP seemed to be very useful in controlling release rate constant of slightly soluble drugs as like salicylic acid without changing it's release characteristics.

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Studies on the Zr-Pyrithione Complex (지르코늄-피리치온 착물에 관한 연구)

  • Kwon, Chung-Moo;Rhee, Gye-Ju
    • Journal of Pharmaceutical Investigation
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    • v.20 no.3
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    • pp.145-152
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    • 1990
  • Zirconium pyrithione complex was prepared by reaction of sodium-pyrithione solution and zirconyl chloride solution. The physico-chemical properties of the complex was examined by means of IR, XRD, DSC and NMR. And the stability of Zr-complex was investigated on the basis of accelerated stability analysis under conditions of temp. elevation, UV radiation and pH dependence. The result indicates that the ratio of the ligand to metal in Zr-pyrithione complex was determined 4:1, and its stability constant was $4.643{\times}10^4$. The rate order of decomposition of the complex was apparent first-order reaction of which rate constant and the decomposition rate was not only accelerated by effect of heat and UV radiation but was catalyzed by specific acid-base catalysis considered the pH dependence for the hydrolysis of the complex and the suspension was most stable over the range pH 4-8 indicating that solvent catalysis is the primary made of reaction in this region.

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Adaptive mode decision based on R-D optimization in H.264 using sequence statistics (영상의 복잡도를 고려한 H.264 기반 비트 율-왜곡 최적화 매크로블록 모드 결정 기법)

  • Kim, Sung-Jei;Choe, Yoon-Sik
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.291-292
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    • 2006
  • This paper presents rate-distortion optimization that is considered sequence statistics(complexity) to choose the best macroblock mode decision in H.264. In previous work, Lagrange multiplier is derived by the function of constant value 0.85 and QP so that is not the proper Lagrange multilplier for any image sequence. The proposed algorithm solves the problem by changing constant value 0.85 into adaptive value which is influenced by image complexity, and by reducing the encoder complexity to estimate the image statistics with the multiplication of transformed, quantized rate and distortion. Proposed algorithm is achieved the bit-rate saving up to 5% better than previous method.

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