• Journal of the Korean Applied Science and Technology
• /
• v.4 no.1
• /
• pp.67-71
• /
• 1987

The transesterification reaction between diethanolamine and methyl methacrylate was kinetically investigated in the presence of various metal acetate catalysts at $120^{\circ}C$. The amount of reacted methyl methacrylate was measured by gas chromatography and liquid chromatography, and the reaction rate also measured from the amount of reaction products and reactants under each catalyst. The transesterification reaction was carried out in the first order with respect to the concentration of diethanolamine and methyl methacrylate, respectively. The over-all order is 2nd. The apparent rate constant was found to obey first-order kinetics with respect to the concentration of catalyst. The maximum reaction rate was appeared at the range of 1.4 to 1.6 of electronegativity of metal ions and instability constant of metal acetates.

• Journal of Broadcast Engineering
• /
• v.8 no.2
• /
• pp.163-171
• /
• 2003

In this paper, we develop an approach toward Joint Source-Channel Coding for MPEG-4(Moving picture Experts Group) based video coding In fixed and mobile reception environment. We have considered channel environment of AWGN and mobile reception. The source coder used MPEG-4 video. the channel coder used RCPC(Rate Compatible Punctured Convolution) and the modulation method used QPSK(Quadrature Phase Shift Keying) modulation. This study determined optimum Trade-off point between source bit rate and channel coding rate In variable channel states. We compared Joint Source/channel Coding method and general constant bit rate transmission. In this results, Joint Source/channel Coding was appeared better performance than constant bit rate transmission.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.28 no.1
• /
• pp.71-78
• /
• 1992

Zr-4 used for a cladding and an end plug of reactor component has creep deformation under operation at high temperature. Creep is regarded as the time dependent deformation of a material under constant applied stress. Although the major source of the deformation of zirconium component in water-cooled reactors is irradiation creep, the thermal creep may give a rise to significant deformation in reactor component especially at relatively high temperatures and at various constant stresses, and therefore it must be predicted accurately. Stress relaxation is the time dependent change of stress at constant strain and it is a process related intimately to creep. In this paper, the creep behavior and stress relaxation of Zr-4 is examined at the temperature of 50$0^{\circ}C$ that is 40% of the absolute melting temperature of Zr-4 under the stress below yield stress and under the various constant strains. The results obtained are summarized as follows: 1) With an increase of stress, the steady state creep rate increases and the creep rupture time decreases. 2) The steady state creep rate $\varepsilon$(%/s) for the stress $\sigma$sub(c) (kgf/mm super(2)) of Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 increases outstandingly. All the empirical equations computed for Zr-4 are in accord with Norton's model equation($\varepsilon$=K$\sigma$ sub(c) super (n)). The constants of materials computed are as follows: K=3.9881$\times$10 super(-5), n=1.9608 3) The rupture time T sub(r) (hr) decreases linearly with the increase of stress on the log-log scaled graph. The empirical equations computed for Zr-4 are in accord with Bailey's model equation (T sub(r)=K sub(1)$\sigma$sub(c) super(m)). The constants of materials computed are as follows: K sub(1)=1.2875$\times$10 super(16), m=-3.467 4) It seems clear that the strain could be quantitatively dependent on the high temperature creep properties such as creep stress, rupture time, steady state creep rate and total creep rate. It is found that these relationships are linear on the log-log graph. 5) In stress relaxation test, as the critical constant strain that can be allowed to the specimen is larger, stress relaxation becomes more rapid, and as the constant strain is smaller, the stress relaxation becomes slower.

• 제어로봇시스템학회:학술대회논문집
• /
• 1994.10a
• /
• pp.106-111
• /
• 1994

We proposed a new variable sampling rate model which expresses the phenomena with both rapid and slow components. A method for determining the variable sampling rate and the older of the time series model was explained. The proposed variable sampling rate model was evaluated based oil an information criterion(AIC). Tile variable sampling rate model brought smaller an information criterion than one of a constant sampling rate model of conventional type, and was proved to be effective as a prediction model of the system with both rapid and slow components.

• KSBB Journal
• /
• v.13 no.6
• /
• pp.730-734
• /
• 1998

The mathematical model of specific growth rate of Saccharomyces cerevisiae ATCC 24858 is proposed as a function of sugar and ethanol concentrations by the combination of Andrew's equation and Aiba's equation. The maximum concentration of sugar Sm, which was the highest concentration of sugar not having any effect on the growth inhibition, was 150 g/L and the substrate inhibition was expressed as a function of (S-Sm). The maximum specific growth inhibition, was 150 g/L and the substrate inhibition was expressed as a function of (S-Sm). The maximum specific growth rate ${\mu}m$, Monod's constant Ks, and Andrew's inhibition constant KI were 0.49 hr-1, 19 g/L, and 139 g/L, respectively. The maximum ethanol concentration, Pm, which did not show any inhibition effect on the specific growth rate was found to be 2 g/L. Therefore, the ethanol inhibition was represented as a function of (P-Pm). The final mathematical model for the specific growth rate of the microorganism in this work is proposed as the following. And the average percent of errors between the calculated specific growth rate and the experimental values was 5.96%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.29 no.12
• /
• pp.628-637
• /
• 2017

This study was conducted to present an effective control method for the common duct system to uniformly discharge volume flow rate exhausted from the kitchen and bathroom of each household in an apartment regardless of the position of household. Since the common duct system is installed vertically and the ventilator is installed in the terminal, the static pressure of each household decreases when vertical height increases. Therefore, the volume flow rate exhausted from each household is different. In order to improve such a phenomenon, a constant air volume damper shall be installed in a branch duct coupled with a common vertical duct system. The selected ventilator should also be able to handle the maximum volume flow rate considering diversity factor. Therefore, a uniform volume flow rate must be exhausted from all households where the hood is operated. This paper mainly focuses on suggestion of an optimum exhaust control method by comparing exhaust performance of each household according to the presence or absence of a constant air volume damper.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2005.04a
• /
• pp.53-56
• /
• 2005

A Laboratory study was conducted to evaluate the kinetics of oxidation of trichloroethylene (TCE) in groundwater by potassium permanganate $(KMnO_4)$, Consumption of permanganate by TCE and aquifer materials was also evaluated to obtain an appropriate injection rate of $KMnO_4$. TCE degradation by $KMnO_4$ in the absence of aquifer material showed effective with pseudo-first order rate constant, $k_{obs}=1.8110^{-3}\;s^{-1}\;at\;KMnO_4=500mg/L$. TCE oxidation by $KMnO_4$ was found to be second order reaction and the rate constant, $k=0.65{\pm}0.08\;M^{-1}s^{-1}$, was independent of pH changes. $KMnO_4$ consumption rate by groundwater sampled from field site was not significant, indicating that groundwater containing negligible amount of dissolved organic matter does not have any influence on the $KMnO_4$ degradation. Meanwhile, aquifer materials from field site were actively reacted with permanganate, resulting in the significant consumption of $KMnO_4$. It might be attributed to the existence of metal oxides in aquifer materials, Based on the rate constants obtained from this study, appropriate injection rate of permanganate and TCE removal rate in groundwater could be estimated.

• Applied Chemistry for Engineering
• /
• v.25 no.2
• /
• pp.167-173
• /
• 2014

The adsorption characteristics of the pellet-type adsorbent prepared from water treatment sludge for trimethylamine and ammonia were studied. The surface area and pore volume of the pellet-type adsorbent increased during calcination at $500^{\circ}C$. It was confirmed that the adsorbent prepared from water treatment sludge contained Br$\ddot{o}$nsted and Lewis acid sites. The breakthrough time of the adsorbent for both trimethylamine and ammonia was measured at different adsorbent weights and linear velocities while maintaining constant amounts of trimethylamine and ammonia. The kinetic saturation capacity and the adsorption rate constant for trimethylamine and ammonia were determined at different linear velocities by using the Wheeler equation. It was found that the kinetic saturation capacity and the adsorption rate constant were dependent on the linear velocity. An experimental equation could be derived to predict the breakthrough time of the adsorbent prepared from water treatment sludge for trimethylamine and ammonia at different adsorption conditions.

• Journal of computational fluids engineering
• /
• v.19 no.4
• /
• pp.1-7
• /
• 2014

A numerical study of transient conjugate heat transfer on micro heater in a micro-channel substrate under a sinusoidal heat load was conducted. It was found that the time constant is not affected by the maximum heating magnitude of the sinusoidal heat load. However, the time constant increases with low duration of the sinusoidal heating period and low Reynolds number. Moreover, there is a threshold where a heater temperature do not reach to time constant at low thermal diffusivity, low flow rate, and low pulse duration of the sinusoidal heating. The time constant should be considered for transient convective heat transfer under transient sinusoidal heat load in a micro heat sink.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.1 no.1
• /
• pp.50-58
• /
• 1993

The ignition delay of diesel oil and fish oil blended with diesel oils was investigated at various pressure and temperature conditions in a constant volume combustion bomb. The evaporation and combustion duration of diesel oil and fish oil blended with diesel oils were respectively different in high and low temperature. The dependence of ignition delay on the temperature was different in high and low temperature ranges which were divided at the 773K. The dependence of ignition delay on the pressure was almost linear, regardless of the test fuels at the constant temperature(863K). The ignition delay became longer as the blending rate of fish oil increased at the constant temperature and pressure, but it was especially short with 20% fish oil blended with diesel oils.