• Title/Summary/Keyword: rare element

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A Study on Addition of Rare Earth Element in the Spent Permanent Magnet Scrap to Gray Cast Iron (회주철에서의 폐 영구자석 스크랩을 활용한 희토류 원소 첨가 영향 연구)

  • Park, Seung-Yeon;Noh, Jung-Hyun;Kim, Hyo-jung;Lim, Kyoung-Mook
    • Resources Recycling
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    • v.27 no.3
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    • pp.48-57
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    • 2018
  • In this study, we developed a method for manufacturing high strength gray cast irons by adding a rare earth element (R.E.) included in a spent permanent magnet scrap to gray cast irons. The improvement of the mechanical properties of gray cast irons is attributed to A-type graphite formation promoted by complex sulfide, which was formed by R.E. in the spent magnets during a solidification process. The cast specimen inoculated by R.E. in the spent magnet scrap showed excellent tensile strength up to 306 MPa, and is similar to that of the specimen inoculated by expensive misch-metal. In this regards, we concluded that the cheap spent magnets scrap is a very efficient inoculation agent in fabrication of high performance gray cast irons.

A Study on the Recovery of Rare Earth Minerals from Ja-Eun Iron Ore. (자은철광석으로부터 희토류광물 회수에 관한 연구)

  • Jeon, Ho-Seok;Kim, Joon-soo;Moon, Young-bae;Lee, Jae-Jang
    • Journal of Industrial Technology
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    • v.21 no.A
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    • pp.257-261
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    • 2001
  • The separation of rare earths minerals is very difficult because of their similar chemical properties. The rare earth minerals are used as the mixed rare earth minerals or the misch metal without separation to each element. However, the high purity rare earths are recently produced commercially to each element so they there are used as the materials for high tech. Based on the characterization results for the raw minerals, we have developed a combined process containing gravity seperation, magnetic seperation and flotation. The result obtained from this study is monazite concentration of TREO grade 69.11% and Recovery 56.02%.

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Study on the Precision Analysis of Lanthanides by Atomic Emission Spectroscopy (I). Separation of Rare Earth Elements Using Ln-EDTA Eluent (원자발광광도법에 의한 란탄족 원소의 정밀분석에 관한 연구 (제 1 보) 희토류-EDTA 용리액에 의한 희토류 원소의 분리 회수)

  • Cha Ki-Won;Oh Jin-Hee;Ha Young-Gu;Kim Ha-Suck
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.692-696
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    • 1992
  • $NH_4^+ form cation exchange resin was used to separate one rare earth element from the rare earth mixture solution using Ln-EDTA eluent. Rare earth mixture solution was passed through the resin bed and eluted with 0.1M La-EDTA solution as an eluent. In here all the rare earth element except lanthanum ion are eluted and lanthanum ion absorbed in resin bed is eluted using 0.1M EDTA solution. If Ce-EDTA solution instead of La-EDTA solution was used as an eluent, all the rare earth element except cerium ion are eluted and cerium ion is eluted with 0.1M EDTA solution. This method can be applied to separate the individual rare earth element from the mixture. The separation mechanism is as follows: Absorption : 3RNH_4 + Ln^{3+} = R_3Ln + 3NH_4^+, La-EDTA elution : R_3Ln + La-Y- = R_3La + Ln-Y-, EDTA elution : R_3La + HY^3- = La_-Y + RH + 2R^-.$

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Trends and Implications of International Standardization for Rare Earths (희토류 관련 국제표준 동향 및 시사점)

  • Abbas, Sardar Farhat;lee, Sang-Hyun;Lee, Bin;Kim, Bum-Sung;Kim, Taek-Soo
    • Journal of Powder Materials
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    • v.25 no.2
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    • pp.165-169
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    • 2018
  • Rare earth elements (REEs) are considered to be vital to modern industry due to their important roles in applications such as permanent magnets, automobile production, displays, and many more. The imbalance between demand and supply of REEs can be solved by recycling processes. Regarding the needs of industry and society, the International Organization for Standardization, Technical Committee 298 (ISO/TC298) Rare Earths has been recently launched for developing international standards on rare earth elements. In accordance with the suggestion of its constituents, it is tentatively working to develop the appropriate standards under five working groups (WG) on terms and definitions (WG1), element recycling (WG2), environmental stewardship (WG3), packaging, labelling, marking, transport, and storage (WG4), and testing analysis (WG5). The scope and structure of ISO/TC298 on the topic of rare earths is discussed in this document.

Co-doping Effects on the Blue Up-conversion Characteristics of Fluoride Glasses (희토류 원소의 복합첨가에 의한 fluride 유리에서의 청색 상향전이현상)

  • 류선윤
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.33-43
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    • 2000
  • Up-conversion of rare-earth element added glass is promising area for short wavelength laser source by utilizing high power semiconductor infra-red laser if the efficiency can be increased by proper method. In this study, relatively low phonon energy fluoride glasses were prepared by co-doping rare-earth elements to realize the high efficiency up-convertor. The physical, chemical, andoptical properties of co-doped fluoride glasses were measured. 10 combinations of 5 different rare-earth fluoride elements doped samples were prepared and their transition temperatures, chemical durability, density, hardness, refractive index, absorption, fluorescence, and fluorescence lifetime were measured. 480nm wavelengths blue up-conversion was found in the Yb3+/Tm3+ co-doped glass sample with 800nm laser source and the optimum composition for the most efficient blue up-conversion was found from the glass sample with 0.3 mol% TmF3 and 1 mol% YbF3.

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Effect of Zircon on Rare-Earth Element Determination of Granitoids by ICP-MS (ICP-MS를 이용한 화강암내 희토류원소 분석시 저어콘이 미치는 영향)

  • Lee, Seung-Gu;Kim, Taehoon;Han, Seunghee;Kim, Hyeon Cheol;Lee, Hyo Min;Tanaka, Tsuyoshi;Lee, Seung Ryeol;Lee, Jong Ik
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.337-349
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    • 2014
  • We measured rare earth element and Zr concentrations of USGS granite standard material GSP-2 and GSJ granite standard material JG-1a to clarify the effect of zircon during rare earth element analysis using ICP-MS. We also measured rare-earth element and zirconium (Zr) contents of zircon from granite by acid-digestion methods using conventional teflon vial and pressure-bomb. The results show that acid-digestion using teflon vial dissolved ca. 50% of zircon compared to pressure-bomb method. The Zr contents of JG-1a and GSP-2 gave ca 50% of reference value. However, rare-earth element abundance of JG-1a and GSP-2 were similar to those of reference values. This suggests that the decomposition degree of zircon might give a negligible effect on a petrological and geochemical interpretation using chondritenormalized REE pattern.

The Composition of the Rare Earth Based Conversion Coating Formed on AZ91D Magnesium Alloy

  • Chang, Menglei;Wu, Jianfeng;Chen, Dongchu;Ye, Shulin
    • Corrosion Science and Technology
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    • v.17 no.1
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    • pp.1-5
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    • 2018
  • As structural materials, magnesium (Mg) alloys have been widely used in the fields of aviation, automobiles, optical instruments, and electronic products. There are few studies on the effect of coating conditions on the compositional variation during the formation process of the conversion coatings. Rare-earth based conversion coating on AZ91 magnesium alloy was prepared in ceric sulfate and hydrogen peroxide contained solution. The element composition and valence as well as their distribution in the coating were analyzed with energy dispersive X-ray spectroscopy (EDS), Electron probe micro-analyzer (EPMA), X-ray photoelectron spectroscopy (XPS). The effect of treating process on the element composition were also studied. It was found that the conversion coating surface consists of Mg, Al, O, Ce, and the weight content of Ce in the coating was affected by the treating solution concentration and immersion time; the Ce element was distributed in the coating non-uniformly and existed in the form of $Ce^{+3}$ and $Ce^{+4}$, while the O element existed in the form of $OH^-$, $O^{2-}$, $H_2O$. Based on microscopic analysis results, the electrochemical deposition mechanism on the micro-anode and micro-cathode in the process of the coating growth was suggested.

Abundane of Rare Earth Element in Duwon Meteorite and Its Geochchemical Significance (두원운석의 희토류원소 존재도 및 지구화학적 의의)

  • Lee Seung-Gu;Kim Kun-Han;Choi Byeon-Gak
    • The Journal of the Petrological Society of Korea
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    • v.13 no.4
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    • pp.238-243
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    • 2004
  • Duwon meteorite was fallen on 23 November 1943 in Duwonmyeon, Goheung, Jeolanam-Do. We measured rare earth element abundance of Duwon meteorite by isotope dilution thermal ion mass spectrometry (ID-TIMS) and ICP-MS. As a result, except La and Ce, abundance of other rare earth element show a correspondence within 10% of error range. However, La and Ce show more than 70% in abundance, which is considered due to 1) experimental procedure or 2) inhomogeneity of sample. Leedey meteorite was fallen on 25 November 1943 in Dewey County, Oklahoma, USA. which suggested that fallen difference between Leedey and Duwon meteorites is only 2 days. Leedey and Duwon meteorites are classified as ordinary chondrite of L6 type. In Leedey chondrite-normalized REE pattern, Duwon meteorite shows nearly flattened, which suggests close relationship between Leedey and Duwon meteorites meteoritically or cosmochemically.

A Study on the Design of BLDC Motor Replacing Ferrite Magnet with Rare Earth Magnet (페라이트 자석을 희토류 자식으로 교체한 BLDC 전동기의 설계에 관한 연구)

  • Chung, Tae-Kyung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.4
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    • pp.121-129
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    • 2008
  • This paper deals with the design of BLDC motor replacing ferrite magnet with rare earth magnet. Electric machinery system using ferrite magnet motor is already widespread in large numbers. Electrical appliance makers have a tendency to adhere to existing system using ferrite magnet motors because of redesigning the whole system. This paper designs the rare earth magnet motor untouching the external system dimension and motor outer size. To do the design simply, finite element package is used iteratively To reduce the cogging torque effect and magnetic saturation, stator yoke shape and the groove of the end face of yoke are redesigned.