• Title/Summary/Keyword: rare element

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Synthesis of the Multifunctional Core/Intermediate/Shell Nanoparticles: Tunable Magnetic and Photoluminescence Properties (자성 및 발광 특성이 조절 가능한 다기능 코어/중간체/쉘 나노 입자 합성)

  • Kim, Mun-Kyoung;Kim, Seyun;Moon, Kyoung-Seok;Shin, Weon Ho;Jeong, Hyung Mo
    • Journal of Powder Materials
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    • v.26 no.6
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    • pp.463-470
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    • 2019
  • Fe3O4/SiO2/YVO4:Eu3+ multifunctional nanoparticles are successfully synthesized by facile stepwise sol-gel processes. The multifunctional nanoparticles show a spherical shape with narrow size distribution (approximately 40 nm) and the phosphor shells are well crystallized. The Eu3+ shows strong photoluminescence (red emission at 619 nm, absorbance at 290 nm) due to an effective energy transfer from the vanadate group to Eu. Core-shell structured multifunctional nanoparticles have superparamagnetic properties at 300 K. Furthermore, the core-shell nanoparticles have a quick response time for the external magnetic field. These results suggest that the photoluminescence and magnetic properties could be easily tuned by either varying the number of coating processes or changing the phosphor elements. The nanoparticles may have potential applications for appropriate fields such as laser systems, optical amplifiers, security systems, and drug delivery materials.

Effect of Pressure on Microstructures and Mechanical Properties in Al-5%Ni-5%Mg-(Mm) Alloy Manufactured by Direct Squeeze Casting (직접가압주조한 Al-5%Ni-5%Mg-(Mm)합금의 조직 및 기계적 성질에 미치는 가압력의 영향)

  • Woo, Kee-Do;Chung, Dong-Suk;Hwang, In-O;Kim, Sug-Won
    • Journal of Korea Foundry Society
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    • v.21 no.2
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    • pp.127-134
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    • 2001
  • Misch metal (rare earth element, Ce, La, Nd, Pr) which has large influence on high-temperature stability and toughness was added to the Al-5%Ni-5%Mg alloy, and squeeze casting was used for Al-5%Ni-5%Mg-(Mm) alloys. The effect of applied pressure and misch metal additions on mechanical properties in Al-5%Ni-5%Mg alloy by direct squeeze casting has been investigated. The applied pressure were 0 MPa(gravity casting), 25, 50 and 75 MPa. Squeeze-cast Al-5%Ni-5%Mg-(Mm) alloys had better mechanical properties than those of non-pressurized cast alloys because of the increased cooling rate by the application of pressure during solidification. By the addition of misch metal in Al-5%Ni-5%Mg alloy, better combination of strength and elongation was obtained. The addition of 0.3%Mm in Al-5%Ni-5%Mg alloy improved the heat resistant property due to the formation of fine eutectic phases.

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The Surgical Management of Traumatic C6-C7 Spondyloptosis

  • Keskin, Fatih;Kalkan, Erdal;Erdi, Fatih
    • Journal of Korean Neurosurgical Society
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    • v.53 no.1
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    • pp.49-51
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    • 2013
  • A case of traumatic spondyloptosis of the cervical spine at the C6-C7 level is reported. The patient was treated succesfully with a anterior-posterior combined approach and decompression. The patient had good neurological outcome after surgery. A-51-year-old female patient was transported to our hospital's emergency department after a vehicle accident. The patient was quadriparetic (Asia D, MRC power 4/5) with severe neck pain. Plain radiographs, computerize tomography and spinal magnetic resonance imaging (MRI) showed C6-7 spondyloptosis and C5, C6 posterior element fractures. Gardner-Wells skeleton traction was applied. Spinal alignment was reachived by traction and dislocation was decreased to a grade 1 spondylolisthesis. Then the patient was firstly operated by anterior approach. Anterior stabilization and fusion was firstly achieved. Seven days after first operation the patient was operated by a posterior approach. The posterior stabilization and fusion was achieved. Postoperative lateral X-rays and three-dimensional computed tomography showed the physiological realignment and the correct screw placements. The patient's quadriparesis was improved significantly. Subaxial cervical spondyloptosis is a relatively rare clinical entity. In this report we present a summary of the clinical presentation, the surgical technique and outcome of this rarely seen spinal disorder.

Theoretical and experimental study of robustness based design of single-layer grid structures

  • Wu, Hui;Zhang, Cheng;Gao, Bo-Qing;Ye, Jun
    • Structural Engineering and Mechanics
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    • v.52 no.1
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    • pp.19-33
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    • 2014
  • Structural robustness refers to the ability of a structure to avoid disproportionate consequences to the original cause. Currently attentions focus on the concepts of structural robustness, and discussions on methods of robustness based structural design are rare. Firstly, taking basis in robust $H_{\infty}$ control theory, structural robustness is assessed by $H_{\infty}$ norm of the system transfer function. Then using the SIMP material model, robustness based design of grid structures is formulated as a continuum topology optimization problem, where the relative density of each element and structural robustness are considered as the design variable and the optimization objective respectively. Generalized elitist genetic algorithm is used to solve the optimization problem. As examples, robustness configurations of plane stress model and the rectangular hyperbolic shell model were obtained by robustness based structural design. Finally, two models of single-layer grid structures were designed by conventional and robustness based method respectively. Different interference scenarios were simulated by static and impact experiments, and robustness of the models were analyzed and compared. The results show that the $H_{\infty}$ structural robustness index can indicate whether the structural response is proportional to the original cause. Robustness based structural design improves structural robustness effectively, and it can provide a conceptual design in the initial stage of structural design.

Discovery of Giant Magnetostriction in Amorphous RFe$_2$B (R = Sm, Tb) Alloys

  • Kim, Jai-Young
    • Journal of Magnetics
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    • v.1 no.2
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    • pp.64-68
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    • 1996
  • Compared with the conventional magnetostriction in Ni alloys which are in the order of several tens ppm (Parts Per Million =10-6), RFe$_2$(R = rare earth element) Laves Phase intermetallic compounds show large saturation magnetostriction in the range of a few thousands ppm. However, the large external magnetic field necessary to obtain saturatio magnetostriction has due to large magnetocrystalline anisotropy energy restrained the applicationof magnetostriction materials in RFe$_2$intermetallic compounds. As a result of its solution, the largest published value of effective giant magnetostriction in a low external magnetic field (less than a few hundred Oe) is reported in this paper by means of amorphisation of RFe$_2$intermetallic compounds with the addition of boron, as a half metal. For the amorphous (SmFe$_2$)0.97 B0.03 alloys, the effective magnetostriction of -545 and -610 $\times$ 10-6 is obtained at 400 and 1,000 Ie, respectively. Moreover, the effective magnetostriction of 590 and 630$\times$10-6 in the amorphous (TbFe$_2$)0.98 B0.02 alloys is also found at 400 and 1,000 Oe, respectively. This result will provide a clue to understanding the effect of half metal on anomalous increase of the effective giant magnetostriction and attract the great attention for magnetostriction applications.

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Application of Buckling Restrained Braces in a 50-Storey Building

  • Sy, Jose A.;Anwar, Naveed;Aung, Thaung Htut;Rayamajhi, Deepak
    • International Journal of High-Rise Buildings
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    • v.3 no.1
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    • pp.81-87
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    • 2014
  • The use of Buckling Restrained Braces (BRB) for enhancing the performance of the buildings is gaining wider acceptance. This paper presents the first application of these devices in a major high-rise building in the Philippines. A 50-storey residential reinforced concrete building tower, with ductile core wall, with BRB system is investigated. The detailed modeling and design procedure of buckling restrained brace system is presented for the optimal design against the two distinct levels of earthquake ground motions; serviceable behavior for frequent earthquakes and very low probability of collapse under extremely rare earthquakes. The stiffness and strength of the buckling restrained brace system are adjusted to optimize the performance of the structural system under different levels of earthquakes. Response spectrum analysis is conducted for Design Basis Earthquake level and Service level, while nonlinear time history analysis is performed for the most credible earthquake. The case study results show the effectiveness of buckling restrained braces.

The influence of vehicles on the flutter stability of a long-span suspension bridge

  • Han, Yan;Liu, Shuqian;Cai, C.S.;Zhang, Jianren;Chen, Suren;He, Xuhui
    • Wind and Structures
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    • v.20 no.2
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    • pp.275-292
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    • 2015
  • The presence of traffic on a slender long-span bridge deck will modify the cross-section profile of the bridge, which may influence the flutter derivatives and in turn, the critical flutter wind velocity of the bridge. Studies on the influence of vehicles on the flutter derivatives and the critical flutter wind velocity of bridges are rather rare as compared to the investigations on the coupled buffeting vibration of the wind-vehicle-bridge system. A typical streamlined cross-section for long-span bridges is adopted for both experimental and analytical studies. The scaled bridge section model with vehicle models distributed on the bridge deck considering different traffic flow scenarios has been tested in the wind tunnel. The flutter derivatives of the modified bridge cross section have been identified using forced vibration method and the results suggest that the influence of vehicles on the flutter derivatives of the typical streamlined cross-section cannot be ignored. Based on the identified flutter derivatives, the influence of vehicles on the flutter stability of the bridge is investigated. The results show that the effect of vehicles on the flutter wind velocity is obvious.

Structural Stability Analysis of Connectors for an Electric Handbike (휠체어 전동주행 보조기기용 커넥터의 구조안정성 해석)

  • Seo, Han Wool;Kim, Dae Dong;Ko, Cheol Woong;Lee, Joon Hmm;Bae, Tae Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.5
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    • pp.491-496
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    • 2015
  • Electric handbike can be easily detachable to various sizes of manual wheelchair and the elderly and people with disabilities can use them easily. Therefore, connectors used for coupling between the handbike and manual wheelchair must secure structural stability for occupant safety. However, related research is rare. The aim of this study is to find the connector with highly structural stability by comparing static and dynamic mechanical characteristics among three typical connectors(a snatch lock, a slide latch, and a fastener) by computational simulations. To perform static and dynamic simulation, we referred to durability test based on Korean Standards and then calculated mechanical stresses in connectors. The results showed that the snatch lock addressed the lowest von-mises stress under the same mechanical condition. Therefore when using the combination of a handbike and a wheelchair, we concluded that the snatch lock is considered as the structurally stable connector to structural stability and usability.

Performance Based Seismic Design State of Practice, 2012 Manila, Philippines

  • Sy, Jose A.;Anwar, Naveed;HtutAung, Thaung;Rayamajhi, Deepak
    • International Journal of High-Rise Buildings
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    • v.1 no.3
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    • pp.203-209
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    • 2012
  • The purpose of this paper is to present the state of practice being used in the Philippines for the performance-based seismic design of reinforced concrete tall buildings. Initially, the overall methodology follows "An Alternative Procedure for Seismic Analysis and Design of Tall Buildings Located in the Los Angeles Region, 2008", which was developed by Los Angeles Tall Buildings Structural Design Council. After 2010, the design procedure follows "Tall Buildings Initiative, Guidelines for Performance-Based Seismic Design of Tall Buildings, 2010" developed by Pacific Earthquake Engineering Research Center (PEER). After the completion of preliminary design in accordance with code-based design procedures, the performance of the building is checked for serviceable behaviour for frequent earthquakes (50% probability of exceedance in 30 years, i.e,, with 43-year return period) and very low probability of collapse under extremely rare earthquakes (2% of probability of exceedance in 50 years, i.e., 2475-year return period). In the analysis, finite element models with various complexity and refinements are used in different types of analyses using, linear-static, multi-mode pushover, and nonlinear-dynamic analyses, as appropriate. Site-specific seismic input ground motions are used to check the level of performance under the potential hazard, which is likely to be experienced. Sample project conducted using performance-based seismic design procedures is also briefly presented.

강원도 탄산수내 희유원소 (REE)의 분포 및 거동

  • 최현수;고용권;배대석;윤성택
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.331-334
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    • 2002
  • 탄산수내 REEs의 함량과 거동특성을 알아보기 위해 암석시료, 탄산수 및 침전물에 대한 REEs 분석을 실시하였다. 탄산수가 산출되는 인접지에서 채취한 암석시료들은 물의 유형에 따라 큰 농도변화를 보여주지 않으며, 대체적으로 LREEs가 부화된 특성을 보여주고 있다. 유형에 따른 탄산수의 REEs 농도변화는 서로 상이한데, Na-HCO$_3$ 유형은 강한 HREE의 부화를 보여주지만, Ca-HCO$_3$ 유형은 HREE의 부화를 보여주지 않고 감소하는 경향을 보이며, 화학적으로 중간 유형에 속하는 Ca-Na-HCO$_3$ 유형 탄산수는 Eu을 제외하고는 전체적으로 flat한 분포를 보여준다. 탄산수에서 침전된 침전물과 침전물을 제거한 물의 REE의 유형은 침전물이 발생되기 전의 탄산수와 유사한 경향을 보이지만, 침전물의 발생으로 인한 특징적이고 강한 anomalies를 보여준다. 침전된 침전물의 REEs 특성은 침전물이 발생되기 전의 원 탄산수와 거의 유사한 분포특성을 보여준다. 반면에 침전물을 제거한 탄산수에서는 탄산염침전물의 침전과 연관되어 매우 강한 Eu anomalies를 보여주며, 대체적으로 HREE가 부화된 특성을 보여주었다. 탄산수내 가장 우세한 REE 종은 CO$_3$$^{2-}$ 종이며, CO$_3$$^{2-}$ 복합체 때문에 REEs의 분별작용 (HREE의 부화)이 일어나는 것으로 판단되 었다.

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