• Title/Summary/Keyword: rare earth

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Review on Evaluation of Rare Earth Metals and Rare Valuable Metals Contained in Coal Ash of Coal-fired Power Plants in Korea

  • Park, Seok-Un;Kim, Jae-Kwan;Seo, Yeon-Seok;Hong, Jun-Seok;Lee, Hyoung-Beom;Lee, Hyun-Dong
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.121-125
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    • 2015
  • Distribution of rare earth metals (REMs) and rare valuable metals (RVMs) contents in coal ashes (fly ash, bottom ash, and pond ash) and leachate from 11 coal-fired power plants in Korea were investigated. Coal ashes and leachates were found to contain important REMs and RVMs such as Yttrium (Y) and Neodymium (Nd), which was in the range of 23~75 mg/kg. However, it still requires developing effective recovery and separation methods in order to utilize REMs and RVMs in ash and leachate. Recovery of valuable elements (Y and Nd) from various and extensive ash sources (8.21 million tons/year in 2013) can provide the existing power plants with additional profit; therefore, it can significantly improve economics of the power plants.

Effect of Zircon on Rare-Earth Element Determination of Granitoids by ICP-MS (ICP-MS를 이용한 화강암내 희토류원소 분석시 저어콘이 미치는 영향)

  • Lee, Seung-Gu;Kim, Taehoon;Han, Seunghee;Kim, Hyeon Cheol;Lee, Hyo Min;Tanaka, Tsuyoshi;Lee, Seung Ryeol;Lee, Jong Ik
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.337-349
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    • 2014
  • We measured rare earth element and Zr concentrations of USGS granite standard material GSP-2 and GSJ granite standard material JG-1a to clarify the effect of zircon during rare earth element analysis using ICP-MS. We also measured rare-earth element and zirconium (Zr) contents of zircon from granite by acid-digestion methods using conventional teflon vial and pressure-bomb. The results show that acid-digestion using teflon vial dissolved ca. 50% of zircon compared to pressure-bomb method. The Zr contents of JG-1a and GSP-2 gave ca 50% of reference value. However, rare-earth element abundance of JG-1a and GSP-2 were similar to those of reference values. This suggests that the decomposition degree of zircon might give a negligible effect on a petrological and geochemical interpretation using chondritenormalized REE pattern.

A Strategical Review on the Rare Earth (희토류에 관한 심층적인 고찰)

  • Lee, Hyo-Sook
    • Journal of the Korean Professional Engineers Association
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    • v.44 no.2
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    • pp.39-42
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    • 2011
  • The main concern at the moment is securing rare earth(RE) resources, because the RE is the essential elements in green technology such as hybrid car, wind power plant, LED, display etc. It's impossible Korea will be a advanced country without securing RE. The importance of investment radically in the securing RE resources and professional engineers can not be overinvested.

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Effects of Rare Earth on Growth Characteristics and Productivities of Crimson Clover and Hairy Vetch (희토가 크림손 클로버와 헤어리 베치의 생산성과 사료가치에 미치는 영향)

  • Lee, Joung-Kyong;Yoon, Sei-Hyung;Jeong, Min-Woong;Kim, Jong-Geun;Park, Hyung-Soo;Lim, Young-Cheol;Kim, Won-Ho;Lee, Sang-Hoon;Ji, Hee-Chung
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.29 no.1
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    • pp.19-24
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    • 2009
  • The plant height of hairy vetch was high to comparing with crimson clover, and that of crimson clover was the lowest while that of hairy vetch was the highest with one application of rare earth. The dry matter content of crimson clover and hairy vetch were 20.3% and 18.1%, respectively and the dry matter content between two species had little difference. In this study, the fresh yield of hairy vetch was higher than that of crimson clover, while the dry matter yield of crimson clover was higher than that of hairy vetch. But there were not significant difference between two species. Although the fresh and dry matter yield of both species were the high with one application of rare earth, there were not significant difference between three treatments of rare earth. The nutritive values of hairy vetch were higher than that of crimson clover Neural detergent fiber (NDF) and acid detergent fiber (ADF) content decreased with one application of rare earth. But crude protein (CP) and digestibility were not significant between rare earth applications.

Application of Rare Earth Compounds for the Treatment of Phosphate and Fluoride in Wastewater (인산염 및 불소폐수 처리제로서의 희토류 화합물 적용에 관한 연구)

  • Kim, Jin-Wha;Shin, Sung-Hye;Song, Hye-Won;Kim, Dong-Su;Woo, Sang-Mo;Kwon, Young-Shik
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1127-1137
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    • 2000
  • Applications of lanthanum ion and crude rare earth chloride to the phosphate wastewater and fluorine wastewater, respectively, as treatment agents were studied. For the investigation of phosphate removal characteristics according to the amount of lanthanum ion, initial phosphate content was decreased by about 50% when molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] was 0.25 and nearly all of phosphate was removed when the molar ratio of [$La^{3+}$]:[$PO_4{^{3-}}-P$] to be doubled. The removal of phosphate by $La^{3+}$ appeared to reach equilibrium state rapidly, and it was exothermic reaction since the removed amount of phosphate was diminished somewhat when the reaction temperature was increased. The zeta potential of combined particulate compound of lanthanum ion and phosphate was located for its isoelectric point at pH 5.5 and the turbidity of treated wastewater was found to vary according to the pH in a similar manner as the absolute value of zeta potential of the combined particulate compound did. For the treatment of fluorine wastewater by crude rare earth chloride, the remaining fluorine content after treatment decreased as the dosage of crude rare earth chloride increased. Whereas, the turbidity of treated wastewater and the amount of sludge generated were shown to increase as more crude rare earth chloride was added. The remaining fluorine content and the turbidity of treated wastewater were decreased and the amount of sludge generated was observed to increase according the increase of coagulant dosage under the condition of constant input of crude rare earth chloride.

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Sintering and Grain Growth of Rare Earth-Doped Ceria Particles

  • Sameshima, Soichiro;Higashi, Kenji;Hirata, Yoshihiro
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.65-86
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    • 2000
  • Rare earth-doped ceria powders with a composition of Ce0.8R0.2O1.9(R=Yb, Y, Gd, Sm, Nd and La) were prepared by heating the oxalate coprecipitate. The green compacts began to shrink at 600$^{\circ}$-700$^{\circ}C$. The relative density after the sintering at 1200$^{\circ}$ and 1400$^{\circ}C$ became higher for the higher green density. The samples were densified above 98% relative density by the sintering ant 1600$^{\circ}C$ for 4 h and the grain sizes (4.7-7.6$\mu\textrm{m}$) showed a tendency to become larger with increasing ionic radius of doped-rare earth element. In the intial stag of sintering at 700$^{\circ}$-800$^{\circ}C$, the dominant mass transport process changed from lattice diffusion to grain boundary diffusion to grain boundary diffusion with heating time. The porosity during the intermediated and final stage of the sintering at 1200$^{\circ}$ and 1400$^{\circ}C$ decreased by the mass transport through lattice diffusion with grain growth.

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