• 제목/요약/키워드: rapid relaxation

검색결과 78건 처리시간 0.024초

FDM 3D프린팅 어닐링 조건에 따른 내부응력 완화에 관한 연구 (Investigation of the Internal Stress Relaxation in FDM 3D Printing : Annealing Conditions)

  • 이선곤;김용래;김수현;김주형
    • 한국기계가공학회지
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    • 제17권4호
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    • pp.130-136
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    • 2018
  • In this paper, the effects of different 3D printing parameters including laminated angle and annealing temperature, were observed for their effects on tensile testing. In 3D printing, a filament is heated quickly, extruded, and then cooled rapidly. Because plastic is a poor heat conductor, it heats and cools unevenly causing the rapid heating and cooling to create internal stress within the printed part. Therefore, internal stress can be removed using annealing and to increase tensile strength and strain. During air cooling at annealing temperature $140^{\circ}C$, the strain of laminated angle $45^{\circ}$ specimens tended to increase by 46% while the tensile stress tended to increase by 7.4%. During oven cooling at annealing temperature $140^{\circ}C$, the strain of laminated angle $45^{\circ}$ specimens tended to increase by 34% while the tensile stress tended to increase by 22.2%. In this study, we found "3D printing with annealing" eliminates internal stress and increases the strength and stiffness of a printed piece. On the microstructural level, annealing reforms the crystalline structures to even out the areas of high and low stress, which created fewer weak areas. These results are very useful for making 3D printed products with a mechanical strength that is suitable for applications.

Pd/Co 다층박막의 구조 및 자기적 특성에 미치는 기판온도 및 열적안정성에 관한 연구 (Thermal Stability and the Effect of Substrate Temperature on the Structural and Magnetic Properties of Pd/Co Multilayer Films)

  • 허용철;김상록;이성래;김창수
    • 한국자기학회지
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    • 제3권4호
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    • pp.298-304
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    • 1993
  • Pd/Co 다층박막을 동시열증착장치로 제작하여, 토오크 자력계, 홀 효과 측정장치 및 X-선 회절기를 이용하여 기판 온도, Pd하지층에 따른 구조적 자기적 및 열적 특성변화를 연구하였다. 기판 온도가 증가함에 따라 $150^{\circ}C$까지는 계면구조 및 각 층의 결정성이 향상되고, (111) 집합조직이 발달되었으며 따라서 계면자기이방성 및 수직자기 이방성에너지는 증가하였다. 그러나 보자력은 감소 하였는데 이는 입자의 성장으로 인한 자구벽 고착효과 감소에 기인된 것으로 보이며 Pd하지층이 두꺼 울 수록 다층박막의 입자크기는 컸다. $200^{\circ}C$ 이상에서는 계면에서 상호확산에 의하여 다층막의 구조의 열화는 촉진되었다. 열처리 초기에 주 피이크 강도의 변화는 컸으며 그 후부터는 작은 폭으로 감소하였다. 초기의 큰 강도 변화는 구조이완등의 현상에 기인된 것으로 추측되며 그 후는 확산에 의 해서이다. 다층박막의 상호확산에 필요한 활성화 에너지는 14.9 KCal/mole.K 였다.

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Thyroid Hormone-Induced Alterations of Ryanodine and Dihydropyridine Receptor Protein Expression in Rat Heart

  • Kim, Hae-Won;Park, Mi-Young;Lee, Eun-Hee;Cho, Hyoung-Jin;Lee, Hee-Ran
    • The Korean Journal of Physiology and Pharmacology
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    • 제3권3호
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    • pp.329-337
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    • 1999
  • Thyroid hormone-induced cellular dysfunctions may be associated with changes in the intracellular $Ca^{2+}$ concentration. The ryanodine receptor, a $Ca^{2+}$ release channel of the SR, is responsible for the rapid release of $Ca^{2+}$ that activates cardiac muscle contraction. In the excitation-contaction coupling cascade, activation of ryanodine receptors is initiated by the activity of sarcolemmal $Ca^{2+}$ channels, the dihydropyridine receptors. In hyperthyroidism left ventricular contractility and relaxation velocity were increased, whereas these parameters were decreased in hypothyroidism. The mechanisms for these changes have been suggested to include alterations in the expression and/or activity levels of various proteins. In the present study, quantitative changes of ryanodine receptors and the dihydropyridine receptors, and the functional consequences of these changes in various thyroid states were investigated. In hyperthyroid hearts, $[^3H]ryanodine$ binding and ryanodine receptor mRNA levels were increased, but protein levels of ryanodine were not changed significantly. However, the above parameters were markedly decreased in hypothyroid hearts. In case of dihydropyridine receptor, there were a significant increase in the mRNA and protein levels, and [3H]nitrendipine binding, whereas no changes were observed in these parameters of hypothyroid hearts. Our findings indicate that hyperthyroidism is associated with increases in ryanodine receptor and dihydropyridine receptor expression levels, which is well correlated with the ryanodine and dihydropyridine binding. Whereas opposite changes occur in ryanodine receptor of the hypothyroid hearts.

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Land Cover Change and Urban Greenery Prediction in Jabotabek by using Remote Sensing

  • Zain, Alinda-Medrial;Takeuchi, Kazuhiko;Tsunekawa, Atsushi
    • Journal of the Korean Institute of Landscape Architecture International Edition
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    • 제1호
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    • pp.59-66
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    • 2001
  • The tremendous growth of population and physical development in the largest urban agglomeration in Indonesia -the Jakarta Metropolitan Region, also known as Jabotabek (Jakarta, Bogor, Tanggerang, Bekasi)- has created many environmental problems, such as land use conversion, increasing urban temperature, water and air pollution, intrusion of seawater, and flooding. These problems have become more serious as the urban green space (trees, shrubs, and groundcovers) has decreased rapidly with the urbanization process. Urban green space directly benefits the urban environment through ameliorating air pollution, controlling temperature, contributing to the balance of the hydrological system, and providing space for recreation and relaxation. Because there is little hard data to support the claim of decreasing greenery in Jabotabek, it is necessary to measure the amount of urban green space. The paper describes the spatial analysis of urban green space within Jabotabek through the use of a geographical information system (GIS). We used GIS and remote sensing to determine land cover change and predicted greenery percentage. Interpretation of Landsat data for 1972, 1983, 1990, and 1997 showed that Jabotabek has experiences rapid development and associated depletion of green open space. The proportion of green open space fell by 23% from 1972 to 1997. We found a low percentage of urban green space in the center of Jakarta but a high percentage in fringe area. The amount of greenery is predicted by the Ratio Vegetation Index (RVI) model: predicted greenery (%) = [146.04] RVI - 134.96. We consider that our result will be useful for landscape planning to improve the environment of Jabotabek.

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Effects of annealing temperature on structural and optical properties of CdS Films prepared by RF magnetron sputtering

  • 황동현;안정훈;손영국
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.233-233
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    • 2010
  • CdS thin films were deposited on glass substrates by R.F. magnetron sputtering method and some of the samples were treated by rapid thermal annealing (RTA) process. Effects of thermal annealing on structural and optical properties were investigated at different temperatures ranging from 100 to $600^{\circ}C$. The crystallographic structure of the films and the size of the crystallites in the films were studied by X-ray diffraction. The crystallite sizes were found to increase, and the X-ray diffraction patterns were seen to sharpen by annealing. Optical properties of the films were calculated using the envelope method and the photoluminescence measurements. The optical properties of the films were seen to be dependent on the film thicknesses. The energy gap of the films was found to decrease by annealing. The band edge sharpness of the optical absorption was seen to oscillate by thermal annealing. Annealing over $400^{\circ}C$ was seen to degrade the optical properties of the film. The best annealing temperature for the films was found to be $400^{\circ}C$ from the optical properties. It is observed that the CdS film annealed at $400^{\circ}C$ reveals the strongest UV emission intensity and narrowest full width at half maximum among the temperature ranges studied. The enhanced UV emission from the film annealed at $400^{\circ}C$ is attributed to the improved crystalline quality of CdS thin film due to the effective relaxation of residual compressive stress and achieving maximum grain size. The results show that heat treatments under optimal annealing condition can provide significant improvements in the properties of CdS thin films.

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GRRI를 이용한 2차원 MT 탐사자료의 역산 (Generalized Rapid Relaxation Inversion of Two-Dimensional Magnetotelluric Survey Data)

  • 정용현;서정희;신창수
    • 지구물리와물리탐사
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    • 제1권1호
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    • pp.71-78
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    • 1998
  • 2차원 MT탐사자료의 역산은 보편적으로 많은 계산시간과 기억용량이 소요되며 TM모드의 경우지표 근처의 불균질대에 야기될 수 있는 정적 효과에 대한 주의 깊은 고려도 필요하게 된다. 이에 본 연구에서는 GRRI를 이용하여 TM모드 MT자료의 2차원 역산 알고리듬을 구현하였다. 본 역산 알고리듬은 국부적인 2차원 해석을 통한 모형변수 증분 해석에 기초를 두는데 이는 모형변수의 증분을 구하는 과정에 있어서 탐사의 대상인 2차원 전 영역을 동시에 고려하지 않고 국부 영역들로 분할하여 순차적으로 고려함으로써 수평적인 변화가 고려되면서도 자코비안을 구하는 과정에서 사용되는 부가적인 모델링 과정을 배제하여 계산시간과 기억용량을 최소화하기 위한 것이다. 구현된 알고리듬의 타당성 검증은 간단한 이론모형에 대한 적용을 통하여 이루어졌으며, 이를 토대로 타 알고리듬과의 비교를 통하여 그 특징을 살펴보는 한편, 여러 가지 다양한 모형에 적용하여 그 현장 적용성을 고찰하였다. 본 알고리듬을 이용한 역산은 계산시간과 기억용량 면에서 매우 경제적이며 전류집중에 의해 탐사자료에 왜곡이 생기는 경우에는 특별한 전처리과정 없이도 타당한 분해능을 확인할 수 있었다. GRRI를 이용한 역산 알고리듬은 향후 현장에서 실시간 역산으로서 경제적이면서 타당한 자료 해석에 적용성이 기대된다.

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Nd2XCd2-3XSiO4 (0.01≤X≤0.21) 고용체의 합성과 구조 규명 (Synthesis, Structure and Characterization of Nd2XCd2-3XSiO4 (0.01≤X≤0.21) Solid-Solutions)

  • Ramesh, S.;Das, B.B.
    • 대한화학회지
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    • 제55권3호
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    • pp.502-508
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    • 2011
  • [ $Nd_{2x}Cd_{2-3x}SiO_4$ ]($0.01{\leq}x{\leq}0.21$) [S1-S3: x=0.01, 0.11 and 0.21] 고용체를 졸-겔 방법을 통해 합성하였다. X선 분말회절(XRD) 측정은 $P2_1$/m 공간군의 단사정계를 보여준다. 평균 결정 크기는 20-45 nm이다. 주사전자현미경(SEM)으로 살펴본 모양은 구형의 특성을 보인다. 에너지 분산 X 선 분광기(EDS) 결과로부터 모든 구성 원소의 존재를 확인하였다. ~750 nm에서의 흡수 밴드는 $Nd^{3+}$ 이온의 $^4I_{9/2}{\rightarrow}^4F_{7/2}+^4S_{3/2}$ 전이에 기인한다. 10, 40, 77, 300 K에서 S1-S3의 전자 상자성 공명 (EPR) 선모양은 $Nd^{3+}$ 이온의 빠른 스핀 격자 이완에 기인하는 폭이 넓은 구분되지 않은 등방성의 선모양을 보여준다.

Unchanged Protein Level of Ryanodine Receptor but Reduced $[^3H]$ Ryanodine Binding of Cardiac Sarcoplasmic Reticulum from Diabetic Cardiomyopathy Rats

  • Lee, Eun-Hee;Seo, Young-Ju;Kim, Young-Hoon;Kim, Hae-Won
    • The Korean Journal of Physiology and Pharmacology
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    • 제5권5호
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    • pp.397-405
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    • 2001
  • The ryanodine receptor, a $Ca^{2+}$ release channel of the sarcoplasmic reticulum (SR), is responsible for the rapid release of $Ca^{2+}$ that activates cardiac muscle contraction. In the excitation-contraction coupling cascade, activation of SR $Ca^{2+}$ release channel is initiated by the activity of sarcolemmal $Ca^{2+}$ channels, the dihydropyridine receptors. Previous study showed that the relaxation defect of diabetic heart was due to the changes of the expressional levels of SR $Ca^{2+}$ATPase and phospholamban. In the diabetic heart contractile abnormalities were also observed, and one of the mechanisms for these changes could include alterations in the expression and/or activity levels of various $Ca^{2+}$ regulatory proteins involving cardiac contraction. In the present study, underlying mechanisms for the functional derangement of the diabetic cardiomyopathy were investigated with respect to ryanodine receptor, and dihydropyridine receptor at the transcriptional and translational levels. Quantitative changes of ryanodine receptors and the dihydropyridine receptors, and the functional consequences of those changes in diabetic heart were investigated. The levels of protein and mRNA of the ryanodine receptor in diabetic rats were comparable to these of the control. However, the binding capacity of ryanodine was significantly decreased in diabetic rat hearts. Furthermore, the reduction in the binding capacity of ryanodine receptor was completely restored by insulin. This result suggests that there were no transcriptional and translational changes but functional changes, such as conformational changes of the $Ca^{2+}$ release channel, which might be regulated by insulin. The protein level of the dihydropyridine receptor and the binding capacity of nitrendipine in the sarcolemmal membranes of diabetic rats were not different as compared to these of the control. In conclusion, in diabetic hearts, $Ca^{2+}$ release processes are impaired, which are likely to lead to functional derangement of contraction of heart. This dysregulation of intracellular $Ca^{2+}$ concentration could explain for clinical findings of diabetic cardiomyopathy and provide the scientific basis for more effective treatments of diabetic patients. In view of these results, insulin may be involved in the control of intracellular $Ca^{2+}$ in the cardiomyocyte via unknown mechanism, which needs further study.

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Formation of Au Particles in Cu2-xICu2IIO3-δ (x ≈ 0.20; δ ≈ 0.10) Oxide Matrix by Sol-Gel Growth

  • Das, Bidhu Bhusan;Palanisamy, Kuppan;venugopal, Potu;Sandeep, Eesam;Kumar, Karrothu Varun
    • 대한화학회지
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    • 제61권1호
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    • pp.29-33
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    • 2017
  • Formation of Au particles in nonstoichiometric $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxide from aniline + hydrochloric acid mixtures and chloroauric acid in the ratios 30 : 1; 60 : 1; 90 : 1 (S1-S3) by volume and 0.01 mol of copper acetate, $Cu(OCOCH_3)_2.H_2O$, in each case is performed by sol-gel growth. Powder x-ray diffraction (XRD) results show Au particles are dispersed in tetragonal nonstoichiometric dicopper (I) dicopper (II) oxides, $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$). Average crystallite sizes of Au particles determined using Scherrer equation are found to be in the approximate ranges ${\sim}85-140{\AA}$, ${\sim}85-150{\AA}$ and ${\sim}80-150{\AA}$ in S1-S3, respectively which indicate the formation of Au nano-micro size particles in $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxides. Hysteresis behaviour at 300 K having low loop areas and magnetic susceptibility values ${\sim}5.835{\times}10^{-6}-9.889{\times}10^{-6}emu/gG$ in S1-S3 show weakly ferromagnetic nature of the samples. Broad and isotropic electron paramagnetic resonance (EPR) lineshapes of S1-S4 at 300, 77 and 8 K having $g_{iso}$-values ${\sim}2.053{\pm}0.008-2.304{\pm}0.008$ show rapid spin-lattice relaxation process in magnetic $Cu^{2+}$ ($3d^9$) sites as well as delocalized electrons in Au ($6s^1$) nano-micro size particles in the $Cu_{2-x}{^I}Cu{_2}^{II}O_{3-{\delta}}$ ($x{\approx}0.20$; ${\delta}{\approx}0.10$) oxides. Broad and weak UV-Vis diffuse reflectance optical absorption band ~725 nm is assigned to $^2B_{1g}{\rightarrow}^2A_{1g}$ transitions, and the weak band ~470 nm is due to $^2B_{1g}{\rightarrow}^2E_g$ transitions from the ground state $^2B_{1g}$(${\mid}d_{x^2-y^2}$>) of $Cu^{2+}$ ($3d^9$) ions in octahedral coordination having tetragonal distortion.

코끼리 조개육이 동결저장중 단백질 조성 및 Texture변화에 미치는 Blanching의 영향 (Effect of Blanching on Protein Composition and Texture in Geoduck Muscle during Frozen Storage)

  • 유병진;정인학;이강호
    • 한국수산과학회지
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    • 제27권1호
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    • pp.33-40
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    • 1994
  • 코끼리 조개의 동결저장중 단백질조성 및 texture변화에 미치는 blanching의 영향에 대하여 조사한 결과는 다음과 같다. 생육에 있어서 근형질 단백질과 근원섬유 단백질은 급격한 감소현상을 보였으나 알카리가용성 단백질은 급격히 증가하였다. Blanching육에서는 근형질 단백질과 근원섬유 단백질은 완만하게 감소하였다. Blanching 시간에 있어서 2분간 처리한 시료가 관능검사에 의해 가장 texture가 우수하였는데 생육과 비교할 때 경도는 차이가 없었으나 탄성, 변형력 완화율은 낮은 값을 보였고 파괴신장율과 toughness은 높은 값을 나타내었다. 동결저장 중의 texture의 변화에 있어서 저장기간이 증가함에 따라 경도와 toughness은 생육과 blanching육 모두 증가하였으며 변형력 완화율은 저장초기 모두 급격히 감소되었다가 그 후로는 큰변화를 보이지 않았으며 파괴신장율은 생육의 경우 저장초기에 급속히 증가하였고 blanching육은 큰 변화가 없었다. 탄성에서는 생육은 점차적으로 감소하였고 blanching육은 증가하는 경향을 나타내었다.

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